无法对工业过程大量存在的复杂液体在线实时监测导致资源消耗和污染产生过多的现象十分普遍。本文介绍一种对高强包裹性和高盐多组分液体中目标物质进行非接触原态在线实时监测的方法，该方法的原理是建立液体中目标物质浓度（C）、不同浓度目标物质色空间坐标(L*, a*, b*) 和最大吸收波长（λmax）三者之间的关系，利用最佳波长λT下高精度扫描式检测系统表达的液体光强信息直接测定流动液体中目标物质的瞬时浓度。与传统分析方法和现有在线分析方法不同，这种方法无需对样品进行任何预处理（过滤、稀释、定容、氧化/还原、添加显色剂等），可实现测试样品的原态化在线实时监测。将一家大型电解锰企业陈化液（Fe3+浓度0.5~18 mg•L-1， 锰离子35~39 g•L-1，硫酸铵90~110 g•L-1）胶体化过程中三价铁离子浓度的实测结果与离线实验室测试结果相比，二者相对误差小于2%。

Failures are very common during the online real-time monitoring of large quantities of complex liquids in industrial processes, and can result in excessive resource consumption and pollution. In this study, we introduce a monitoring method capable of non-contact original-state online real-time monitoring for strongly coated, high-salinity, and multi-component liquids. The principle of the method is to establish the relationship among the concentration of the target substance in the liquid (C), the color space coordinates of the target substance at different concentrations (L*, a*, b*), and the maximum absorption wavelength (λ_max); subsequently, the optimum wavelength λ_T of the liquid is determined by a high-precision scanning-type monitoring system that is used to detect the instantaneous concentration of the target substance in the flowing liquid. Unlike traditional monitoring methods and existing online monitoring methods, the proposed method does not require any pretreatment of the samples (i.e., filtration, dilution, oxidation/reduction, addition of chromogenic agent, constant volume, etc.), and it is capable of originalstate online real-time monitoring. This method is employed at a large electrolytic manganese plant to monitor the Fe³⁺ concentration in the colloidal process of the plant's aging liquid (where the concentrations of Fe³⁺, Mn²⁺, and (NH₄)2SO₄are 0.5–18 mg·L1, 35–39 g·L1, and 90–110 g·L1, respectively). The relative error of this monitoring method compared with an off-line laboratory monitoring is less than 2%.