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Thermodynamic analysis of reaction pathways and equilibrium yields for catalytic pyrolysis of naphtha

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1700-1712 doi: 10.1007/s11705-022-2207-6

Abstract: length and hydrocarbon type significantly affect the production of light olefins during the catalytic pyrolysisand operation parameters optimization, the reaction pathways and equilibrium yields for the catalytic pyrolysisdevelopment of superior catalysts and the selection of proper operation parameters for the catalytic pyrolysis

Keywords: naphtha     catalytic pyrolysis     reaction pathway     equilibrium yield    

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 11, doi: 10.1007/s11783-022-1581-0

Abstract: >

● The co-existing metals in WPCBs has positive catalytic influence in pyrolysis

Keywords: Waste printed circuit board     Catalyst     Pyrolysis     Kinetics    

Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 7, doi: 10.1007/s11783-021-1488-1

Abstract:

• Adding kaolin/zeolite promotes the formation of stable heavy metals.

Keywords: Co-pyrolysis     Sewage sludge     Heavy metals     Rotary kiln     Immobilization mechanism    

Theoretical study on the mechanism of sulfur migration to gas in the pyrolysis of benzothiophene

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 3,   Pages 334-346 doi: 10.1007/s11705-022-2209-4

Abstract: The release and control of sulfur species in the pyrolysis of fossil fuels and solid wastes have attractedthe mechanism of sulfur migration during the release of sulfur-containing radicals in benzothiophene pyrolysisstrong competitiveness of S and SH radicals results in abundant H2S during benzothiophene pyrolysisstudy lays a foundation for elucidating sulfur migration mechanisms and furthering the development of pyrolysis

Keywords: benzothiophene     sulfur migration     pyrolysis     density functional theory    

Effect of / molecular structures on pyrolysis performance and heat sink of decalin isomers

Frontiers of Chemical Science and Engineering 2023, Volume 18, Issue 1, doi: 10.1007/s11705-023-2375-z

Abstract: However, decalin contains two isomers with a tunable composition, and their effects on the pyrolysisHerein, we investigated the pyrolysis of decalin isomers, i.e., cis-decalin, trans-decalinThe pyrolysis results confirmed that conversion of the tested fuels (600–725 °C, 4 MPa) decreased inDetailed analyses of the pyrolysis products were used to compare the product distributions from cisThis work demonstrates the relationship between the cis/trans structures and the pyrolysis

Keywords: endothermic fuel     decalin     pyrolysis     heat sink     molecular structure    

Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

Frontiers in Energy 2010, Volume 4, Issue 3,   Pages 424-429 doi: 10.1007/s11708-010-0015-z

Abstract: Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed to achieve fast pyrolysis of xylanand on-line analysis of pyrolysis vapors.temperature on pyrolytic products, and to reveal the effect of HZSM-5 and M/HZSM-5 (M= Fe, Zn) zeolites on pyrolysisCatalytic cracking of pyrolysis vapors with HZSM-5 and M/HZSM-5 (M= Fe, Zn) catalysts significantly altered

Keywords: xylan     fast pyrolysis     catalytic pyrolysis     Py-GC/MS     HZSM-5    

Mechanism insight into the formation of HS from thiophene pyrolysis: A theoretical study

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1404-8

Abstract: ListItem>

• Possible formation pathways of H2S were revealed in thiophene pyrolysis

Keywords: Density functional theory     Waste rubber     Thiophene     H2S     Pyrolysis    

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1570-3

Abstract:

● Collaborative treatment of plastics and OS was established to improve oil quality.

Keywords: Oily sludge     Pyrolysis     Polyethylene     H/Ceff ratio     Oil quality    

Upgrading of derived pyrolysis vapors for the production of biofuels from corncobs

Liaoyuan Mao, Yanxin Li, Z. Conrad Zhang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 50-58 doi: 10.1007/s11705-017-1685-4

Abstract: were fast pyrolyzed in the bubbling bed using fine sand particles as a heat carrier and the resulting pyrolysisEven a low usage of zeolite catalyst at WSHV of 180 h was effective in upgrading the pyrolysis oil and

Keywords: corncob     monolith     upgrading     pyrolysis    

Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 355-361 doi: 10.1007/s11705-010-0567-9

Abstract: flammable gas, charcoal, wood vinegar, wood tar oil and noncombustible materials with thermo-chemical pyrolysisBased on the data from a straw pyrolysis demonstration project, the mass and heat balance of the biomasspyrolysis process were analyzed.These results showed that the straw pyrolysis project has little risk, and will produce remarkable economic

Keywords: mass balance     heat balance     biomass pyrolysis     economic benefit    

Prediction of high-density polyethylene pyrolysis using kinetic parameters based on thermogravimetric

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 1, doi: 10.1007/s11783-023-1606-3

Abstract:

● Reducting the sampling frequency can enhance the modelling process.

Keywords: HDPE     Pyrolysis     Kinetics     Thermogravimetric     ANOVA     Artificial neural network    

Hydro-pyrolysis of lignocellulosic biomass over alumina supported Platinum, Mo

Songbo He, Jeffrey Boom, Rolf van der Gaast, K. Seshan

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 155-161 doi: 10.1007/s11705-017-1655-x

Abstract: In-line hydro-treatment of bio-oil vapor from fast pyrolysis of lignocellulosic biomass (hydro-pyrolysiswere compared at 500 °C and atmospheric pressure which are same as the reaction conditions for fast pyrolysisResults indicated that under the pyrolysis conditions, the major components, such as acids and carbonyls, of the fast pyrolysis bio-oil can be completely and partially hydrogenated to form hydrocarbons, anhydrocarbon formation (ca. 60%), showing the feasibility of using the cheap non-noble catalysts for hydro-pyrolysis

Keywords: bio-oil     pyrolysis     hydro-deoxygenation (HDO)     non-noble metal catalysts     hydro-treatment    

A review on co-pyrolysis of coal and oil shale to produce coke

Xiangchun Liu, Ping Cui, Qiang Ling, Zhigang Zhao, Ruilun Xie

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 504-512 doi: 10.1007/s11705-019-1850-z

Abstract: utilization of oil shale (OS) as a feedstock for coal-blending coking, in which the initial and basic step is pyrolysisseparation and beneficiation techniques for organic matter in OS, and provides an overview on coal and OS pyrolysisthrough several viewpoints (e.g., pyrolysis process, phenomena, and products).Then the exploratory studies on co-pyrolysis of coal with OS, including co-pyrolysis phenomena and processFinally, co-pyrolysis of different ranks of coals with OS in terms of coal-blending coking, where further

Keywords: coal     oil shale     co-pyrolysis     coal blending coking     coke    

Nanostructure and reactivity of soot from biofuel 2,5-dimethylfuran pyrolysis with CO

Lijie ZHANG, Kaixuan YANG, Rui ZHAO, Mingfei CHEN, Yaoyao YING, Dong LIU

Frontiers in Energy 2022, Volume 16, Issue 2,   Pages 292-306 doi: 10.1007/s11708-020-0658-3

Abstract: investigated the nanostructure and oxidation reactivity of soot generated from biofuel 2,5-dimethylfuran pyrolysis

Keywords: 2     5-dimethylfuran pyrolysis     soot     CO2 addition     nanostructure     reactivity    

Particle formation of hydroxyapatite precursor containing two components in a spray pyrolysis process

W. Widiyastuti, Adhi Setiawan, Sugeng Winardi, Tantular Nurtono, Heru Setyawan

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 1,   Pages 104-113 doi: 10.1007/s11705-014-1406-1

Abstract: precursor containing two components, Ca(OOCCH ) and (NH ) HPO with a ratio of Ca/P= 1.67, in a spray pyrolysis

Keywords: droplet     hydroxyapatite particle     CFD     tubular furnace     spray pyrolysis    

Title Author Date Type Operation

Thermodynamic analysis of reaction pathways and equilibrium yields for catalytic pyrolysis of naphtha

Journal Article

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

Journal Article

Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

Journal Article

Theoretical study on the mechanism of sulfur migration to gas in the pyrolysis of benzothiophene

Journal Article

Effect of / molecular structures on pyrolysis performance and heat sink of decalin isomers

Journal Article

Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

Journal Article

Mechanism insight into the formation of HS from thiophene pyrolysis: A theoretical study

Journal Article

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis

Journal Article

Upgrading of derived pyrolysis vapors for the production of biofuels from corncobs

Liaoyuan Mao, Yanxin Li, Z. Conrad Zhang

Journal Article

Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

Journal Article

Prediction of high-density polyethylene pyrolysis using kinetic parameters based on thermogravimetric

Journal Article

Hydro-pyrolysis of lignocellulosic biomass over alumina supported Platinum, Mo

Songbo He, Jeffrey Boom, Rolf van der Gaast, K. Seshan

Journal Article

A review on co-pyrolysis of coal and oil shale to produce coke

Xiangchun Liu, Ping Cui, Qiang Ling, Zhigang Zhao, Ruilun Xie

Journal Article

Nanostructure and reactivity of soot from biofuel 2,5-dimethylfuran pyrolysis with CO

Lijie ZHANG, Kaixuan YANG, Rui ZHAO, Mingfei CHEN, Yaoyao YING, Dong LIU

Journal Article

Particle formation of hydroxyapatite precursor containing two components in a spray pyrolysis process

W. Widiyastuti, Adhi Setiawan, Sugeng Winardi, Tantular Nurtono, Heru Setyawan

Journal Article