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《中国工程科学》 >> 2019年 第21卷 第1期 doi: 10.15302/J-SSCAE-2019.01.004

中国高温气冷堆制氢发展战略研究

清华大学核能与新能源技术研究院先进核能技术协同创新中心,北京 100084

资助项目 :中国工程院咨询项目“新一代核能用材发展战略研究”(2016-ZD-06) 收稿日期: 2019-01-10 修回日期: 2019-01-18

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摘要

核能制氢是一种有应用前景的高效、大规模、无排放的制氢技术,有望在氢气大规模集中供应的场景中起到重要作用。高温气冷堆是最适于核能制氢的堆型,在我国已有几十年的研发基础,目前正在国家科技重大专项支持下建造高温气冷堆示范电站。本文介绍了核能制氢技术的特点和主流的核能制氢工艺包括热化学碘硫循环、混合硫循环和高温蒸汽电解的原理,对国际上核能制氢技术发展现状进行了简要综述,并概述了清华大学在该领域的研发现状。此外对核能制氢的安全性、技术经济评价等问题进行了讨论,在此基础上对与高温气冷堆耦合的制氢技术进行了评价,并以氢气直接还原炼铁为例探讨了高温气冷堆制氢在工业领域的应用前景。最后对我国高温气冷堆制氢技术的发展路线进行了探讨。

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参考文献

[ 1 ] Zhang Z Y, Wu Z X, Wang D Z. Current status and technical description of Chinese 2 × 250 MWth HTR-PM demonstration plant [J]. Nuclear Engineering Design, 2009, 239(7): 1212–1219. 链接1

[ 2 ] Forsberg C W. Hydrogen, nuclear energy and the advanced hightemperature reactor [J]. International Journal of Hydrogen Energy. 2003, 28(10): 1073–1081. 链接1

[ 3 ] International Atomic Energy Agency. Hydrogen as an energy carrier and its production by nuclear power [R]. Vienna: International Atomic Energy Agency, 1999.

[ 4 ] Funk J E. Thermochemical hydrogen production: Past and present [J]. International Journal of Hydrogen Energy, 2001, 26(3): 185– 190. 链接1

[ 5 ] O’Brien J A, Hinkley J T, Donne S W. Electrochemical oxidation of aqueous sulfur dioxide II. Comparative studies on platinum and gold electrodes [J]. Journal of the Electrochemical Society, 2012, 159(9): F585–F593. 链接1

[ 6 ] O’Brien J E, Herring J S, Stoots C M, et al. Progress in hightemperature electrolysis for hydrogen production using planar SOFC technology [J]. International Journal of Hydrogen Energy, 2007, 32(4): 440–450. 链接1

[ 7 ] Kasahara S, Iwastuki J, Takegami H, et al. Current R&D status of thermochemical water splitting iodine-sulfur process in Japan Atomic Energy Agency [J]. International Journal of Hydrogen Energy, 2017, 42(19): 13477–13485. 链接1

[ 8 ] Moore R, Parma E, Russ B. An integrated laboratory-scale experiment on the sulfur – Iodine thermochemical cycle for hydrogen production [R]. Washington, DC : Proceedings of HTR2008, 2008. 链接1

[ 9 ] Vitart X, Carles P, Anzieu P. A general survey of the potential and the main issues associated with the sulfur iodine thermochemical cycle for hydrogen production using nuclear heat [J]. Progress in Nuclear Energy, 2008, 50(2–6): 402–410.

[10] Lee B J, No H C, Yoon H J. Development of a flowsheet for iodine–sulfur thermo-chemical cycle based on optimized Bunsen reaction [J]. Internationgal Journal of Hydrogen Energy, 2009, 34(5): 2133–2143. 链接1

[11] Neterer G F, Suppiah S, Stolberg L, et al. Progress in thermochemical hydrogen production with the copperechlorine cycle [J]. International Journal of Hydrogen Energy, 2015, 40(19): 6283– 6295.

[12] El-Emam RS, Khamis I. Advances in nuclear hydrogen production: Results from an IAEA international collaborative research project [J]. International Journal of Hydrogen Energy, 2018, https://doi. org/10.1016/j.ijhydene.2018.04.012. 链接1

[13] Zhang P, Wang L J, Chen S, et al. Progress of nuclear hydrogen production through the iodine-sulfur process in China [J]. Renewable and Sustainable Energy Reviews, 2018 (18): 1802– 1812. 链接1

[14] Guo H F, Zhang P, Chen S Z, et al. Modeling and validation of the iodine-sulfur hydrogen production process [J]. AIChE Journal, 2014, 60(2): 546–558. 链接1

[15] 张平, 于波, 徐景明. 我国核能制氢技术的发展 [J]. 核化学与放 射化学, 2011, 33(4):193–203. Zhang P, Yu B, Xu J M. Development of the technology for nuclear production of hydrogen in China [J]. Nuclear and Radiochemistry, 2011, 33(4): 193–203.
Zhang P, Yu B, Xu J M. Development of the technology for nuclear production of hydrogen in China [J]. Nuclear and Radiochemistry, 2011, 33(4): 193–203. Chinese.

[16] Xue L, Zhang P, Chen S Z, et al. Quantitative analysis of the cell voltage of SO2-depolarized electrolysis in hybrid sulfur process [J]. Nuclear Engineering and Design, 2016, 306: 203–207. 链接1

[17] Sato H, Ohashi H, Nakagawa S, et al. Safety design consideration for HTGR coupling with hydrogen production plant [J]. Progress in Nuclear Energy, 2015 (82): 46–52. 链接1

[18] Allen D, Pickard P, Patterson M. NHI economic analysis of candidate nuclear hydrogen process [C]. Oakbrook: The fourth information exchange meeting of nuclear production of hydrogen, 2009. 链接1

[19] El-Emam RS, Ozcan H, Dincer I. Comparative cost evaluation of nuclear hydrogen production methods with the Hydrogen Economy Evaluation Program (HEEP) [J]. International Journal of Hydrogen Energy, 2015, 40(34): 11168–11177. 链接1

[20] Yan X, Kasahara S, Tachibana Y, et al. Study of a nuclear energy supplied steelmaking system for near-term application [J]. Energy, 2012 (39): 154–165. 链接1

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