基于一维纳米结构阵列的质子交换膜燃料电池电极设计的研究进展

杜尚峰

工程(英文) ›› 2021, Vol. 7 ›› Issue (1) : 33 -49.

PDF (10365KB)
工程(英文) ›› 2021, Vol. 7 ›› Issue (1) : 33 -49. DOI: 10.1016/j.eng.2020.09.014
研究论文

基于一维纳米结构阵列的质子交换膜燃料电池电极设计的研究进展

作者信息 +

Recent Advances in Electrode Design Based on One-Dimensional Nanostructure Arrays for Proton Exchange Membrane Fuel Cell Applications

Author information +
文章历史 +
PDF (10613K)

摘要

一维(1D)铂基电催化剂对氧还原反应(ORR)展现出了良好的催化活性和稳定性。基于一维铂基纳米结构阵列的三维(3D)有序电极的研究进展表明,它们在解决现有铂/碳(Pt/C)纳米颗粒电极在高性能质子交换膜燃料电池(PEMFC)的传质特性和持久性挑战方面具有巨大的潜力。本文综述了该领域的最新进展,重点介绍了基于独立的铂纳米线阵列的三维有序结构电极,讨论了纳米结构薄膜(NSTF)催化剂以及沉积在聚合物纳米线、碳和二氧化钛纳米管阵列上的铂基纳米颗粒电极,并回顾了铂基纳米管阵列电极的研究进展。本文指出了一维催化剂纳米结构的尺寸、表面性质和分配控制的重要性。最后,讨论了一维纳米结构阵列电极在增大电化学比表面积(ECSA)和氧传质阻力定量研究方面面临的挑战和未来的发展机遇。

Abstract

One-dimensional (1D) Pt-based electrocatalysts demonstrate outstanding catalytic activities and stability toward the oxygen reduction reaction (ORR). Advances in three-dimensional (3D) ordered electrodes based on 1D Pt-based nanostructure arrays have revealed great potential for developing highperformance proton exchange membrane fuel cells (PEMFCs), in particular for addressing the mass transfer and durability challenges of Pt/C nanoparticle electrodes. This paper reviews recent progress in the field, with a focus on the 3D ordered electrodes based on self-standing Pt nanowire arrays. Nanostructured thin-film (NSTF) catalysts are discussed along with electrodes made from Pt-based nanoparticles deposited on arrays of polymer nanowires, and carbon and TiO2 nanotubes. Achievements on electrodes from Pt-based nanotube arrays are also reviewed. The importance of size, surface properties, and the distribution control of 1D catalyst nanostructures is indicated. Finally, challenges and future development opportunities are addressed regarding increasing electrochemical surface area (ECSA) and quantifying oxygen mass transport resistance for 1D nanostructure array electrodes.

关键词

质子交换膜燃料电池(PEMFC) / 电极 / 一维(1D) / 氧还原反应(ORR) / 催化剂 / 有序化

Key words

Proton exchange membrane fuel cell (PEMFC) / Electrode / One-dimensional (1D) / Oxygen reduction reaction (ORR) / Catalyst / Ordered

引用本文

引用格式 ▾
杜尚峰 基于一维纳米结构阵列的质子交换膜燃料电池电极设计的研究进展[J]. 工程(英文), 2021, 7(1): 33-49 DOI:10.1016/j.eng.2020.09.014

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

基金资助

()

AI Summary AI Mindmap
PDF (10365KB)

1831

访问

0

被引

详细

导航
相关文章

AI思维导图

/