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Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomic

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

《化学科学与工程前沿（英文）》 2012年第6卷第4期页码 432-435 doi: 10.1007/s11705-012-1219-z

摘要： In the present work, a new preconcentration method of trace elements by adsorption onto a niobium wire has been developed for electrothermal atomization atomic absorption spectrometry (ETAAS) with a tungsten tube atomizer. Detection limits (pg·mL ) by this method combined with ETAAS were 45 for bismuth, 7.0 for cadmium, 20 for copper, 1.3 for gold, 36 for lead, 65 for manganese, 9.5 for rhodium and 19 for silver.

关键词： preconcentration adsorption onto niobium wire electrothermal atomization atomic absorption spectrometry tungsten tube atomizer trace elements

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Determination of aniline derivatives in water samples after preconcentration with oxidized multiwalled

Hideyuki KATSUMATA, Yuta ODA, Satoshi KANECO, Tohru SUZUKI, Kiyohisa OHTA

《化学科学与工程前沿（英文）》 2012年第6卷第3期页码 270-275 doi: 10.1007/s11705-012-1298-x

摘要： A sensitive and selective preconcentration method using solid-phase extraction (SPE) disk made from oxidized multiwalled carbon nanotubes (OMWCNTs), has been developed for the determination of aniline derivatives, such as 2-nitroaniline (2-NA), 4-nitroaniline (4-NA), and 2,4-dichloroaniline (2,4-DCA) in water samples. Anilines were extracted onto OMWCNT disk and then determined by high performance liquid chromatography (HPLC) with UV detector. Several parameters on the recovery of the analytes were investigated. The experimental results showed that it was possible to obtain quantitative analysis when the solution pH was 8 using 200 mL of validation solution containing 2 μg of anilines and 10 mL of acetonitrile/ethanol (8/2, v/v) as an eluent. Relative standard deviations for five determinations were 7.5% (2-NA), 6.5% (4-NA) and 3.8% (2,4-DCA) under optimum conditions. The linear range of calibration curves were 0.5 ng·mL to 15 ng·mL for each analyte with good correlation coefficients. The detection limits (3S/N) of 2-NA, 4-NA and 2,4-DCA were 30 pg·mL , 31 pg·mL and 26 pg·mL , respectively. Our method was successfully applied to the determination of aniline compounds in river water sample with high precision and accuracy.

关键词： aniline determination solid-phase extraction oxidized multiwalled carbon nanotubes water sample HPLC-UV

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Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples

Qingyun CHANG, Jingwen ZHANG, Xin DU, Jingjun MA, Jingci LI,

《环境科学与工程前沿（英文）》 2010年第4卷第2期页码 187-195 doi: 10.1007/s11783-010-0030-7

摘要： A simple and efficient liquid-phase microextraction (LPME) technique was developed using ultrasound-assisted emulsification solidified floating organic drop microextraction (USAE-SFODME) combined with flame atomic absorption spectrometry, for the extraction and determination of trace copper in water samples. 1-(2-Pyridylazo)-2-naphthol (PAN) was used as chelating agent. Microextraction efficiency factors (including extraction solvent type, extraction volume, time, temperature, and pH), the amount of the chelating agent, and salt effect were investigated and optimized. Under the optimum extraction conditions, figures of merit of the proposed method were evaluated. The calibration graph was linear in the range of 20–600 g·L with a detection limit of 0.76 g·L. The relative standard deviation (R.S.D) for ten replicate measurements of 20 and 400 g·L of copper was 3.83% and 2.65%, respectively. Finally, the proposed method was applied to tap water, river water, and sea water, and accuracy was assessed through the analysis of certified reference water or recovery experiments.

关键词： ultrasound-assisted emulsification solidified floating organic drop microextraction flame atomic absorption spectrometry preconcentration copper