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Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 1,   Pages 80-84 doi: 10.1007/s11705-008-0017-0

Abstract: 2-(5-Amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl thioester(III), an importantintermediate of the fourth generation cephalosporins, was efficiently synthesized by reacting 2-(5-amino-1,2,4-thiadiazol-3-ylthiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid (I) with 2,2′-dibenzothiazole disulfide (II) in the presence

Keywords： 5-Amino-1     2     4-thiadiazol-3-yl     1     2-dichloroethane     important intermediate     2-benzothiazolyl thioester     temperature    

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Microwave-assisted synthesis and antimicrobial activities of 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin-4-ones

Hua CHEN, Yanan LI, Jie BAI, Lian ZHAO, Xiangguo YUAN, Xiaoliu LI, Keqiang CAO

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 186-191 doi: 10.1007/s11705-009-0004-0

Abstract: 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin-4-ones and were synthesized in 41%-67% yield by

Keywords： microwave-assisted synthesis     naphthyl     thiazolidin-4-one     antimicrobial    

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Wideband circular-polarized transmitarray for generating a high-purity vortex beam Correspondence

Liangjie QIU, Xiuping LI, Zihang QI, Wenyu ZHAO, Yuhan HUANG,xpli@bupt.edu.cn

Frontiers of Information Technology & Electronic Engineering 2023, Volume 24, Issue 6,   Pages 927-934 doi: 10.1631/FITEE.2200539

Abstract: The measured peak gain is 22.3 dBic, and the 3-dB axial ratio bandwidth is 27.6%.

Keywords： 轨道角动量；涡旋波束；透射阵；宽带；高纯度    

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acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH3<

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1399-1411 doi: 10.1007/s11705-023-2345-5

Abstract: Three kinds of Ce-based catalysts (CePO4, CeVO4, Ce2(SO4)> Ce2(SO4)3, which is in agreement with their abilities of NH343–, VO43– and SO42–4+, large NH3 adsorption/sub>)3.

Keywords： CePO4     CeVO4     Ce2(SO4)3     selective catalytic reduction    

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Rh2O3/hexagonal CePO4 nanocatalysts for N2O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2O3     CePO4     N2O decomposition    

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China in the eyes of news media: a case study under COVID-19 epidemic Research Article

Hong Huang, Zhexue Chen, Xuanhua Shi, Chenxu Wang, Zepeng He, Hai Jin, Mingxin Zhang, Zongya Li,honghuang@hust.edu.cn,chenzhexue@hust.edu.cn,xhshi@hust.edu.cn,wangchenxu@hust.edu.cn,hezepeng@hust.edu.cn,hjin@hust.edu.cn,mingxinzhang@hust.edu.cn,lzy901014@sina.com

Frontiers of Information Technology & Electronic Engineering 2021, Volume 22, Issue 11,   Pages 1443-1457 doi: 10.1631/FITEE.2000689

Abstract: (3) What is the media’s attitude when talking about China?

Keywords： 国家形象；新冠肺炎；主题挖掘；实体；新闻立场；情感    

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Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10,   Pages 1514-1525 doi: 10.1007/s11705-022-2158-y

Abstract: Under mild reaction conditions, the Pd/Fe3O4@C magnetic nanocatalyst demonstratedAlso, the Pd/Fe3O4@C magnetic nanocatalyst exhibited excellent catalytic activityAlso, we explored the use of Pd/Fe3O4@C magnetic nanocatalyst as an electrocatalystInterestingly, the Pd/Fe3O4@C magnetic nanocatalyst exhibited better electrochemicalactivity compared to bare carbon and magnetite (Fe3O4 nanoparticles) with an overpotential

Keywords： bio-waste     cellulosic-carbon     Pd/Fe3O4     Hiyama cross-coupling     hydrogen evolution    

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Preparation and property characterization of PAA/Fe3O4 nanocomposite

WEI Shanshan, ZHANG Yi, XU Jiarui

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 3,   Pages 233-237 doi: 10.1007/s11705-007-0042-4

Abstract: PAA/FeO nanocomposites were prepared by mixing nano-FeOvent. The materials were characterized by transmission electron microscope (TEM), Fourier transform infrared spectroscope (FTIR), thermogravimetry analysis (TGA), dynamic ultra-micro hardness tester (DUMHT) and superconducting quantum interference device (SQUID) magnetometer. Results showed that PAA coordinated with nano-FeO to form a cross-linking structure. The presence of nano-FeO enhanced the thermal stability of the nanocomposite. The elasticity and hardness of the nanocomposite increased, and the indentation depth reduced with the increase of FeO content in the composites. The nanocomposites showed superparamagnetic properties at 300 K.

Keywords： magnetometer     superparamagnetic     ultra-micro     thermogravimetry     transmission    

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Development of Bioimplants with 2D, 3D, and 4D Additive Manufacturing Materials Review

Guo Liu, Yunhu He, Pengchao Liu, Zhou Chen, Xuliang Chen, Lei Wan, Ying Li, Jian Lu

Engineering 2020, Volume 6, Issue 11,   Pages 1232-1243 doi: 10.1016/j.eng.2020.04.015

Abstract: However, 3D printable materials are still quite limited for the fabrication of bioimplants.In this work, 2D/3D AM materials for bioimplants are reviewed.Furthermore, inspired by Tai Chi, a simple yet novel soft/rigid hybrid 4D AM concept is advanced to developcomplex and dynamic biological structures in the human body based on 4D printing hybrid ceramic precursor/4D AM materials can be anticipated.

Keywords： Bioprinting     2D additive manufacturing     3D printing     4D printing     Bioimplants    

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Synthesis, molecular docking and antibacterial evaluation of 2-(4-(4-aminophenylsulfonyl)phenylamino)-3-(thiophen-2-ylthio)naphthalene-1,4-dione derivatives

Palanisamy RAVICHANDIRAN, Dhanaraj PREMNATH, Samuel VASANTHKUMAR

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 1,   Pages 46-56 doi: 10.1007/s11705-015-1506-6

Abstract: A new series of 2-(4-(4-aminophenylsulfonyl)phenylamino)-3-(thiophen-2-ylthio)naphthalene-1,4-dione derivatives( 3a-3n) were synthesized and characterized by spectral techniques.(4-(1,4-dioxo-3-(thiophen-2-ylthio)-1,4-dihydronaphthalen-2-ylamino)phenylsulfonyl)phenyl)-3-methylbenzamide( 3b) exhibited good glide and E model scores of ?(4-(1,4-dioxo-3-(thiophen-2-ylthio)-1,4-dihydronaphthalen-2-ylamino)phenylsulfonyl)phenyl)-4-nitrobenzamide

Keywords： MIC     2-thiophene thiol     water as solvent     acid chlorides     sulfone    

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Ultrasound-assisted co-precipitation synthesis of mesoporous Co3O4–CeO2 composite oxides for highly selective

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1211-1223 doi: 10.1007/s11705-022-2145-3

Abstract: In this study, a Co3O4–CeO2 composite oxide catalyst was successfully/Co2+ and Ce4+/Ce3+ redox pairs, than bulk CeO2 and/or Co3O4.conditions, 89.6% selectivity to KA-oil with a cyclohexane conversion of 5.8% was achieved over Co3O4–CeO2.

Keywords： Co3O4–CeO2 composite oxides     cyclohexanone     cyclohexanol     ultrasonic-assisted    

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On the monolayer dispersion behavior of Co3O4 on HZSM-5 support: designing applicable

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1741-1754 doi: 10.1007/s11705-023-2332-x

Abstract: Based on monolayer dispersion theory, Co3O4/ZSM-5 catalysts with different loadingsCo3O4 can spontaneously disperse on HZSM-5 support with a monolayer dispersionHowever, the formation of crystalline Co3O4 above the capacity is harmful to thereaction performance. 4% Co3O4/ZSM-5, the catalyst close to the monolayer dispersioncapacity amount of Co3O4 onto HZSM-5 support.

Keywords： Co3O4/ZSM-5     NOx-SCR by NH3     monolayer dispersion    

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Passive mode-locked Er-doped fiber laser pulse generation based on titanium disulfide saturable absorber Research Articles

Xinxin Shang, Linguang Guo, Huanian Zhang, Dengwang Li, Qingyang Yue,huanian_zhang@163.com,qingyangyue@sdnu.edu.cn

Frontiers of Information Technology & Electronic Engineering 2021, Volume 22, Issue 5,   Pages 615-766 doi: 10.1631/FITEE.2000341

Abstract: In this study, (TiS) polyvinyl alcohol (PVA) film-type (SA) is synthesized with a modulation depth of 5.08% and a saturable intensity of 10.62 MW/cm by liquid-phase exfoliation and spin-coating methods. Since TiS-based SA has a strong nonlinear saturable absorption property, two types of optical soliton were observed in a mode-locked Er-doped . When the pump power was raised to 67.3 mW, a conventional mode-locked pulse train with a repetition rate of 1.716 MHz and a pulse width of 6.57 ps was generated, and the output spectrum centered at 1556.98 nm and 0.466 nm spectral width with obvious Kelly sidebands was obtained. Another type of mode-locked pulse train with the maximum output power of 3.92 mW and pulse energy of 2.28 nJ at the pump power of 517.2 mW was achieved when the polarization controllers were adjusted. Since TiS-based SA has excellent nonlinear saturable absorption characteristics, broad applications in ultrafast photonic are expected.

Keywords： 光纤激光器；被动锁模；可饱和吸收体；二硫化钛    

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Changes of phenotype and function of human CD4 CD25 T cells induced by transfection of Foxp3

WU Kui, BI Yutian, WANG Yaoli, WANG Changzheng

Frontiers of Medicine 2008, Volume 2, Issue 4,   Pages 366-369 doi: 10.1007/s11684-008-0070-6

Abstract: of naive CD4 T cells.The pMSCV-Foxp3 retroviral vector encoding Foxp3 gene was transduced into the PT67 packaging cell lineFoxp3-gene transfected CD4 T cells could express Foxp3 and transfection of Foxp3 gene up-regulated theCD4CD25 T cells acquired a regulatory phenotype and function after it was transduced with the Foxp3 geneThis suggested a key role of Foxp3 in the generation of CD4CD25 regulatory T cells.
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Biomimetic Macrophage–Fe3O4@PLGA Particle-Triggered Intelligent Catalysis for Killing Multidrug-Resistant

Jieni Fu,Xiangmei Liu,Zhaoyang Li,Yufeng Zheng,Yu Zhang,Hui Jiang,Yanqin Liang,Shengli Zhu,Zhenduo Cui,Shuilin Wu,

Engineering doi: 10.1016/j.eng.2023.05.022

Abstract: an intelligent controlling center (a living macrophage, MΦ) and a Fenton reaction catalyst (Fe3O4@poly(lactic-co-glycolic acid) (PLGA) nanoparticles) for killing MDR EThe MΦ–Fe3O4@PLGA particles (i.e., the intelligent catalysis particles) exhibitThe H2O2 further reacts with Fe3O4@PLGA to form highly toxicO4@PLGA particles is well maintained.

Keywords： Multidrug-resistant Escherichia coli     Macrophage–Fe3O4@PLGA particles     Biomimetic intelligent catalysis    

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Title Author Date Type Operation

Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

Journal Article

Microwave-assisted synthesis and antimicrobial activities of 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin-4-ones

Hua CHEN, Yanan LI, Jie BAI, Lian ZHAO, Xiangguo YUAN, Xiaoliu LI, Keqiang CAO

Journal Article

Wideband circular-polarized transmitarray for generating a high-purity vortex beam

Liangjie QIU, Xiuping LI, Zihang QI, Wenyu ZHAO, Yuhan HUANG,xpli@bupt.edu.cn

Journal Article

acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH3<

Journal Article

Rh2O3/hexagonal CePO4 nanocatalysts for N2O decomposition

Huan Liu, Zhen Ma

Journal Article

China in the eyes of news media: a case study under COVID-19 epidemic

Hong Huang, Zhexue Chen, Xuanhua Shi, Chenxu Wang, Zepeng He, Hai Jin, Mingxin Zhang, Zongya Li,honghuang@hust.edu.cn,chenzhexue@hust.edu.cn,xhshi@hust.edu.cn,wangchenxu@hust.edu.cn,hezepeng@hust.edu.cn,hjin@hust.edu.cn,mingxinzhang@hust.edu.cn,lzy901014@sina.com

Journal Article

Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic

Journal Article

Preparation and property characterization of PAA/Fe3O4 nanocomposite

WEI Shanshan, ZHANG Yi, XU Jiarui

Journal Article

Development of Bioimplants with 2D, 3D, and 4D Additive Manufacturing Materials

Guo Liu, Yunhu He, Pengchao Liu, Zhou Chen, Xuliang Chen, Lei Wan, Ying Li, Jian Lu

Journal Article

Synthesis, molecular docking and antibacterial evaluation of 2-(4-(4-aminophenylsulfonyl)phenylamino)-3-(thiophen-2-ylthio)naphthalene-1,4-dione derivatives

Palanisamy RAVICHANDIRAN, Dhanaraj PREMNATH, Samuel VASANTHKUMAR

Journal Article

Ultrasound-assisted co-precipitation synthesis of mesoporous Co3O4–CeO2 composite oxides for highly selective

Journal Article

On the monolayer dispersion behavior of Co3O4 on HZSM-5 support: designing applicable

Journal Article

Passive mode-locked Er-doped fiber laser pulse generation based on titanium disulfide saturable absorber

Xinxin Shang, Linguang Guo, Huanian Zhang, Dengwang Li, Qingyang Yue,huanian_zhang@163.com,qingyangyue@sdnu.edu.cn

Journal Article

Changes of phenotype and function of human CD4 CD25 T cells induced by transfection of Foxp3

WU Kui, BI Yutian, WANG Yaoli, WANG Changzheng

Journal Article

Biomimetic Macrophage–Fe3O4@PLGA Particle-Triggered Intelligent Catalysis for Killing Multidrug-Resistant

Jieni Fu,Xiangmei Liu,Zhaoyang Li,Yufeng Zheng,Yu Zhang,Hui Jiang,Yanqin Liang,Shengli Zhu,Zhenduo Cui,Shuilin Wu,

Journal Article