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《中国工程科学》 >> 2014年 第16卷 第12期

智能高分子开关膜的制备方法研究进展

四川大学化学工程学院,成都 610065

资助项目 :国家自然科学基金项目(21276162);教育部新世纪优秀人才支持计划项目(NCET-11-0352) 收稿日期: 2014-09-16 发布日期: 2015-01-05 14:07:17.000

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摘要

智能高分子开关膜是将智能高分子与非刺激响应型基材膜结合而成。由于智能高分子能够响应外界刺激发生亲疏水性转变和构象变化,智能高分子开关膜也能根据外部刺激改变自身的表面/界面特性、渗透通量或选择透过性。智能高分子膜被用作抗污染滤膜、亲和分离、酶反应的起/停控制以及控制释放等。智能高分子开关膜的制备方法直接影响其环境刺激响应特性、稳定性和可重复制备性等。因此,系统介绍了基材膜修饰法、基材修饰成膜法和共混成膜法等3种智能高分子开关膜制备方法的定义、分类、机理和研究进展,并对比了3种方法的优缺点。基材膜修饰法研究最多,而共混成膜法最有望用于大规模制备智能高分子膜。本文以期为高效制备具有稳定、优良响应特性的智能高分子开关膜提供指导和参考。

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