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Mercury enrichment in

Chunhao Dai, Pufeng Qin, Zhangwei Wang, Jian Chen, Xianshan Zhang, Si Luo

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 1, doi: 10.1007/s11783-017-0892-z

Abstract: Mercury enrichment in response to elevated atmospheric mercury concentrations in the organs of rape (Elevated soil mercury content had significant impact on mercury accumulation in rape stems, roots, seedsMercury in the aboveground plant tissue mainly derived from atmospheric absorption, and atmospheric mercuryMercury enrichment in response to elevated atmospheric mercury concentrations in the organs of rape (mercury.

Keywords: Open top chamber     Gaseous elemental mercury (GEM)     Soil Mercury     Brassica napus    

Mercury removal from flue gas using nitrate as an electron acceptor in a membrane biofilm reactor

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 2, doi: 10.1007/s11783-021-1454-y

Abstract:

Membrane bioreactor achieved mercury removal using nitrate as an electron

Keywords: Mercury removal     Oxygen     Ferrous sulfide     Transformation of mercury     Microbial community    

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4,   Pages 514-520 doi: 10.1007/s11705-011-1114-z

Abstract: Hence, for China, it is necessary to explore environmental friendly non-mercury catalysts for acetyleneThis paper presents a review of non-mercury heterogeneous and homogeneous catalysts as well as reactordesigns, and recommends future work for developing cleaner processes to produce VCM over non-mercury

Keywords: polyvinyl chloride     vinyl chloride monomer     acetylene hydrochlorination     non-mercury catalysts     green chemical    

A review of atmospheric mercury emissions, pollution and control in China

Shuxiao WANG,Lei ZHANG,Long WANG,Qingru WU,Fengyang WANG,Jiming HAO

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 5,   Pages 631-649 doi: 10.1007/s11783-014-0673-x

Abstract: Mercury, as a global pollutant, has significant impacts on the environment and human health.The current state of atmospheric mercury emissions, pollution and control in China is comprehensivelyWith about 500–800 t of anthropogenic mercury emissions, China contributes 25%–40% to the global mercuryThe mercury emissions from natural sources in China are equivalent to the anthropogenic mercury emissionsDedicated mercury control technologies are required in the future to further mitigate the mercury emissions

Keywords: atmospheric mercury     emissions     pollution     control     China    

New insights into mercury removal mechanism on CeO

Ling Li, Yu He, Xia Lu

Frontiers of Environmental Science & Engineering 2018, Volume 12, Issue 2, doi: 10.1007/s11783-018-1007-1

Abstract: First-principles calculations were performed to investigate the mechanism of Hg adsorption and oxidation on CeO (111). Surface oxygen activated by the reduction of Ce to Ce was vital to Hg adsorption and oxidation processes. Hg was fully oxidized by the surface lattice oxygen on CeO (111), without using any other oxidizing agents. HCl could dissociate and react with the Hg adatom on CeO (111) to form adsorbed Hg–Cl or Cl–Hg–Cl groups, which promoted the desorption of oxidized Hg and prevented CeO catalyst deactivation. In contrast, O–H and H–O–H groups formed during HCl adsorption consumed the active surface oxygen and prohibited Hg oxidation. The consumed surface oxygen was replenished by adding O into the flue gas. We proposed that oxidized Hg desorption and maintenance of sufficient active surface oxygen were the rate-determining steps of Hg removal on CeO -based catalysts. We believe that our thorough understanding and new insights into the mechanism of the Hg removal process will help provide guidelines for developing novel CeO -based catalysts and enhance the Hg removal efficiency.

Keywords: Elemental mercury removal     Surface adsorption     Ceria     First-principles calculations    

Removal of elemental mercury by KI-impregnated clay

Boxiong SHEN,Jianhong CHEN,Ji CAI

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 2,   Pages 236-243 doi: 10.1007/s11783-014-0765-7

Abstract: This study described the use of clay impregnated by KI in gas phase elemental mercury (Hg ) removal inThe results indicated that after adsorption, most of the mercury escaped from the surface again.Some of the mercury may have been oxidized as it left the surface.The results demonstrated that the chemical reaction primarily occurred between KI and mercury on the

Keywords: clay     elemental mercury     removal efficiency     potassium iodide     mechanism    

Biosorption of mercury and lead by aqueous

Pratibha SANJENBAM, Kumar SAURAV, Krishnan KANNABIRAN

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 2,   Pages 198-202 doi: 10.1007/s11705-012-1285-2

Abstract: The biosorption of mercury and lead by marine actinomycetes isolated from marine sediment collected fromeffects of the initial metal ion concentration, the pH and the biomass dosage on the biosorption of mercuryThe MTC of the isolate to metals was 200 mg·L for mercury and 1800 mg·L for lead.At neutral pH, the isolate had a maximum biosorption of metal ions of 200 mg·L and 150 mg·L for mercury

Keywords: mercury     lead     biosorption     maximum tolerance concentration     Streptomyces VITSVK9 sp.    

Mercury removal and recovery by immobilized

Meifang CHIEN, Ryo NAKAHATA, Tetsuya ONO, Keisuke MIYAUCHI, Ginro ENDO

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 2,   Pages 192-197 doi: 10.1007/s11705-012-1284-3

Abstract: From several mercury removing microorganisms, we selected MB1, which is non-pathogenic, broad-spectrumbioremediation of mercury pollution.efficient and stable catalytic bio-agent for mercury bioremediation.a large portion of reduced metallic mercury was trapped in the gel beads.from mercury-containing water.

Keywords: mercury removal     immobilized bacteria     alginate gel     bioremediation    

Source attribution for mercury deposition with an updated atmospheric mercury emission inventory in the

Jiajun Liu, Long Wang, Yun Zhu, Che-Jen Lin, Carey Jang, Shuxiao Wang, Jia Xing, Bin Yu, Hui Xu, Yuzhou Pan

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 1, doi: 10.1007/s11783-019-1087-6

Abstract:

Estimated anthropogenic Hg emission was 11.9 tons in Pearl River Delta for 2014.

Quantifying contributions of emission sources helps to provide control strategies.

More attentions should be paid to Hg deposition around the large point sources.

Power plant, industrial source and waste incinerator were priorities for control.

A coordinated regional Hg emission control was important for controlling pollution.

Keywords: Emission inventory     Mercury deposition     Pearl River Delta (PRD)     Source attribution     Control strategy    

Removal of elemental mercury with Mn/Mo/Ru/Al

Yongfu GUO, Naiqiang YAN, Ping LIU, Shijian YANG, Juan WANG, Zan QU

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 464-473 doi: 10.1007/s11783-012-0430-y

Abstract: this work, a catalytic membrane using Mn/Mo/Ru/Al O as the catalyst was employed to remove elemental mercury

Keywords: flue gas     elemental mercury     membrane     catalysis     transition metal    

A density functional theory study of the adsorption of Hg and HgCl2 on a CaO(001) surface

GUO Xin, ZHENG Chuguang, LU Nanxia

Frontiers in Energy 2007, Volume 1, Issue 1,   Pages 101-104 doi: 10.1007/s11708-007-0011-0

Abstract: The adsorption of mercury and mercury chloride on a CaO(001) surface was investigated by the densityFor the mercury molecular axis normal to the surface, the mercury can only coordinate to the O anionWhen the mercury chloride molecular axis is vertical to the surface, the Cl atom coordinates to the CaWhen the mercury chloride molecular axis is parallel to the surface, the Hg atom coordinates to the OThe present calculations show that CaO injection could substantially reduce gaseous mercury chloride,

Keywords: mercury chloride     mercury molecular     surface     cluster     electrostatic    

Mercury emission and adsorption characteristics of fly ash in PC and CFB boilers

Li JIA, Baoguo FAN, Xianrong ZHENG, Xiaolei QIAO, Yuxing YAO, Rui ZHAO, Jinrong GUO, Yan JIN

Frontiers in Energy 2021, Volume 15, Issue 1,   Pages 112-123 doi: 10.1007/s11708-020-0682-3

Abstract: The mercury emission was obtained by measuring the mercury contents in flue gas and solid samples in, while the mercury was enriched in fly ash and captured by the precipitator in CFB boiler.As the coal factor increased, the mercury emission to the atmosphere decreased.As the unburned carbon content increased, the mercury adsorbed increased.The capacity of adsorbing mercury by fly ash was directly related to the particle size.

Keywords: mercury     combustion modes     coal property     fly ash     particle size    

A Historical Sedimentary Record of Mercury in a Shallow Eutrophic Lake: Impacts of Human Activities and Article

Hanxiao Zhang, Shouliang Huo, Kevin M. Yeager, Beidou Xi, Jingtian Zhang,Fengchang Wu

Engineering 2019, Volume 5, Issue 2,   Pages 296-304 doi: 10.1016/j.eng.2018.11.022

Abstract:

Mercury and its derivatives are hazardous environmental pollutants and could affect the aquatic ecosystemsThis research investigates the 100-year history of mercury (Hg) deposition in sediments from Chao Lake

Keywords: Lake sediment     Mercury     Vertical distribution     Anthropogenic activities    

Reduced texaphyrin: A ratiometric optical sensor for heavy metals in aqueous solution

Harrison D. Root, Gregory Thiabaud, Jonathan L. Sessler

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 1,   Pages 19-27 doi: 10.1007/s11705-019-1888-y

Abstract: We report here a water-soluble metal cation sensor system based on the as-prepared or reduced form of an expanded porphyrin, texaphyrin. Upon metal complexation, a change in the redox state of the ligand occurs that is accompanied by a color change from red to green. Although long employed for synthesis in organic media, we have now found that this complexation-driven redox behavior may be used to achieve the naked eye detectable colorimetric sensing of several number of less-common metal ions in aqueous media. Exposure to In(III), Hg(II), Cd(II), Mn(II), Bi(III), Co(II), and Pb(II) cations leads to a colorimetric response within 10 min. This process is selective for Hg(II) under conditions of competitive analysis. Furthermore, among the subset of response-producing cations, In(III) proved unique in giving rise to a ratiometric change in the ligand-based fluorescence features, including an overall increase in intensity. The cation selectivity observed in aqueous media stands in contrast to what is seen in organic solvents, where a wide range of texaphyrin metal complexes may be prepared. The formation of metal cation complexes under the present aqueous conditions was confirmed by reversed phase high-performance liquid chromatography, ultra-violet-visible absorption and fluorescence spectroscopies, and high-resolution mass spectrometry.

Keywords: texaphyrin     fluorescent sensor     ion-sensing     indium     mercury    

Title Author Date Type Operation

Mercury enrichment in

Chunhao Dai, Pufeng Qin, Zhangwei Wang, Jian Chen, Xianshan Zhang, Si Luo

Journal Article

Mercury removal from flue gas using nitrate as an electron acceptor in a membrane biofilm reactor

Journal Article

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Journal Article

A review of atmospheric mercury emissions, pollution and control in China

Shuxiao WANG,Lei ZHANG,Long WANG,Qingru WU,Fengyang WANG,Jiming HAO

Journal Article

New insights into mercury removal mechanism on CeO

Ling Li, Yu He, Xia Lu

Journal Article

Removal of elemental mercury by KI-impregnated clay

Boxiong SHEN,Jianhong CHEN,Ji CAI

Journal Article

Biosorption of mercury and lead by aqueous

Pratibha SANJENBAM, Kumar SAURAV, Krishnan KANNABIRAN

Journal Article

Mercury removal and recovery by immobilized

Meifang CHIEN, Ryo NAKAHATA, Tetsuya ONO, Keisuke MIYAUCHI, Ginro ENDO

Journal Article

Source attribution for mercury deposition with an updated atmospheric mercury emission inventory in the

Jiajun Liu, Long Wang, Yun Zhu, Che-Jen Lin, Carey Jang, Shuxiao Wang, Jia Xing, Bin Yu, Hui Xu, Yuzhou Pan

Journal Article

Removal of elemental mercury with Mn/Mo/Ru/Al

Yongfu GUO, Naiqiang YAN, Ping LIU, Shijian YANG, Juan WANG, Zan QU

Journal Article

A density functional theory study of the adsorption of Hg and HgCl2 on a CaO(001) surface

GUO Xin, ZHENG Chuguang, LU Nanxia

Journal Article

Mercury emission and adsorption characteristics of fly ash in PC and CFB boilers

Li JIA, Baoguo FAN, Xianrong ZHENG, Xiaolei QIAO, Yuxing YAO, Rui ZHAO, Jinrong GUO, Yan JIN

Journal Article

Mercury removal from aqueous solution using petal-like MoS2

Ragini Pirarath, Palani Shivashanmugam, Asad Syed, Abdallah M. Elgorban, Sambandam Anandan, Muthupandian Ashokkumar

Journal Article

A Historical Sedimentary Record of Mercury in a Shallow Eutrophic Lake: Impacts of Human Activities and

Hanxiao Zhang, Shouliang Huo, Kevin M. Yeager, Beidou Xi, Jingtian Zhang,Fengchang Wu

Journal Article

Reduced texaphyrin: A ratiometric optical sensor for heavy metals in aqueous solution

Harrison D. Root, Gregory Thiabaud, Jonathan L. Sessler

Journal Article