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Hydroxyl radical-involved cancer therapy via Fenton reactions

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 3,   Pages 345-363 doi: 10.1007/s11705-021-2077-3

Abstract: versatile therapeutic strategies based on H2O2 as a reaction substrate to generate hydroxylradical (•OH) have been used as a prospective therapeutic method to boost anticancer efficiency.Furthermore, the challenges and future developments of hydroxyl radical-involved cancer therapy are discussed

Keywords： hydroxyl radical     Fenton catalyst     hydrogen peroxide     cancer therapy    

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A pulsed switching peroxi-coagulation process to control hydroxyl radical production and to enhance 2,4

Yaobin Lu, Songli He, Dantong Wang, Siyuan Luo, Aiping Liu, Haiping Luo, Guangli Liu, Renduo Zhang

Frontiers of Environmental Science & Engineering 2018, Volume 12, Issue 5, doi: 10.1007/s11783-018-1070-7

Abstract:

• A new pulsed switching peroxi-coagulation (PSPC) system was developed.

• The ECT for 2,4-D removal in the PSPC was lower than that in the EF.

• The iron consumption for 2,4-D removal in the PSPC was lower than that in the PC.

Keywords： Pulsed switching peroxi-coagulation system     Energy consumption     Hydroxyl radical production     2     4- Dichlorophenoxyacetic    

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Hydroxyl radical intensified Cu

Wenyue Li, Min Chen, Zhaoxiang Zhong, Ming Zhou, Weihong Xing

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 6, doi: 10.1007/s11783-020-1281-6

Abstract: The intensified radical yield, fast mass transfer and nanoparticles high activity all contributed to

Keywords： Ceramic membrane reactor     N     N-dimethylacetamide     Fenton process     Cu2O     Wastewater treatment    

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Zero-valent manganese nanoparticles coupled with different strong oxidants for thallium removal from wastewater

Keke Li, Huosheng Li, Tangfu Xiao, Gaosheng Zhang, Aiping Liang, Ping Zhang, Lianhua Lin, Zexin Chen, Xinyu Cao, Jianyou Long

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 2, doi: 10.1007/s11783-019-1213-5

Abstract: . • Mn0 can activate persulfate to form hydroxyl and sulfate radicals. • Oxidation-induced precipitationThe Mn0 nanomaterials can activate persulfate to produce sulfate radicals and hydroxyl radicals.

Keywords： Nano zero-valent manganese     Thallium     Adsorption     Oxidation     Sulfate radical     Hydroxyl radical    

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Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate in the rotating packed bed

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 4,   Pages 460-469 doi: 10.1007/s11705-022-2224-5

Abstract: Nitric oxide being a major gas pollutant has attracted much attention and various technologies have been developed to reduce NO emission to preserve the environment. Advanced persulfate oxidation technology is a workable and effective choice for wet flue gas denitrification due to its high efficiency and green advantages. However, NO absorption rate is limited and affected by mass transfer limitation of NO and aqueous persulfate in traditional reactors. In this study, a rotating packed bed (RPB) was employed as a gas–liquid absorption device to elevate the NO removal efficiency (ηNO) by aqueous persulfate ((NH4)2S2O8) activated by ferrous ethylenediaminetetraacetate (Fe2+-EDTA). The experimental results regarding the NO absorption were obtained by investigating the effect of various operating parameters on the removal efficiency of NO in RPB. Increasing the concentration of (NH4)2S2O8 and liquid–gas ratio could promoted the oxidation and absorption of NO while the ηNO decreased with the increase of the gas flow and NO concentration. In addition, improving the high gravity factor increased the ηNO and the total volumetric mass transfer coefficient (KGα) which raise the ηNO up to more than 75% under the investigated system. These observations proved that the RPB can enhance the gas–liquid mass transfer process in NO absorption. The correlation formula between KGα and the influencing factors was determined by regression calculation, which is used to guide the industrial scale-up application of the system in NO removal. The presence of O2 also had a negative effect on the NO removal process and through electron spin resonance spectrometer detection and product analysis, it was revealed that Fe2+-EDTA activated (NH4)2S2O8 to produce •SO4–, •OH and •O2–, played a leading role in the oxidation of NO, to produce NO3– as the final product. The obtained results demonstrated a good applicable potential of RPB/PS/Fe2+-EDTA in the removal of NO from flue gases.

Keywords： rotating packed bed     Fe2+-EDTA     sulfate radical     hydroxyl radical     NO removal efficiency    

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Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 513-521 doi: 10.1007/s11705-019-1825-0

Abstract: The yields of hydroxyl radical were estimated on the kinetics data for the hydroxylation of benzoic acid

Keywords： atmospheric pressure glow discharge     underwater diaphragm discharge     oxidation     benzoic acid     hydroxyl radical    

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Toward better understanding vacuum ultraviolet–iodide induced photolysis via hydrogen peroxide formation, iodine species change, and difluoroacetic acid degradation

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 5, doi: 10.1007/s11783-021-1489-0

Abstract:

• UV/VUV/I– induces substantial H2O2 and IO3– formation, but UV/I– does not.

Keywords： Vacuum ultraviolet     Hydrogen peroxide     Iodate     Hydroxyl radical     Redox transition    

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Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 1,   Pages 37-45 doi: 10.1007/s11783-014-0729-y

Abstract: A study of the decolorization of reactive brilliant blue in an aqueous solution using Fe-Mn-sepiolite as a heterogeneous Fenton-like catalyst has been performed. The Fourier transform infrared (FTIR) spectra of the catalyst showed bending vibrations of the Fe-O. The X-ray diffraction (XRD) patterns of the catalyst showed characteristic diffraction peaks of α-Fe O , γ-Fe O and MnO. A four factor central composite design (CCD) coupled with response surface methodology (RSM) was applied to evaluate and optimize the important variables (catalyst addition, hydrogen peroxide dosage, initial pH value and initial dye concentration). When the reaction conditions were catalyst dosage= 0.4 g, [H O ]= 0.3 mL, pH= 2.5, [reactive brilliant blue] = 50 mg·L , and volume of solution= 500 mL at room temperature, the decolorization efficiency of reactive brilliant blue was 91.98% within 60 min. Moreover, the Fe-Mn-sepiolite catalyst had good stability for the degradation of reactive brilliant blue even after six cycles. Leaching of iron ions (<0.4 mg·L ) was observed. The decoloring process was reactive brilliant blue specific via a redox reaction. The benzene ring and naphthalene ring were first oxidized to open ring; these were then oxidized to the alcohol and carboxylic acid. The reactive brilliant blue was decomposed mainly by the attack of ·OH radicals including surface-bound ·OH radicals generated on the catalyst surface.

Keywords： Fe-Mn-sepiolite catalyst     heterogeneous Fenton-like     reactive brilliant blue     homogeneous precipitation method     hydroxylradical    

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Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic ozonation

Jin Yang, Xuelian Liu, Hongbin Cao, Yanchun Shi, Yongbing Xie, Jiadong Xiao

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 1,   Pages 185-191 doi: 10.1007/s11705-018-1713-z

Abstract: An appropriate co-catalyst can significantly promote the photocatalytic efficacy, but this has been seldom studied in the visible-light photocatalysis combined with ozone, namely photocatalytic ozonation. In this work, a dendritic bismuth vanadium tetraoxide (BiVO ) material composited with highly dispersed MnO nanoparticles was synthesized, and its catalytic activity is 86.6% higher than bare BiVO in a visible light and ozone combined process. Catalytic ozonation experiments, ultra-violet-visible (UV-Vis) diffuse reflectance spectra and photoluminescence spectra jointly indicate that MnO plays a triple role in this process. MnO strengthens the light adsorption and promotes the charge separation on the composite material, and it also shows good activity in catalytic ozonation. The key reactive species in this process is ·OH, and various pathways for its generation in this process is proposed. This work provides a new direction of catalyst preparation and pushes forward the application of photocatalytic ozonation in water treatment.

Keywords： manganese oxide     bismuth vanadium tetraoxide     photocatalytic ozonation     hydroxyl radical     co-catalyst    

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Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH· generation

Hong SUN,Min SUN,Yaobin ZHANG,Xie QUAN

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 4,   Pages 591-595 doi: 10.1007/s11783-014-0694-5

Abstract: degradation efficiency, indicating that the degradation of Reactive Red X-3B followed the mechanism of hydroxylradical (OH·) oxidation.

Keywords： catalytic ozonation     reactive red X-3B     ceramic honeycomb     hydroxyl radical (OH·)    

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Significant enhancement in catalytic ozonationefficacy: From granular to super-fine powdered activated carbon

Tianyi Chen, Wancong Gu, Gen Li, Qiuying Wang, Peng Liang, Xiaoyuan Zhang, Xia Huang

Frontiers of Environmental Science & Engineering 2018, Volume 12, Issue 1, doi: 10.1007/s11783-018-1022-2

Abstract: In this study, super-fine powdered activated carbon (SPAC) hasbeen proposed and investigated as a novel catalyst for the catalyticozonation of oxalate for the first time. SPAC was prepared from commercialgranular activated carbon (GAC) by ball milling. SPAC exhibited highexternal surface area with a far greater member of meso- and macropores(563% increase in volume). The catalytic performances of activatedcarbons (ACs) of 8 sizes were compared and the rate constant for pseudofirst-order total organic carbon removal increased from 0.012 min to 0.568 min (47-fold increase) withthe decrease in size of AC from 20 to 40 mesh (863 mm) to SPAC (~1.0 mm). Furthermore, the diffusion resistance of SPAC decreased17-fold compared with GAC. The ratio of oxalate degradation by surfacereaction increased by 57%. The rate of transformationof ozone to radicals by SPAC was 330 times that of GAC. The resultssuggest that a series of changes stimulated by ball milling, includinga larger ratio of external surface area, less diffusion resistance,significant surface reaction and potential oxidized surface all contributedto enhancing catalytic ozonation performance. This study demonstratedthat SPAC is a simple and effective catalyst for enhancing catalyticozonation efficacy.

Keywords： Super-fine activated carbon     Catalytic ozonation     External surface area     Surface reaction     Hydroxyl radical    

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Non-closure of the peritoneum and subcutaneous tissue at radical hysterectomy: A randomized controlled

Zhou-Fang XIONG MD, Wei-Hong DONG MD, Ze-Hua WANG MD,

Frontiers of Medicine 2010, Volume 4, Issue 1,   Pages 112-116 doi: 10.1007/s11684-010-0016-7

Abstract: peritoneum and subcutaneous tissue on the clinical outcomes of cervical cancer patients who underwent radicalThe practice of closure of the peritoneum and subcutaneous tissue at radical hysterectomy should be questioned

Keywords： cervical cancer     radical surgery     peritoneum     subcutaneous tissue    

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Bacteria inactivation by sulfate radical: progress and non-negligible disinfection by-products

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 3, doi: 10.1007/s11783-023-1629-9

Abstract:

● Status of inactivation of pathogenic microorganisms by SO4•− is reviewed.

Keywords： Sulfate radicals     Disinfection by-products     Inactivation mechanisms     Bacterial inactivation     Water disinfection    

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Kinetics and mechanism of nitrobenzene degradation by hydroxyl radicals-based ozonation process enhanced

Weizhou Jiao, Shengjuan Shao, Peizhen Yang, Kechang Gao, Youzhi Liu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1197-1205 doi: 10.1007/s11705-020-1998-6

Abstract: This study investigated the indirect oxidation of nitrobenzene (NB) by hydroxyl radicals (·OH) in a rotating

Keywords： high gravity technology     hydroxyl radicals     nitrobenzene     reaction kinetics    

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Free radical scavenging window of infertile patients with polycystic ovary syndrome: correlation with

Bo Huang, Zhou Li, Xinling Ren, Jihui Ai, Lixia Zhu, Lei Jin

Frontiers of Medicine 2017, Volume 11, Issue 2,   Pages 247-252 doi: 10.1007/s11684-017-0519-6

Abstract: However, studies analyzing the relationship between the free radical scavenging capacity and embryo qualityThe aim of this study was to evaluate the relationship between the free radical scavenging window of(DPPH), 2,2-azinobis (3-ethylbenzthiazoline-6-sulphonic acid) assay, superoxide radical, and reactiveThe lower control limit of DPPH radical scavenging capacity and upper control limit of ROS level wereThese cut-off values of free radical scavenging activity of follicular fluid could assist embryologists

Keywords： in vitro fertilization     PCOS     free radical     embryo quality    

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Title Author Date Type Operation

Hydroxyl radical-involved cancer therapy via Fenton reactions

Journal Article

A pulsed switching peroxi-coagulation process to control hydroxyl radical production and to enhance 2,4

Yaobin Lu, Songli He, Dantong Wang, Siyuan Luo, Aiping Liu, Haiping Luo, Guangli Liu, Renduo Zhang

Journal Article

Hydroxyl radical intensified Cu

Wenyue Li, Min Chen, Zhaoxiang Zhong, Ming Zhou, Weihong Xing

Journal Article

Zero-valent manganese nanoparticles coupled with different strong oxidants for thallium removal from wastewater

Keke Li, Huosheng Li, Tangfu Xiao, Gaosheng Zhang, Aiping Liang, Ping Zhang, Lianhua Lin, Zexin Chen, Xinyu Cao, Jianyou Long

Journal Article

Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate in the rotating packed bed

Journal Article

Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

Journal Article

Toward better understanding vacuum ultraviolet–iodide induced photolysis via hydrogen peroxide formation, iodine species change, and difluoroacetic acid degradation

Journal Article

Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

Journal Article

Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic ozonation

Jin Yang, Xuelian Liu, Hongbin Cao, Yanchun Shi, Yongbing Xie, Jiadong Xiao

Journal Article

Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH· generation

Hong SUN,Min SUN,Yaobin ZHANG,Xie QUAN

Journal Article

Significant enhancement in catalytic ozonationefficacy: From granular to super-fine powdered activated carbon

Tianyi Chen, Wancong Gu, Gen Li, Qiuying Wang, Peng Liang, Xiaoyuan Zhang, Xia Huang

Journal Article

Non-closure of the peritoneum and subcutaneous tissue at radical hysterectomy: A randomized controlled

Zhou-Fang XIONG MD, Wei-Hong DONG MD, Ze-Hua WANG MD,

Journal Article

Bacteria inactivation by sulfate radical: progress and non-negligible disinfection by-products

Journal Article

Kinetics and mechanism of nitrobenzene degradation by hydroxyl radicals-based ozonation process enhanced

Weizhou Jiao, Shengjuan Shao, Peizhen Yang, Kechang Gao, Youzhi Liu

Journal Article

Free radical scavenging window of infertile patients with polycystic ovary syndrome: correlation with

Bo Huang, Zhou Li, Xinling Ren, Jihui Ai, Lixia Zhu, Lei Jin

Journal Article