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Frontiers of Chemical Science and Engineering >> 2018, Volume 12, Issue 3 doi: 10.1007/s11705-018-1743-6
Crystal-to-crystal transformation from the triclinic to the cubic crystal system by partial desolvation
Abstract
Diffusion reaction of the labile building block Mg(acacCN)2 (acacCN= 3-cyanoacetylacetonate) with silver salts leads to a series of solvated Mg/Ag bimetallic coordination polymers with composition [Mg(acacCN)3Ag]·solvent. Despite their common stoichiometry, the topology of these polymers depends on the solvent of crystallization. The two-dimensional coordination compound [Mg(acacCN)3Ag]·4CHCl3 in space group P
Keywords
ditopic ligand ; substituted acetylacetone ; desolvation ; diffraction
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