下一代锂电池在能源化学工程方面的研究进展

工程（英文） ›› 2018, Vol. 4 ›› Issue (6) : 831-847.

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工程（英文） ›› 2018, Vol. 4 ›› Issue (6) : 831-847. DOI: 10.1016/j.eng.2018.10.008
研究论文
Research Green Chemical Engineering—Review

下一代锂电池在能源化学工程方面的研究进展

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Recent Advances in Energy Chemical Engineering of Next-Generation Lithium Batteries

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Abstract

Rechargeable lithium-ion batteries (LIBs) afford a profound impact on our modern daily life. However, LIBs are approaching the theoretical energy density, due to the inherent limitations of intercalation chemistry; thus, they cannot further satisfy the increasing demands of portable electronics, electric vehicles, and grids. Therefore, battery chemistries beyond LIBs are being widely investigated. Next-generation lithium (Li) batteries, which employ Li metal as the anode and intercalation or conversion materials as the cathode, receive the most intensive interest due to their high energy density and excellent potential for commercialization. Moreover, significant progress has been achieved in Li batteries attributed to the increasing fundamental understanding of the materials and reactions, as well as to technological improvement. This review starts by summarizing the electrolytes for next-generation Li batteries. Key challenges and recent progress in lithium-ion, lithium–sulfur, and lithium–oxygen batteries are then reviewed from the perspective of energy and chemical engineering science. Finally, possible directions for further development in Li batteries are presented. Next-generation Li batteries are expected to promote the sustainable development of human civilization.

Keywords

Lithium-ion batteries / Lithium–sulfur batteries / Lithium–oxygen batteries / Lithium metal / Solid-state batteries / Battery chemistry / Electrolyte

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. . Engineering. 2018, 4(6): 831-847 https://doi.org/10.1016/j.eng.2018.10.008

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Acknowledgements

This work was supported by the National Key Research and Development Program (2016YFA0202500 and 2016YFA0200102), the National Natural Science Foundation of China (21676160, 21776019, and 21825501), and the Tsinghua University Initiative Scientific Research Program. We thank Bo-Quan Li, Xin-Bing Cheng, Hong-Jie Peng, Xiang Chen, and Chong Yan for helpful discussion.
Compliance with ethics guidelines

Xue-Qiang Zhang, Chen-Zi Zhao, Jia-Qi Huang, and Qiang Zhang declare that they have no conflict of interest or financial conflicts to disclose.

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