
Al-NaOH复合液态金属——一种具有热和气动特性且快速响应的水触发材料
Bo Yuan, Xuyang Sun, Jing Liu
工程(英文) ›› 2020, Vol. 6 ›› Issue (12) : 1454-1462.
Al-NaOH复合液态金属——一种具有热和气动特性且快速响应的水触发材料
Al-NaOH-Composited Liquid Metal: A Fast-Response Water-Triggered Material with Thermal and Pneumatic Properties
水触发材料因其操作简单、驱动柔和、成本低廉、环境友好等诸多优点受到越来越多的关注。但是,大多数此类材料通常具有较长的反应时间,并且需要严格的保存条件,这限制了它们在实践中的适应性。本研究提出并证明了一种基于Al-NaOH复合共晶镓-铟(eGaIn)合金的新型水触发材料,该材料具有快速响应性和可变形性。一旦加入水,制成的材料将在短短几秒钟内随着气体的产生而升温40 ℃,这表明它具有用作热驱动器和气动驱动器的巨大潜力。此外,研究还测试了新材料的可重复使用性和降解能力。并据此设计了双层结构的智能绷带,其内部填充了Al-NaOH复合eGaIn,而BiInSn则作为外部支撑材料。实验显示,厚度为2 mm的片状结构经过冷却处理后能够支撑1.8 kg的重物,这比常用的玻璃纤维高分子绷带的承重能力要好得多。同时,研究还使用Al-NaOH复合eGaIn制作了水触发球形机器人的原型,该原型在特定的外部刺激下实现了滚动和弹跳行为。这些发现表明,当前材料在开发未来的可穿戴设备、软驱动器和软机器人方面具有潜在价值。
Water-triggered materials are receiving increasing attentions due to their diverse capabilities such as easy operation, soft actuation, low cost, environmental friendliness, and many more other advantages. However, most of such materials generally have a long reaction time and require strict preservation conditions, which limit their adaptability in practice. In this study, a novel water-triggered material based on Al-NaOH-composited eutectic gallium–indium alloys (eGaIn) was proposed and demonstrated, which is rather fast-responsive and deformable. Once water is applied, the material thus fabricated would achieve a temperature rise of 40 °C in just several seconds along with gas production, indicating its big potential to be used as a thermal and pneumatic actuator. Further, the new material's reusability and degradation ability were also tested. Following that, a double-layer-structure smart bandage was designed, whose bulk was filled with Al-NaOH-composited eGaIn while BiInSn served as outer supporting material. According to the experiments, a sheet structure with a thickness of 2 mm would support a weight of 1.8 kg after it was subjected to a cooling process, which is much better than the weight-bearing capability of fiberglass. In addition, a prototype of a water-triggered sphere robot was also fabricated using Al-NaOH-eGaIn, which realized rolling and bouncing behaviors under specific external stimulation. These findings indicate the potential value of the present material in developing future wearable devices, soft actuators, and soft robotics.
Liquid metal / Water-triggered materials / Self-heating materials / Soft actuator
[1] |
Huang Y, Cheng H, Shi G, Qu L. Highly efficient moisture-triggered nanogenerator based on graphene quantum dots. ACS Appl Mater Interfaces 2017;9(44):38170–5.
|
[2] |
Gao Y, Zhang Y, Wang X, Sim K, Liu J, Chen J, et al. Moisture-triggered physically transient electronics. Sci Adv 2017;3(9):e1701222.
|
[3] |
Cheng H, Liu J, Zhao Y, Hu C, Zhang Z, Chen N, et al. Graphene fibers with predetermined deformation as moisture-triggered actuators and robots. Angew Chem Int Ed Engl 2013;52(40):10482–6.
|
[4] |
Jiang ZC, Xiao YY, Kang Y, Li BJ, Zhang S. Semi-IPNs with moisture-triggered shape memory and self-healing properties. Macromol Rapid Commun 2017;38 (14):1700149.
|
[5] |
Wang W, Xiang C, Liu Q, Li M, Zhong W, Yan K, et al. Natural alginate fiberbased actuator driven by water or moisture for energy harvesting and smart controller applications. J Mater Chem A Mater Energy Sustain 2018;6 (45):22599–608.
|
[6] |
Cheng H, Hu Y, Zhao F, Dong Z, Wang Y, Chen N, et al. Moisture-activated torsional graphene-fiber motor. Adv Mater 2014;26(18):2909–13.
|
[7] |
Yang B, Huang WM, Li C, Lee CM, Li L. On the effects of moisture in a polyurethane shape memory polymer. Smart Mater Struct 2003;13(1): 191–5.
|
[8] |
Gu X, Mather PT. Water-triggered shape memory of multiblock thermoplastic polyurethanes (TPUs). RSC Adv 2013;3(36):15783–91.
|
[9] |
Fassler A, Majidi C. Liquid-phase metal inclusions for a conductive polymer composite. Adv Mater 2015;27(11):1928–32.
|
[10] |
Yu YZ, Lu JR, Liu J. 3D printing for functional electronics by injection and package of liquid metals into channels of mechanical structures. Mater Des 2017;122:80–9.
|
[11] |
Yang XH, Liu J. Liquid metal enabled combinatorial heat transfer science: toward unconventional extreme cooling. Front Energy 2018;12(2): 259–75.
|
[12] |
Chu K, Song BG, Yang HI, Kim DM, Lee CS, Park M, et al. Smart passivation materials with a liquid metal microcapsule as self-healing conductors for sustainable and flexible perovskite solar cells. Adv Funct Mater 2018;28 (22):1800110.
|
[13] |
Gao Y, Li H, Liu J. Direct writing of flexible electronics through room temperature liquid metal ink. PLoS ONE 2012;7(9):e45485.
|
[14] |
Zheng Y, He ZZ, Yang J, Liu J. Personal electronics printing via tapping mode composite liquid metal ink delivery and adhesion mechanism. Sci Rep 2014;4 (1):1–8.
|
[15] |
Nathan A, Ahnood A, Cole MT, Lee S, Suzuki Y, Hiralal P, et al. Flexible electronics: the next ubiquitous platform. Proc IEEE 2012;100(Special Centennial Issue):1486–517.
|
[16] |
Chang H, Guo R, Sun Z, Wang H, Hou Y, Wang Q, et al. Direct writing and repairable paper flexible electronics using nickel–liquid metal ink. Adv Mater Interfaces 2018;5(20):1800571.
|
[17] |
Tang J, Zhao X, Li J, Zhou Y, Liu J. Liquid metal phagocytosis: intermetallic wetting induced particle internalization. Adv Sci 2017;4(5): 1700024.
|
[18] |
Wang H, Yuan B, Liang S, Guo R, Rao W, Wang X, et al. PLUS-M: a porous liquid–metal enabled ubiquitous soft material. Mater Horiz 2018;5(2): 222–9.
|
[19] |
Zhang J, Yao Y, Sheng L, Liu J. Self-fueled biomimetic liquid metal mollusk. Adv Mater 2015;27(16):2648–55.
|
[20] |
Xu S, Zhao X, Liu J. Liquid metal activated aluminum–water reaction for direct hydrogen generation at room temperature. Renew Sustain Energy Rev 2018;92:17–37.
|
[21] |
Ghasemian M, Mayyas M, Idrus-Saidi S, Jamal MA, Yang J, Mofarah SS, et al. Self-limiting galvanic growth of MnO2 monolayers on a liquid metal—applied to photocatalysis. Adv Funct Mater 2019;29(36):1901649.
|
[22] |
Zavabeti A, Zhang B, De Castro I, Ou JZ, Carey BJ, Mohiuddin M, et al. Green synthesis of low-dimensional aluminum oxide hydroxide and oxide using liquid metal reaction media: ultrahigh flux membranes. Adv Funct Mater 2018;28(44):1804057.
|
[23] |
Wang X, Guo R, Liu J. Liquid metal based soft robotics: materials, designs, and applications. Adv Mater Technol 2019;4(2):1800549.
|
[24] |
Huang X, Gao T, Pan X, Wei D, Lv C, Qin L, et al. A review: feasibility of hydrogen generation from the reaction between aluminum and water for fuel cell applications. J Power Sources 2013;229:133–40.
|
/
〈 |
|
〉 |