钠超离子导体型固体电解质的改性及其在钠离子电池中的应用

张强强; 周权; 陆雅翔; 邵元骏; 戚钰若; 戚兴国; 钟贵明; 杨勇; 陈立泉; 胡勇胜

doi:10.1016/j.eng.2021.04.028

工程（英文） ›› 2022, Vol. 8 ›› Issue (1) : 170 -180. DOI: 10.1016/j.eng.2021.04.028

钠超离子导体型固体电解质的改性及其在钠离子电池中的应用

张强强 ^a^,^b^,^* ,
周权 ^a^,^b^,^e^,^* ,
陆雅翔 ^a^,^f ,
邵元骏 ^a^,^b ,
戚钰若 ^a^,^b ,
戚兴国 ^e ,
钟贵明 ^c ,
杨勇 ^d ,
陈立泉 ^a^,^b ,
胡勇胜 ^a^,^b^,^e

作者信息 +

Modification of NASICON Electrolyte and Its Application in Real Na-Ion Cells

Qiangqiang Zhang ^a^,^b^,^* ,
Quan Zhou ^a^,^b^,^e^,^* ,
Yaxiang Lu ^a^,^f ,
Yuanjun Shao ^a^,^b ,
Yuruo Qi ^a^,^b ,
Xingguo Qi ^e ,
Guiming Zhong ^c ,
Yong Yang ^d ,
Liquan Chen ^a^,^b ,
Yong-Sheng Hu ^a^,^b^,^e

Author information +

文章历史 +

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摘要

固体电解质的低离子电导率及固体电解质与固态电极之间较差的界面可靠性是阻碍固态钠电池（SSSB）应用的两大紧迫挑战。本文采用简单的两步固相法合成了名义成分为Na_3+2xZr_2‒xMg_xSi₂PO₁₂ 的钠（Na）超离子导体（NASICON）型固体电解质，其中在25 ℃时Na_3.3Zr_1.85Mg_0.15Si₂PO₁₂（x=0.15, NZSP-Mg_0.15)表现出了3.54 mS∙cm^‒1的最高离子电导率。通过深入研究，本文证实晶界成分在决定NASICON总离子电导率中起着至关重要的作用。此外，由于文献中缺乏关于NASICON是否能够提供足够的阳极电化学稳定性来实现高压固态钠电池的研究，我们首先使用了高压Na₃(VOPO₄)₂F (NVOPF)正极来验证其与优化后的NZSP-Mg_0.15固体电解质之间的兼容性。通过比较不同配置（低压阴极与高压阴极、液态电解质与固体电解质）电池的电化学性能，以及对循环后的NZSP-Mg_0.15进行X射线光电子能谱（XPS）评估，结果表明，NASICON固体电解质在高电压下不够稳定，这证明了研究NASICON固体电解质和高压阴极之间界面的重要性。此外，通过将NZSP-Mg_0.15 NASICON 粉末涂在聚乙烯（PE）隔膜（PE@NASICON）上，形成了2.42 A∙h 的碳|PE@NASICON|NaNi_2/9Cu_1/9Fe_1/3Mn_1/3O₂ 非水系钠离子电池，其具有出色的循环性能，在2000 周循环后容量保持率为88%，从而证明涂有NASICON型固体电解质的隔膜具有高可靠性。

Abstract

The low ionic conductivity of solid-state electrolytes (SSEs) and the inferior interfacial reliability between SSEs and solid-state electrodes are two urgent challenges hindering the application of solid-state sodium batteries (SSSBs). Herein, sodium (Na) super ionic conductor (NASICON)-type SSEs with a nominal composition of Na₃₊₂_xZr_2–_xMg_xSi₂PO₁₂ were synthesized using a facile two-step solid-state method, among which Na_3.3Zr_1.85Mg_0.15Si₂PO₁₂ (x = 0.15, NZSP-Mg_0.15) showed the highest ionic conductivity of 3.54 mS∙cm^–1 at 25 °C. By means of a thorough investigation, it was verified that the composition of the grain boundary plays a crucial role in determining the total ionic conductivity of NASICON. Furthermore, due to a lack of examination in the literature regarding whether NASICON can provide enough anodic electrochemical stability to enable high-voltage SSSBs, we first adopted a high-voltage Na₃(VOPO₄)₂F (NVOPF) cathode to verify its compatibility with the optimized NZSP-Mg_0.15 SSE. By comparing the electrochemical performance of cells with different configurations (low-voltage cathode vs high-voltage cathode, liquid electrolytes vs SSEs), along with an X-ray photoelectron spectroscopy (XPS) evaluation of the after-cycled NZSP-Mg_0.15, it was demonstrated that the NASICON SSEs are not stable enough under high voltage, suggesting the importance of investigating the interface between the NASICON SSEs and high-voltage cathodes. Furthermore, by coating NZSP-Mg_0.15 NASICON powder onto a polyethylene (PE) separator (PE@NASICON), a 2.42 A∙h non-aqueous Na-ion cell of carbon|PE@NASICON|NaNi_2/9Cu_1/9Fe_1/3Mn_1/3O₂ was found to deliver an excellent cycling performance with an 88% capacity retention after 2000 cycles, thereby demonstrating the high reliability of a separator coated with NASICON-type SSEs.

关键词

固态电解质 / 固态钠电池 / NASICON / 界面 / 隔膜 / 涂层

Key words

Solid-state electrolytes / Solid-state sodium batteries / NASICON / Interface / Separator / Coating

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张强强,周权,陆雅翔,邵元骏,戚钰若,戚兴国,钟贵明,杨勇,陈立泉,胡勇胜. 钠超离子导体型固体电解质的改性及其在钠离子电池中的应用[J]. 工程（英文）, 2022, 8(1): 170-180 DOI:10.1016/j.eng.2021.04.028

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1. 引言

丰富且低成本的钠（Na）资源为推广钠离子电池（NIB）作为大型储能系统的候选电池提供了一个令人信服的理由[1‒9]。基于固体电解质的固态钠电池（SSSB）不使用易燃的液态电解质（LE），具有更高的安全性，从而引起了人们极大的兴趣[10‒13]。然而，在固态钠电池实际应用之前，仍有两个主要挑战有待解决，即固体电解质的低离子电导率及固体电解质与固态电极之间较差的界面可靠性[10,11,14‒18]。

1976年，Goodenough等[19]和对钠超离子导体（NASICON）型Na⁺固体电解质、Na₁₊Zr₂P_3‒SiO₁₂（0<x<3）进行了开创性的研究。这项工作表明，该材料具有开放的三维（3D）通道，允许Na⁺快速传输，因此表现出相当高的电导率。NASICON型固体电解质的刚性3D共价网络由共角的PO₄四面体、SiO₄四面体和ZrO₆八面体组成；每个八面体连接六个四面体，每个四面体连接四个八面体，Na⁺位于网络结构的间隙位点。此外，在1.8≤x≤2.2的范围内，NASICON表现为具有C2/c空间群的单斜晶系结构，而在剩余x值处为具有R-3c空间群的菱面体结构[19‒20]。特别是最有前景的NASICON型固体电解质单斜晶体Na₃Zr₂Si₂PO₁₂，在室温下表现出最高的Na⁺电导率，其值为0.67 mS∙cm^‒1 [10,14,17,21‒22]。为了进一步提高NASICON型固体电解质的离子电导率，除了传统的固相法外[23]，本文还采用了多种烧结技术，如溶液辅助固相反应[24]、放电等离子体烧结[25]、溶胶-凝胶法[26]和添加剂辅助固相工艺[27]，这些方法都显著提高了离子电导率。即便如此，固相法仍是最简便的工艺。除了优化合成过程之外，掺杂外来元素是一种非常有效的方法。Zhang等[26]通过引入La³⁺开发了一种名义成分为Na_3.3Zr_1.7La_0.3Si₂PO₁₂自成型复合NASICON电解质，从而在25 ℃下将Na⁺电导率显著提升至3.4 mS∙cm^‒1。然而，镧（La）是一种昂贵的稀土元素，会大大增加固态钠电池成本[28‒29]。因此迫切需要使用含量丰富且具有成本效益的元素来开发可以达到高离子电导率水平的固态钠电池。

尽管NASICON的离子电导率仍低于有机液态电解质（LE），但1 mS∙cm^‒1的量级足以保证固态钠电池在室温下稳定运行。因此，提高固体电解质与固态电极之间界面的可靠性变得越来越重要[30]。已经开发了几种界面工程方法来减轻钠金属和NASICON之间的阻抗，例如，添加液态电解质[31‒32]、插入原位化学形成的界面相（interphase）[33]、插入聚合物电解质[33]、使用复合阳极[34]、使用3D钠金属阳极[35]和化学镀层[35‒37]以及增加单轴压强[38]。此外，为了降低阴极与NASICON之间的电阻，已经提出了各种界面优化工艺，包括共烧结[39‒40]、添加液态电解质[28,31‒32,35‒36,41]、引入塑晶电解质[42]、添加离子液体[23,26]、插入固态聚合物电解质[33]、与固态聚合物电解质混合[35,43]、使用薄膜阴极[44‒45]以及使用3D阴极[24]。上述所有固态钠电池均采用低平均电压阴极，如Na₃V₂(PO₄)₃[23‒24,26,35‒36,39‒42]、S [31‒32]、NaTi₂(PO₄)₃ [33]、Na₂MnFe(CN)₆ [43]、Na_0.9Cu_0.22Fe_0.3Mn_0.48O₂ [28]或NaCoO₂ [44‒45]，但是测量其阳极电化学稳定性时，电压值几乎都超过了5 V [28,31,33,35,41]。值得注意的是，低平均电压阴极无法体现固态钠电池的高电压优势，也无法验证基于NASICON的高压固态钠电池的可行性。因此，有必要使用高压阴极来评估NASICON在高电位下的可靠性。

层状过渡金属（transition metal, TM）氧化物是钠离子电池中研究最多的阴极之一；然而，仍然存在诸多问题，制约着NIB性能的进一步提升。其中一个问题是锰（Mn）等过渡金属元素的溶解，由于变价过渡金属元素减少，导致阴极晶体结构损坏和容量衰减[46]。此外，溶解的过渡金属阳离子可能会迁移并沉积在阳极上，从而破坏固体电解质相界面（SEI）的组成，并导致NIB性能下降[47]。使用具有涂层的功能性聚合物隔膜被认为是抑制TM溶解的有效策略。最近，Yan等[48]在聚乙烯（PE）隔膜上涂覆了紧凑的NASICON型Li_1.5Al_0.5Ti_1.5(PO₄)₃ (LATP)固体电解质层，有效抑制了过渡金属从LiCoO₂和LiMn₂O₄阴极溶解以及沉积在阳极上。此外，在聚丙烯（PP）和（或）PE隔膜上涂覆固体电解质层可以显著提高隔膜对液体电解质的润湿性，从而降低电池的内阻，有利于电池的容量释放，提高电池的倍率性能[49]。

在本文中，我们将储量丰富且成本低廉的元素镁（Mg），通过简单的固相方法引入NASICON，使得离子电导率显著提高，主要来自晶界的贡献。采用最佳名义成分Na_3.3Zr_1.85Mg_0.15Si₂PO₁₂ (NZSP-Mg_0.15)，在25 ℃时可实现3.54 mS∙cm^‒1的高电导率；据我们所知，这是所有掺杂Mg的NASICON电解质的最高值。基于NZSP-Mg_0.15，采用高压Na₃(VOPO₄)₂F (NVOPF)阴极和金属Na阳极构建了固态钠电池。为了提高电极/电解质的界面相容性，在阴极侧添加了大约5 μL∙cm^‒2的液体电解质，并将碳纳米管（CNT）与钠金属阳极集成在一起。通过比较NVOPF|LE|NZSP-Mg_0.15|Na固态钠电池与NVOPF|LE|Na电池和Na₃V₂(PO₄)₃ (NVP)|LE|NZSP-Mg_0.15|Na电池的电化学性能，发现其阴极侧界面不够稳定。此外，循环后NZSP-Mg_0.15颗粒的X射线光电子能谱（XPS）分析结果表明NZSP-Mg_0.15的价态升高。因此，我们的研究展示了未来研究NASICON固体电解质与高压阴极之间界面的重要性。

此外，我们制备了千克级NZSP-Mg_0.15 NASICON粉末，并在细化颗粒后将其涂覆在PE隔膜（PE@NASICON）上，利用PE隔膜制备了2.42 A∙h的碳|PE@NASICON|NaNi_2/9Cu_1/9Fe_1/3Mn_1/3O₂非水系钠离子电池，其在1 C下经过2000周循环后具有容量保持率为88%的优异性能，从而证明了涂有NASICON型固体电解质隔膜的高可靠性和稳定性。

2. 材料和方法

2.1. 材料

试剂包括碳酸钠（Na₂CO₃, 99.95%, Acros Organics，美国）、二氧化锆[ZrO₂, 99.99%，上海阿拉丁生化科技有限公司（以下简称Aladdin）]、二氧化硅[SiO₂, 99.9%，美国Alfa Aesar（以下简称Alfa）]、磷酸二氢铵（NH₄H₂PO₄, 99%, Aladdin）、氧化镁（MgO, 99%, Alfa）、水合硫酸氧钒（VOSO₄ xH₂O, 99.9%, Alfa）、二水合磷酸二氢钠（NaH₂PO₄ 2H₂O, 99%，美国Sigma-Aldrich）、氟化钠（NaF, 99.99%, Aladdin）、氧化钒（V₂O₃, 99.7%, Alfa）、蔗糖（Alfa）、硬碳（中科海钠科技有限责任公司）和NaNi_2/9Cu_1/9Fe_1/3Mn_1/3O₂（NNCFM，中科海钠科技有限责任公司），按原样使用，未进行进一步处理。

2.2. NASICON陶瓷颗粒的制备

如先前工作所述[23]，我们使用传统的两步固相方法合成名义成分为Na₃₊₂Zr_2‒MgSi₂PO₁₂（x = 0, 0.05, 0.10, 0.15, 0.20）的材料，并将其烧结成陶瓷颗粒。在典型的合成中，在化学计量比下，Na₂CO₃、ZrO₂、SiO₂、NH₄H₂PO₄和MgO在行星式球磨机（PM 400, Retsch GmbH，德国）中以400 r min^-1的速度球磨12 h。将所制备的混合物在1000 ℃空气中烧结10 h。在与上述相同的条件下进一步球磨烧结产物。将得到的粉末压制成直径15 mm的陶瓷片；随后在1200 ℃下进行20 h的最终烧结，此时陶瓷片被母粉覆盖。

2.3. NVOPF和NVP@C的合成

如之前报道[50]，我们使用了一种简便的低温水热策略来合成NVOPF。简而言之，将所有VOSO₄ xH₂O、NaH₂PO₄ 2H₂O和NaF的原料溶解在去离子水中形成均匀溶液，其中，V:P:F的总摩尔比为1:3:1.7。然后将均匀溶液转移到聚四氟乙烯（PTFE）衬里的不锈钢高压釜中，并在120 ℃下保持10 h。反应结束后，通过离心收集反应产物，并将其用蒸馏水充分洗涤，然后在120 ℃下干燥10 h，得到最终产物。合成后的NVOPF具有单相[附录A中的图S1（a）]和纳米级形态[附录A中的图S1（b）]。此外，透射电子显微镜（TEM）图像中（103）平面的晶格条纹[附录A中的图S1（c）]和XPS光谱中钒（V）元素的结合能[附录A中的图S1（d）]进一步证明了所制备NVOPF阴极的组成。根据我们之前的方法[51]，用一步固相法制备了NVP。简而言之，将含有V₂O₃（10 mmol）、NaH₂PO₄ 2H₂O（30 mmol）和蔗糖（1 g）的前驱体在行星式球磨机（PM 400）中以400 r min^-1速度球磨12 h，然后将混合物置于900 ℃下氩气（Ar）氛围中烧结24 h。图1、图2分别展示了合成的NVP阴极的X射线粉末衍射（XRD）谱图和扫描电子显微镜（SEM）图像。附录A中的图S2（a）、（b）显示了其具有纳米级形态的纯相。

图1 （a）名义成分为Na₃₊₂_xZr_2‒_xMg_xSi₂PO₁₂（x = 0, 0.05, 0.10, 0.15, 0.20）样品的XRD图谱，对应于NZSP-Mg₀、NZSP-Mg_0.05和NZSP-Mg_0.10；（b）18.5°~20.0°的放大；（c）27.0°~28.0°的放大。

图2 NZSP-Mg₀、NZSP-Mg_0.05、NZSP-Mg_0.10、NZSP-Mg_0.15和NZSP-Mg_0.20样品的固态³¹P NMR光谱。

2.4. 材料表征

我们使用配备了铜（Cu）K_α辐射（λ=1.5405 Å）的D8 ADVANCE X射线衍射仪（Bruker Corporation，德国）来进行XRD表征，使用Hitachi S-4800（Hitachi，日本）获得了SEM图像，使用配备有Gatan光谱仪Gif Quantum 965（Gatan Inc.，美国）的JEOL JEM-2100F（JEOL，日本）显微镜获得了TEM图像，使用配备单色铝（Al）K_α辐射的Thermo Scientific ESCLAB 250Xi（Thermo Fisher Scientific，美国）进行XPS，由于荷电效应，所有光谱均根据C 1s的结合能值284.8 eV进行校准。我们在CHI800D电化学工作站（上海辰华仪器有限公司）上测得线性扫描伏安（LSV）曲线，从Solartron电化学工作站上获得电化学阻抗谱（EIS, AHNER-elektrik GmbH & Co. KG，德国），该工作站的频率范围为10 MHz至1 Hz，交流电压幅值为10 mV。在400 MHz AVANCE III HD光谱仪（Bruker Corporation，德国）上测得了核磁共振（NMR）光谱。³¹P的化学位移分别参考1 mol∙L^-1 H₃PO₄水溶液（0 ppm）。在12 kHz的自旋频率下使用循环延迟为60 s和90 s的单脉冲获得了³¹P魔角自旋（MAS）NMR光谱。

2.5. 电化学测量

将固态电池组装在Swagelok电池中，液态电池组装在纽扣电池中，其间所有恒电流测量均在Land BT2000电池测试系统（武汉LAND电子有限公司）上进行。将NVOPF、Super P和PTFE以7:2:1的质量比混合，然后将复合材料辊压成方形薄片，随后在120 ℃高真空下干燥过夜，制备NVOPF阴极片。活性材料负载量约为3 mg cm^‒2。将NVP、Super P和聚偏二氟乙烯（PVDF）以7:2:1的质量比混合，在适量的N-甲基吡咯烷酮（NMP）溶液中制成均匀的浆料并涂覆在铝箔上，随后在120 ℃高真空环境下干燥过夜，制备NVP阴极片。其活性材料负载量约为3 mg∙cm^‒2。NVOPF阴极的截止电压保持在2.8~4.3 V之间，NVP的截止电压保持在2.7~3.7 V之间。制备阳极时，将金属钠和碳纳米管以90:10的质量比在300 ℃下混合制备，然后将其冷却至室温以供使用。特别地，为了组装固态电池，钠附着在NASICON陶瓷片的一侧，在阴极侧添加了5 μL∙cm^‒2的液态电解液[电解液组分为1 mol∙L^-1 NaClO₄/PC，5wt.%氟代碳酸乙烯酯（FEC）作添加剂]以提高润湿性。所有液态纽扣电池都使用与上述相同的液态电解质。所有电池都在充满氩气的手套箱中组装。在充电和放电过程中，使用相同的电流速率。此外，基于PE@NASICON隔膜，中科海钠科技有限责任公司制造了以硬碳为阳极、NNCFM为阴极的2.42 A∙h 26650型圆柱形钠离子电池。

3. 结果与讨论

在Na₁₊Zr₂P_3‒SiO₁₂（0<x<3）中掺杂外来元素是提高离子电导率的一种非常有效的方法；已掺杂的元素汇总在附录A中的表S1中。然而，应该注意的是，与未掺杂的NASICON相比，大多数掺杂型NASICON表现出几个不纯的相，这可能是由于离子半径和电荷的巨大差异引起的。因此，掺杂NASICON时最可能的情况是外来元素在晶界析出并改变了晶粒的成分，然后同时调整晶界和晶粒的成分以实现更好的性能。

图1（a）显示了未掺杂和掺杂Mg的NASICON的XRD图谱，分别标记为NZSP-Mg₀、NZSP-Mg_0.05、NZSP-Mg_0.10、NZSP-Mg_0.15和NZSP-Mg_0.20。在所有XRD结果中，ZrO₂杂质相都与以前的报道一致，很难消除。掺杂Mg的NASICON呈现出更多的ZrO₂以及一个新的NaMgPO₄杂质相。据报道，Mg²⁺不能作为NASICON中的框架离子[52‒53]。因此，此处Mg转化为NaMgPO₄并分布在晶界中。因此，NASICON中Na和P的含量减少，而Si的含量相对增加。同时，ZrO₂在含硅酸盐的化合物中溶解性较差[54]，因此在NASICON中掺杂Mg后，由于Si含量的增加，发现ZrO₂杂质相应增加。此外，根据上述Na含量与NASICON相形成的关系，NZSP-Mg_0.15和NZSP-Mg_0.20应为菱面体R-3c晶系的NASICON [19‒20]。然而，所有合成的材料都表现为单斜C2/c晶体结构，这可以通过位于19.2°和27.5°左右的衍射峰来证实，如图1（b）和（c）所示。XRD结果进一步证实Mg元素不能替代Zr，而NaMgPO₄消耗名义成分Na₃₊₂Zr_2‒MgSi₂PO₁₂（x = 0, 0.05, 0.10, 0.15, 0.20）中的Na。简而言之，Mg的掺杂同时修饰了NASICON的晶粒和晶界。

为了获得更多有关合成产物的结构和组成的信息，我们通过固态³¹P NMR光谱进行定量分析。在图2中，与未掺杂的NASICON相比，可以观察到掺杂Mg的NASICON具有一个额外的峰。如图1（a）所示，位于-11 ppm附近的峰可被识别为NASICON中的磷酸盐，而位于6 ppm附近的峰则归因于NaMgPO₄。此外，随着Mg含量的增加，NASICON的峰逐渐向低场移动，对应于Si/P比的增加。此外，位于6 ppm附近的峰强度随着Mg含量的增加而逐渐增加，表明NaMgPO₄含量增加。

为了更直观地研究NaMgPO₄的分布，进行了透射电子显微镜-电子能量损失谱（TEM-EELS）研究，如图3所示。值得注意的是，Mg元素主要分布在代表晶界的颗粒边缘，而由于NaMgPO₄和Na₃₊₂Zr_2‒Si₂PO₁₂中P元素的浓度不同，P在内部区域和外部边缘之间的分布也不同。这些结果进一步证实了晶界中存在NaMgPO₄，与通过XRD得到的结论一致。

图3 NZSP-Mg_0.15样品的TEM-EELS映射。

NASICON的微观结构通常对最终的离子电导率有极大的影响[23,55‒56]，较大的晶粒通常具有更高的离子电导率[57]。图4显示了合成物的光学照片[图4（a）]和SEM图像[图4（b）~（f）]。从图中可以看出，由于Mg含量低，NZSP-Mg_0.05的微观形貌与未掺杂的NASICON相似，而镁含量越高，晶粒尺寸越大。因此，我们期望可以通过掺杂Mg来提高NASICON的离子电导率。

图4 （a）NZSP-Mg₀、NZSP-Mg_0.05、NZSP-Mg_0.10、NZSP-Mg_0.15和NZSP-Mg_0.20样品的光学照片；（b~f）NZSP-Mg₀（b）、NZSP-Mg_0.05（c）、NZSP-Mg_0.10（d）、NZSP-Mg_0.15（e）和NZSP-Mg_0.20（f）的SEM图像。

在-100~40 ℃的温度范围内，通过EIS测量了所制备的名义成分为Na₃₊₂Zr_2‒MgSi₂PO₁₂（x = 0, 0.05, 0.10, 0.15, 0.20）电解质的电阻。离子电导率根据以下公式计算[58‒59]：

σ = \frac{l}{R S} 式中， σ 为离子电导率； l 为陶瓷片的厚度； R 为测得的电阻； S 为陶瓷颗粒的面积。附录A中的表S2列出了陶瓷颗粒尺寸的信息，图5（a）~（c）总结了由此产生的阿伦尼乌斯行为。通过阿伦尼乌斯方程计算活化能[16,58,60]： σ = \frac{A}{T} e^{- \frac{E_{a}}{k_{B} T}} 式中， A 为指前因子； T 为热力学温度； E a 为扩散的活化能； k B 为玻尔兹曼常量。 图5 总电导率（a）、晶界电导率（b）和晶粒电导率（c）与温度倒数的阿伦尼乌斯图；（d）NZSP-Mg 0.15 样品在25 ℃下的复阻抗平面图。 从图5（a）可以看出，在整个测量温度范围内，随着Mg掺杂量的增加，NASICON的总 σ t 也增加，直到达到NZSP-Mg 0.15 。在复平面阻抗谱中，很难区分来自晶粒和晶界的电阻，因为其曲线在高测量温度下谱图会重叠。基于方程 ω max RC =1（其中， ω max 是阻抗谱中最大损耗的频率， R 是组件的电阻， C 是组件的电容，对于确定的组件来说电容通常是常数）[61]，需要降低测量温度以获得更高的 R 值，以便在工作站的频率范围内分离晶粒和晶界的阻抗，如NZSP-Mg 0.15 阻抗谱中的-100 ℃（附录A中的图S3）。图5（b）和（c）分别显示了在-100 ~ -10 ℃的温度下晶界和晶粒的阿伦尼乌斯行为。可以看出，晶界的 σ （ σ gb ）比晶粒的 σ （ σ g ）变化更大，并且 σ gb 随着Mg掺杂量的增加而增大，直至达到NZSP-Mg 0.15 。由XRD结果可知， σ gb 的增大归因于离子导体NaMgPO 4 （掺杂Mg的Na 3 PO 4 ）的产生[29,60]。空间电荷的影响也有助于晶界处的离子快速扩散[26]。此外，NZSP-Mg 0.20 表现出相似的 σ gb ，因此NZSP-Mg 0.15 的 σ t 比NZSP-Mg 0.20 更高是 σ g 导致的，如图5（c）所示。这是因为NZSP-Mg 0.20 消耗了更多的Na来形成NaMgPO 4 ，从而降低了晶粒中Na + 的浓度；因此，与NZSP-Mg 0.15 相比，NZSP-Mg 0.20 的 σ g 较低，因此 σ t 也较低。 我们测量了合成产物的密度并列于表1，这些数据表明NASICON的密度随着Mg杂质的增加而降低，这被认为对 σ t 不利[57,62]。因此，密度数据进一步证实了晶界在提高离子电导率中起到关键作用。图5（d）显示了NZSP-Mg 0.15 在25 ℃时的阻抗谱。该样品在所制备的NASICON样品中具有最高的离子电导率（25 ℃时为3.54 mS∙cm ‒1 ）；该值也是已报道的掺杂Mg的NASICON电解质中最高的。应该注意的是，之前有人声称一种掺杂Mg的NASICON在室温下具有3.5 mS∙cm -1 的高电导率[31]，但同时期的一篇文章证明了该值是不正确的[29]。 表1 NZSP-Mg、NZSP-Mg、NZSP-Mg、NZSP-Mg和NZSP-Mg样品的密度 Sample Density (g∙cm ‒3) NZSP-Mg 0 3.27 NZSP-Mg 0.05 3.27 NZSP-Mg 0.10 3.23 NZSP-Mg 0.15 3.15 NZSP-Mg 0.20 3.11 NASICON和电极之间的界面相容性在决定固态钠电池的电化学性能方面起着关键作用。特别是，低界面电阻、化学稳定的相界面和较宽的电化学稳定窗口确保了固态钠电池的稳定循环。据报道，钠金属和NASICON之间存在高界面阻抗，这导致固态钠电池的电化学性能较差，尤其是在室温下[33,35‒36,38‒39,63]。在此，为了减轻NASICON/Na阳极的界面阻抗，我们将10%（质量分数）的CNT引入钠金属中，以降低表面张力并增加润湿性。如图6（a）所示，Na|NZSP-Mg 0.15 |Na对称电池在室温下的阻抗谱表现出很小的电阻，足以允许固态钠电池在室温下运行。此外，如图6（b）所示，电流密度为0.1 mA∙cm -2 的恒电流Na剥离/沉积表现出高稳定性，尽管由于钝化层的形成，电压极化略有增加[43,63]，这表明钠金属与NASICON之间的界面稳定性较高。我们还在不同电流密度下进行了恒电流Na剥离/沉积实验，如附录A中的图S4所示，1 mA∙cm -2 的临界电流密度表明界面稳定性高。除了阴极稳定性，NASICON的阳极电化学稳定性对固态钠电池至关重要；高抗氧化性使采用高压阴极获得高能量密度成为可能。大多数研究声称，通过使用LSV或循环伏安法（CV）测试，NASICON的阳极电化学稳定性超过5 V[28,31,33,35,41]。在本研究中，我们也对Au|NASICON|Na进行了LSV测量，以确定其阳极稳定性[图6（c）]。根据LSV曲线，如果以两条切线的交叉点为基准（同文献所述），阳极电化学窗口约为4.62 V，如果以氧化电流为起始点，其阈值为3.75 V。图6（d）显示了Na|NZSP-Mg 0.15 |Na电池和Au|NZSP-Mg 0.15 |Na电池的示意图。 图6 （a）Na|NZSP-Mg 0.15 |Na对称电池在25 ℃时的复阻抗平面图；（b）Na|NZSP-Mg 0.15 |Na对称电池在25 ℃、电流密度为0.1 mA∙cm -2 、电容为0.1 mA∙h∙cm -2 条件下的恒电流Na剥离/电镀循环；（c）NZSP-Mg 0.15 的LSV，扫描速率为0.01 mV∙s -1 ；（d）Na|NZSP-Mg 0.15 |Na电池和Au|NZSP-Mg 0.15 |Na从上到下的示意图。 运行电池是验证NASICON在高压下工作的可行性的直接方法。平均电压低于3.75 V的钠阴极已普遍用于基于NASICON的固态钠电池，且有多个报告证实了NASICON的高稳定性[26,35,42]。在此，我们首次使用高压NVOPF阴极构建了固态钠电池。制备的NVOPF|LE|NZSP-Mg 0.15 |Na SSSB的初始放电容量为113.9 mA∙h∙g ‒1 ，室温下在1 C循环100周后保持率为90.5%，如图7（a）所示。为了研究NVOPF|LE|NZSP-Mg 0.15 |Na固态钠电池容量衰减的原因，在与NVOPF|LE|NZSP-Mg 0.15 |Na固态钠电池相同的条件下构建并运行了对照组电池NVOPF|LE|Na液态电池。如图7（b）所示，对照组电池的首次放电容量为114.9 mA∙h∙g ‒1 ，100周循环后保持率高达98.6%。该结果表明NVOPF配合LE使用的高可靠性，并表明NVOPF和LE不是导致NVOPF|LE|NZSP-Mg 0.15 |Na固态钠电池容量衰减的关键因素。此外，还制备了NVP|LE|NZSP-Mg 0.15 |Na固态钠电池，与预期结果相同，在与NVOPF|LE|NZSP-Mg 0.15 |Na固态钠电池相同的工作条件下，由于其平均工作电压较低，在100周循环后该电池表现出高稳定性，容量保持率为98.8%，如图7（c）所示。 图7 室温下NVOPF|LE|NZSP-Mg 0.15 |Na电池（a）、NVOPF|LE|Na电池（b）和NVP|LE|NZSP-Mg 0.15 |Na电池（c）的循环性能；（d）NVOPF|LE|NZSP-Mg 0.15 |Na电池、NVOPF|LE|Na电池和NVP|LE|NZSP-Mg 0.15 |Na电池从上到下的示意图。 附录A中的图S5给出了NVOPF|LE|NZSP-Mg 0.15 |Na电池[图S5（a）]、NVOPF|LE|Na电池[图S5（b）]和NVP|LE|NZSP-Mg 0.15 |Na电池[图S5（c）]在1 C时的第1周和第100周充放电曲线。图7（d）分别展示了NVOPF|LE|NZSP-Mg 0.15 |Na电池、NVOPF|LE|Na电池和NVP|LE|NZSP-Mg 0.15 |Na电池的示意图。因此，我们推断NASICON在高压下可能不稳定。在恒电流循环测试前后，通过XPS探测了NVOPF|LE|NZSP-Mg 0.15 |Na SSSB阴极侧表面上NZSP-Mg 0.15 的演变，结果如图8所示。Zr 3d、Si 2p、P 2p和Mg 1s峰都向更高的结合能方向移动，表明在电化学充放电过程中NZSP-Mg 0.15 已在高压下被氧化。实验结果与之前的理论计算一致，表明NASICON的阳极电化学稳定性低于4 V [64‒65]。因此，NASICON的分解电位应根据氧化电流的起点，而不是LSV或CV曲线两条切线的交叉点来确定。 图8 NZSP-Mg 0.15 样品在固态钠电池的恒电流循环测试之前（a）和之后（b）的表面特征。C 1s、Zr 3d、Si 2p、P 2p和Mg 1s的XPS光谱。 基于高导电性NZSP-Mg 0.15 固体电解质，制备了PE@NASICON隔膜。图9（a）提供了PE@NASICON表面形貌的SEM图像，从图中可以看出，粒径分布在500~1000 nm范围内的不规则NZSP-Mg 0.15 颗粒均匀地包覆在PE隔膜表面。基于PE@NASICON隔膜，我们以硬碳为阳极、NNCFM为阴极构建了2.42 A∙h 26650型圆柱形钠离子电池；这些电池的平均电压相对于Na + /Na为3.0 V。根据上述结果，PE@NASICON与NNCFM阴极之间具有电化学稳定性。进行第一次循环以在电极表面构建稳定的SEI；附录A中的图S6展示了充电和放电曲线。在1.5~4.0 V的电压范围内，在0.1 C时获得了2.74 A∙h的放电容量。在第一次形成循环结束后，整个电池在1 C电流速率下循环，放电容量为2.42 A∙h，如图9（b）所示。全电池表现出出色的循环性能，2000周循环后容量保持率为88%，如图9（c）所示。图9（c）中的插图是2.42 A∙h 26650型圆柱形钠离子电池的数码照片。电池卓越的性能得益于PE@NASICON隔膜的高可靠性和稳定性。NZSP-Mg 0.15 与NNCFM阴极相容，功能涂层可以抑制TM溶解，保持NNCFM阴极的结构稳定性。此外，在PE隔膜上涂覆NZSP-Mg 0.15 固体电解质层，显著增强了隔膜对LE的润湿性，从而降低了电池的内阻，有助于提升电池性能。因此，NASICON 固体电解质是一种很有前途的功能材料，可用于隔膜优化。 图9 （a）PE@NASICON的表面形貌；（b）硬碳|PE@NASICON|NNCFM在1C时的充放电曲线；（c）硬碳|PE@NASICON|NNCFM在1C下的循环性能。插图是2.42 A∙h 26650型圆柱形钠离子电池的数码照片。 4. 结论 综上所述，本文使用简单的固相法合成了具有低成本的Mg掺杂的NASICON，并且在已报道的名义成分为NZSP-Mg 0.15 的Mg掺杂的NASICON电解质中，在25 ℃时达到了3.54 mS∙cm ‒1 的最高电导率。通过XRD、NMR和TEM-EELS绘图，证实Mg元素不在NASICON的晶格中；相反，Mg在晶界中沉淀，且形成了NaMgPO 4 离子导体。Mg的这种行为同时改变了晶粒和晶界的组成，从而提高了NASICON的离子电导率。此外，基于优化的NZSP-Mg 0.15 ，我们率先采用高压NVOPF作为阴极，以验证高压NASICON基的固态钠电池的可行性。通过比较NVOPF|LE|NZSP-Mg 0.15 |Na固态钠电池与NVOPF|LE|Na电池和NVP|LE|NZSP-Mg 0.15 |Na电池的电化学性能，分析了NZSP-Mg 0.15 的阳极电化学稳定性，结果表明其稳定性不足。对循环后的NZSP-Mg 0.15 颗粒进行XPS检测，结果表明，NZSP-Mg 0.15 的价态上升，进一步证明高压阴极的稳定性差。我们的研究表明，迫切需要制定有效的策略来实现NASICON固体电解质与高压阴极之间的稳定界面。此外，基于PE@NASICON隔膜，构建了2.42 A∙h 26650型圆柱形全电池，该电池在2000周循环后表现出卓越的循环性能，容量保持率为88%。这一结果表明，NASICON固体电解质是一种很有前途的功能材料，可用于隔膜改性。 参考文献 原文顺序 | 出版日期 | 本文引用 [1] Zhao S, Qin B, Chan KY, Li CY, Li F. Recent development of aprotic Na–O2 batteries. Batter Supercaps 2019;2(9):725–42. [2] Lang J, Li J, Zhang F, Ding X, Zapien JA, Tang Y. Sodium-ion hybrid battery combining an anion-intercalation cathode with an adsorption-type anode for enhanced rate and cycling performance. Batter Supercaps 2019;2(5):440–7. [3] Zhao C, Lu Y, Chen L, Hu YS. Flexible Na batteries. InfoMat 2020;2(1):126–38. [4] Lin Z, Xia Q, Wang W, Li W, Chou S. Recent research progresses in ether- and ester-based electrolytes for sodium-ion batteries. InfoMat 2019;1(3):376–89. [5] Hu YS, Lu Y. 2019 Nobel Prize for the Li-ion batteries and new opportunities and challenges in Na-ion batteries. ACS Energy Lett 2019;4(11):2689–90. [6] Li Y, Yang Y, Lu Y, Zhou Q, Qi X, Meng Q, et al. Ultralow-concentration electrolyte for Na-ion batteries. ACS Energy Lett 2020;5(4):1156–8. [7] Eshetu GG, Elia GA, Armand M, Forsyth M, Komaba S, Rojo T, et al. Electrolytes and interphases in sodium-based rechargeable batteries: recent advances and perspectives. Adv Energy Mater 2020;10(20):2000093. [8] Hu Pu, Wang X, Ma J, Zhang Z, He J, Wang X, et al. NaV3(PO4)3/C nanocomposite as novel anode material for Na-ion batteries with high stability. Nano Energy 2016;26:382–91. [9] Hu P, Wang X, Wang T, Chen L, Ma J, Kong Q, et al. Boron substituted Na3V2(P1xBxO4)3 cathode materials with enhanced performance for sodiumion batteries. Adv Sci 2016;3(12):1600112. Correction in: Adv Sci 2017;4(2). [10] Wang Y, Song S, Xu C, Hu N, Molenda J, Lu Li. Development of solid-state electrolytes for sodium-ion battery—a short review. Nano Mater Sci 2019;1 (2):91–100. [11] Huang Y, Zhao L, Li L, Xie M, Wu F, Chen R. Electrolytes and electrolyte/electrode interfaces in sodium-ion batteries: from scientific research to practical application. Adv Mater 2019;31(21):1808393. [12] Liu L, Qi X, Yin S, Zhang Q, Liu X, Suo L, et al. In situ formation of a stable interface in solid-state batteries. ACS Energy Lett 2019;4(7):1650–7. [13] Qiao L, Judez X, Rojo T, Armand M, Zhang H. Review—polymer electrolytes for sodium batteries. J Electrochem Soc 2020;167(7):070534. [14] Zhou C, Bag S, Thangadurai V. Engineering materials for progressive all-solidstate Na batteries. ACS Energy Lett 2018;3(9):2181–98. [15] Zhao C, Liu L, Qi X, Lu Y, Wu F, Zhao J, et al. Solid-state sodium batteries. Adv Energy Mater 2018;8(17):1703012. [16] Lu Y, Li L, Zhang Q, Niu Z, Chen J. Electrolyte and interface engineering for solid-state sodium batteries. Joule 2018;2(9):1747–70. [17] Hou W, Guo X, Shen X, Amine K, Yu H, Lu J. Solid electrolytes and interfaces in all-solid-state sodium batteries: progress and perspective. Nano Energy 2018;52:279–91. [18] Zhang XQ, Zhao CZ, Huang JQ, Zhang Q. Recent advances in energy chemical engineering of next-generation lithium batteries. Engineering 2018;4 (6):831–47. [19] Goodenough JB, Hong HYP, Kafalas JA. Fast Na+ -ion transport in skeleton structures. Mater Res Bull 1976;11(2):203–20. [20] Hong HYP. Crystal structures and crystal chemistry in the system Na1+xZr2SixP3xO12. Mater Res Bull 1976;11(2):173–82. [21] Zhang Z, Shao Y, Lotsch B, Hu YS, Li H, Janek J, et al. New horizons for inorganic solid state ion conductors. Energy Environ Sci 2018;11(8):1945–76. [22] Jalalian-Khakshour A, Phillips CO, Jackson L, Dunlop TO, Margadonna S, Deganello D. Solid-state synthesis of NASICON (Na3Zr2Si2PO12) using nanoparticle precursors for optimisation of ionic conductivity. J Mater Sci 2020;55(6):2291–302. [23] Shao Y, Zhong G, Lu Y, Liu L, Zhao C, Zhang Q, et al. A novel NASICON-based glass–ceramic composite electrolyte with enhanced Na-ion conductivity. Energy Storage Mater 2019;23:514–21. [24] Lan T, Tsai CL, Tietz F, Wei XK, Heggen M, Dunin-Borkowski RE, et al. Roomtemperature all-solid-state sodium batteries with robust ceramic interface between rigid electrolyte and electrode materials. Nano Energy 2019;65:104040. [25] Lee JS, Chang CM, Lee YIL, Lee JH, Hong SH. Spark plasma sintering (SPS) of NASICON ceramics. J Am Ceram Soc 2004;87(2):305–7. [26] Zhang Z, Zhang Q, Shi J, Chu YS, Yu X, Xu K, et al. A self-forming composite electrolyte for solid-state sodium battery with ultralong cycle life. Adv Energy Mater 2017;7(4):1601196. [27] Noi K, Suzuki K, Tanibata N, Hayashi A, Tatsumisago M. Liquid-phase sintering of highly Na+ ion conducting Na3Zr2Si2PO12 ceramics using Na3BO3 additive. J Am Ceram Soc 2018;101(3):1255–65. [28] Yang J, Wan HL, Zhang ZH, Liu GZ, Xu XX, Hu YS, et al. NASICON-structured Na3.1Zr1.95Mg0.05Si2PO12 solid electrolyte for solid-state sodium batteries. Rare Met 2018;37(6):480–7. [29] Samiee M, Radhakrishnan B, Rice Z, Deng Z, Meng YS, Ong SP, et al. Divalentdoped Na3Zr2Si2PO12 natrium superionic conductor: improving the ionic conductivity via simultaneously optimizing the phase and chemistry of the primary and secondary phases. J Power Sources 2017;347:229–37. [30] Hu YS. Batteries: getting solid. Nat Energy 2016;1(4):16042. [31] Song S, Duong HM, Korsunsky AM, Hu N, Lu L. A Na+ superionic conductor for room-temperature sodium batteries. Sci Rep 2016;6(1):32330. [32] Yu X, Manthiram A. Sodium–sulfur batteries with a polymer-coated NASICONtype sodium-ion solid electrolyte. Matter 2019;1(2):439–51. [33] Zhou W, Li Y, Xin S, Goodenough JB. Rechargeable sodium all-solid-state battery. ACS Cent Sci 2017;3(1):52–7. [34] Fu H, Yin Q, Huang Y, Sun H, Chen Y, Zhang R, et al. Reducing interfacial resistance by Na–SiO2 composite anode for NASICON-based solid-state sodium battery. ACS Mater Lett 2020;2(2):127–32. [35] Lu Y, Alonso JA, Yi Q, Lu L, Wang ZL, Sun C. A high-performance monolithic solid-state sodium battery with Ca2+ doped Na3Zr2Si2PO12 electrolyte. Adv Energy Mater 2019;9(28):1901205. [36] Matios E, Wang H, Wang C, Hu X, Lu X, Luo J, et al. Graphene regulated ceramic electrolyte for solid-state sodium metal battery with superior electrochemical stability. ACS Appl Mater Interfaces 2019;11(5):5064–72. [37] Miao X, Di H, Ge X, Zhao D, Wang P, Wang R, et al. AlF3-modified anodeelectrolyte interface for effective Na dendrites restriction in NASICON-based solid-state electrolyte. Energy Storage Mater 2020;30:170–8. [38] Uchida Y, Hasegawa G, Shima K, Inada M, Enomoto N, Akamatsu H, et al. Insights into sodium ion transfer at the Na/NASICON interface improved by uniaxial compression. ACS Appl Energy Mater 2019;2(4):2913–20. [39] Noguchi Y, Kobayashi E, Plashnitsa LS, Okada S, Yamaki JI. Fabrication and performances of all solid-state symmetric sodium battery based on NASICONrelated compounds. Electrochim Acta 2013;101:59–65. [40] Lalère F, Leriche JB, Courty M, Boulineau S, Viallet V, Masquelier C, et al. An allsolid state NASICON sodium battery operating at 200 C. J Power Sources 2014;247:975–80. [41] Ruan Y, Guo F, Liu J, Song S, Jiang N, Cheng B. Optimization of Na3Zr2Si2PO12 ceramic electrolyte and interface for high performance solid-state sodium battery. Ceram Int 2019;45(2):1770–6. [42] Gao H, Xue L, Xin S, Park K, Goodenough JB. A plastic-crystal electrolyte interphase for all-solid-state sodium batteries. Angew Chem Int Ed Engl 2017;56(20):5541–5. [43] Gao H, Xin S, Xue L, Goodenough JB. Stabilizing a high-energy-density rechargeable sodium battery with a solid electrolyte. Chem 2018;4(4): 833–44. [44] Kehne P, Guhl C, Ma Q, Tietz F, Alff L, Hausbrand R, et al. Electrochemical performance of all-solid-state sodium-ion model cells with crystalline NaxCoO2 thin-film cathodes. J Electrochem Soc 2019;166(3):A5328–32. [45] Kehne P, Guhl C, Ma Q, Tietz F, Alff L, Hausbrand R, et al. Sc-substituted Nasicon solid electrolyte for an all-solid-state NaxCoO2/Nasicon/Na sodium model battery with stable electrochemical performance. J Power Sources 2019;409:86–93. [46] Zhan C, Wu T, Lu J, Amine K. Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes—a critical review. Energy Environ Sci 2018;11(2):243–57. [47] Zhang Q, Gu QF, Li Y, Fan HN, Luo WB, Liu HK, et al. Surface stabilization of O3- type layered oxide cathode to protect the anode of sodium ion batteries for superior lifespan. iScience 2019;19:244–54. [48] Yan Z, Pan H, Wang J, Chen R, Luo F, Yu X, et al. Suppressing transition metal dissolution and deposition in lithium-ion batteries using oxide solid electrolyte coated polymer separator. Chin Phys B 2020;29(8):088201. [49] Qi XG, Zhou Q, Tang K, Hu YS, inventors; HiNa Battery Technology Co., Ltd., assignee. [Ceramic separator and sodium ion secondary battery for sodium ion battery and its application]. Chinese Patent CN109244314A. 2019 Jan 18. Chinese. [50] Qi Y, Zhao J, Yang C, Liu H, Hu Y. Comprehensive studies on the hydrothermal strategy for the synthesis of Na3(VO1xPO4)2F1+2x (0 x 1) and their Nastorage performance. Small Methods 2019;3(4):1800111. [51] Zhang Q, Lu Y, Yu H, Yang G, Liu Q, Wang Z, et al. PEO-NaPF6 blended polymer electrolyte for solid state sodium battery. J Electrochem Soc 2020;167 (7):070523. [52] Tsai CL, Hong HYP. Investigation of phases and stability of solid electrolytes in the NASICON system. Mater Res Bull 1983;18(11):1399–407. [53] Takahashi T, Kuwabara K, Shibata M. Solid-state ionics—conductivities of Na+ ion conductors based on NASICON. Solid State Ion 1980;1(3–4):163–75. [54] Vonalpen U, Bell M, Hofer H. Compositional dependence of the electrochemical and structural parameters in the Nasicon system (Na1+xSixZr2P3xO12). Solid State Ion 1981;3-4:215–8. [55] Fuentes RO, Figueiredo FM, Marques FMB, Franco JI. Processing and electrical properties of NASICON prepared from yttria-doped zirconia precursors. J Eur Ceram Soc 2001;21(6):737–43. [56] Fuentes R. Influence of microstructure on the electrical properties of NASICON materials. Solid State Ion 2001;140(1–2):173–9. [57] Naqash S, Sebold D, Tietz F, Guillon O. Microstructure–conductivity relationship of Na3Zr2(SiO4)2(PO4) ceramics. J Am Ceram Soc 2019;102 (3):1057–70. [58] Guin M, Tietz F, Guillon O. New promising NASICON material as solid electrolyte for sodium-ion batteries: correlation between composition, crystal structure and ionic conductivity of Na3+xSc2SixP3xO12. Solid State Ion 2016;293:18–26. [59] Deng Y, Eames C, Nguyen LHB, Pecher O, Griffith KJ, Courty M, et al. Crystal structures, local atomic environments, and ion diffusion mechanisms of scandium-substituted sodium superionic conductor (NASICON). Chem Mater 2018;30(8):2618–30. [60] Ben Bechir M, Ben Rhaiem A. The sodium-ion battery: study of alternative current conduction mechanisms on the Na3PO4-based solid electrolyte. Physica E 2020;120:114032. [61] Irvine JTS, Sinclair DC, West AR. Electroceramics: characterization by impedance spectroscopy. Adv Mater 1990;2(3):132–8. [62] Kim JH, Oh TS, Lee MS, Park JG, Kim YH. Effects of Al2O3 addition on the sinterability and ionic conductivity of nasicon. J Mater Sci 1993;28(6): 1573–7. [63] Wang S, Xu H, Li W, Dolocan A, Manthiram A. Interfacial chemistry in solidstate batteries: formation of interphase and its consequences. J Am Chem Soc 2018;140(1):250–7. [64] Tang H, Deng Z, Lin Z, Wang Z, Chu IH, Chen C, et al. Probing solid–solid interfacial reactions in all-solid-state sodium-ion batteries with firstprinciples calculations. Chem Mater 2018;30(1):163–73. [65] Lacivita V, Wang Y, Bo SH, Ceder G. Ab initio investigation of the stability of electrolyte/electrode interfaces in all-solid-state Na batteries. 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        "summaryEn": `\\#\\#\\# Summary and Abstract\n\n**Research Background**\nThe inheritance of Chinese ethnic music culture in universities is a current hotspot in aesthetic education. This study focuses on exploring the significance, necessity, and practical modes and pathways of inheriting Chinese ethnic music culture in the aesthetic education of medical universities, aiming to enhance students' ethnic consciousness, self-confidence, and sense of identity, while also promoting their comprehensive development.\n\n**Research Methods**\nThe research employs a combination of theoretical analysis and practical exploration. Through literature review, case studies, and empirical research, the study investigates the current status and challenges of Chinese ethnic music culture inheritance in medical universities and proposes a "4+3+5" inheritance mode and pathway.\n\n**Experimental Design**\nThe "4+3+5" mode is based on "four combinations" (knowledge teaching and practical experience, intra-school and extra-school cooperation, cultural inheritance and innovation projects, aesthetic education and ideological education), supported by "three measures" (strengthening curriculum construction, optimizing resource integration, and ensuring conditions), and implemented through "five paths" (aesthetic education teaching, campus cultural activities, inter-school and international exchanges, social practice services, and college student innovation and entrepreneurship).\n\n**Results and Analysis**\nThe implementation of the "4+3+5" mode in Sichuan University has achieved significant results. It has effectively promoted the inheritance and innovation of Chinese ethnic music culture among medical students, enhanced their aesthetic abilities and cultural qualities, and cultivated their teamwork and innovative spirits. The study also finds that music has a positive auxiliary effect on medical treatment, which can help improve patients' physical and mental health.\n\n**Overall Conclusion**\nThe inheritance of Chinese ethnic music culture in the aesthetic education of medical universities is of great significance. The "4+3+5" mode proposed in this study provides an effective pathway for the inheritance and innovation of Chinese ethnic music culture in medical universities, which helps to enhance students' comprehensive qualities and promote their all-round development.\n\n**Paper Review**\nThis paper systematically explores the inheritance mode and pathway of Chinese ethnic music culture in the aesthetic education of medical universities, with clear research ideas and practical research methods. The proposed "4+3+5" mode is innovative and operable, providing valuable references for the inheritance and innovation of Chinese ethnic music culture in universities.\n\n**Ten Questions and Answers**\n\n1. **Q: What is the main research content of this paper?**  \n   A: This paper mainly studies the inheritance mode and pathway of Chinese ethnic music culture in the aesthetic education of medical universities, aiming to explore effective ways to promote the inheritance and development of Chinese ethnic music culture among medical students.\n\n2. **Q: Why is it necessary to inherit Chinese ethnic music culture in medical universities?**  \n   A: Inheriting Chinese ethnic music culture in medical universities can enhance students' ethnic consciousness, self-confidence, and sense of identity, promote their comprehensive development, and also help them better serve the national medical cause by utilizing the auxiliary medical effects of music.\n\n3. **Q: What is the "4+3+5" mode proposed in this paper?**  \n   A: The "4+3+5" mode refers to an inheritance mode and pathway based on "four combinations," supported by "three measures," and implemented through "five paths." It aims to comprehensively promote the inheritance and innovation of Chinese ethnic music culture in medical universities.\n\n4. **Q: How does the "4+3+5" mode promote the inheritance of Chinese ethnic music culture?**  \n   A: By integrating knowledge teaching with practical experience, intra-school and extra-school cooperation, cultural inheritance with innovation projects, and aesthetic education with ideological education, the "4+3+5" mode creates a dynamic and cooperative educational environment that effectively promotes the inheritance and innovation of Chinese ethnic music culture.\n\n5. **Q: What are the "three measures" in the "4+3+5" mode?**  \n   A: The "three measures" refer to strengthening curriculum construction and aesthetic activity innovation, optimizing the integration of aesthetic education and ethnic music cultural resources, and ensuring conditions for aesthetic education and cultural inheritance work, such as strengthening teacher training, improving facilities, and enhancing campus cultural environment.\n\n6. **Q: How does the "five paths" approach implement the inheritance of Chinese ethnic music culture?**  \n   A: The "five paths" include aesthetic education teaching, campus cultural activities, inter-school and international exchanges, social practice services, and college student innovation and entrepreneurship. These paths provide diverse platforms and opportunities for students to learn, experience, and innovate Chinese ethnic music culture.\n\n7. **Q: What are the benefits of implementing the "4+3+5" mode in medical universities?**  \n   A: Implementing the "4+3+5" mode can enhance students' aesthetic abilities and cultural qualities, cultivate their teamwork and innovative spirits, and promote their comprehensive development. It also helps to improve the quality of medical services by utilizing the auxiliary medical effects of music.\n\n8. **Q: How does this paper contribute to the field of aesthetic education in medical universities?**  \n   A: This paper provides a comprehensive and innovative framework for the inheritance and innovation of Chinese ethnic music culture in medical universities, enriching the theoretical and practical research in the field of aesthetic education and offering valuable references for other universities.\n\n9. **Q: What are the limitations of this study?**  \n   A: This study mainly focuses on the inheritance mode and pathway of Chinese ethnic music culture in medical universities, with limited exploration of other aspects such as the specific effects of music therapy in medical practice. Future research can further explore these aspects.\n\n10. **Q: How can the "4+3+5" mode be promoted and applied in other universities?**  \n    A: The "4+3+5" mode can be promoted and applied in other universities by sharing successful cases, conducting academic exchanges, and providing training and guidance. Universities can also combine their own characteristics and resources to adapt and innovate the mode to better serve their educational goals.\n\n**Key Points Extraction**\n- The inheritance of Chinese ethnic music culture in medical universities is necessary and significant.\n- The "4+3+5" mode provides an effective pathway for the inheritance and innovation of Chinese ethnic music culture.\n- The implementation of the "4+3+5" mode can enhance students' comprehensive qualities and promote their all-round development.\n- The auxiliary medical effects of music should be further explored and applied in medical practice.\n- Universities should strengthen cooperation and exchanges to promote the inheritance and innovation of Chinese ethnic music culture.`,
        "summaryCn": '\\# 总结摘要\n\n\\#\\# 研究背景\n\n中国民族音乐文化作为中华优秀传统文化的重要组成部分，其传承与发展在当今社会具有重要意义。特别是在医科大学美育教育中，传承中国民族音乐文化不仅能够增强大学生的民族意识、民族自信和民族认同感，还能发挥民族音乐的医疗辅助效力，提高大学生的综合素质，促进全面发展。因此，本研究旨在探索中国民族音乐文化在医科大学美育教育中的传承模式与路径。\n\n\\#\\# 研究方法\n\n本研究采用文献综述、实证研究、案例分析等方法，结合四川大学美育教育的实践经验，对中国民族音乐文化的传承模式与路径进行深入探讨。\n\n\\#\\# 实验设计\n\n研究通过构建“4+3+5”传承模式与路径，即以“四个结合”为基础、“三项措施”为保障、“五条路径”为抓手，来实施中国民族音乐文化传承教育。具体实验设计包括加强第一课堂与第二课堂的融合、建立校地合作平台、依托大学生创新创业项目等。\n\n\\#\\# 结果与分析\n\n研究结果显示，“4+3+5”传承模式与路径在医科大学美育教育中取得了显著成效。通过知识讲授与实践体验相结合、校内与校外结合、文化传承与“双创”项目结合、审美教育与思政教育结合，有效提升了学生对中国民族音乐文化的认知度和兴趣。同时，加强课程建设与美育活动创新、优化整合美育教育与民族音乐文化资源、加大美育教育与民族文化传承工作的条件保障等措施，为传承活动提供了有力支持。五条路径的实施更是将中国民族音乐文化传承贯穿于课堂教学、课外活动、文化氛围、网络空间等多个维度，实现了全方位、多层次的传承。\n\n\\#\\# 总体结论\n\n中国民族音乐文化在医科大学美育教育中的传承模式和路径探索具有可行性和有效性。通过“4+3+5”传承模式与路径的实施，不仅能够提升学生的综合素质和审美能力，还能促进中国民族音乐文化的传承与发展。未来，应进一步锐意创新，解决美育教育与学生专业成长和个性化需求相结合等问题，实现美育教育与医学专业教育的优化组合。\n\n\\#\\# 论文点评\n\n该论文选题新颖，具有重要的理论和实践意义。研究方法科学合理，实验设计严谨可行。结果分析深入透彻，总体结论具有说服力。论文结构清晰，逻辑严密，语言流畅。然而，论文在探讨具体传承措施和路径时，可进一步细化操作细节和案例分析，以增强研究的实用性和可操作性。\n\n\\#\\# 论文十问\n\n问题1. **中国民族音乐文化在医科大学美育教育中的传承有何重要意义？**\n答案：传承中国民族音乐文化能够增强医学生的民族意识、民族自信和民族认同感，提升综合素质，同时发挥民族音乐的医疗辅助效力，促进医患沟通理解和情感交流。\n\n问题2. **“4+3+5”传承模式与路径具体包括哪些内容？**\n答案：“4+3+5”传承模式与路径包括“四个结合”（知识讲授与实践体验、校内与校外、文化传承与“双创”项目、审美教育与思政教育）、“三项措施”（加强课程建设与美育活动创新、优化整合资源、加大条件保障）和“五条路径”（美育教育教学、校园文化活动、校际国际交流、社会实践服务、大学生创新创业）。\n\n问题3. **如何加强第一课堂与第二课堂的融合？**\n答案：通过理论教学指导学生参与中国民族音乐文化的传承、保护与创新创作活动，在实践活动中融入理论知识，实现第一课堂与第二课堂的有机融合。\n\n问题4. **校地合作平台在传承中扮演什么角色？**\n答案：校地合作平台为学生开辟社会实践学习通道和演出通道，引导学生个体、学校群体、社会整体的相互联动，积极整合吸引各种社会资源和教育资源。\n\n问题5. **如何依托大学生创新创业项目促进民族音乐治疗科研创新？**\n答案：以大学生创新创业项目为依托，加强中国民族音乐治疗科研创新，促进科研成果转化，培养学生创新创造能力。\n\n问题6. **美育课程建设在传承中起到什么作用？**\n答案：美育课程建设是传承的基础，通过开设中华文化美育必修课程、美育类模块课程等，落实美育课程开设刚性要求，提升学生审美素养。\n\n问题7. **如何优化整合美育教育和文化传承资源？**\n答案：加强与民族大学、民族艺术团、民族博物馆等的工作联系与沟通，邀请高水平老师参加学生艺术团建设和指导，办好各类音乐活动。\n\n问题8. **社会实践服务在传承中有哪些具体形式？**\n答案：社会实践服务包括“大川文艺轻骑兵”服务进社区、中小学、医院、农村等活动，实现人才培养与服务地方的双向联动。\n\n问题9. **如何鼓励大学生创新创业团队参与传承研究工作？**\n答案：鼓励学生组建科研兴趣小组和团队，参与地方非物质文化遗产的传承研究工作，参加各类创新创业比赛和社会实践。\n\n问题10. **论文对未来传承模式与路径的探索有何建议？**\n答案：论文建议未来应锐意创新，解决美育教育与学生专业成长和个性化需求相结合等问题，实现美育教育与医学专业教育的优化组合。\n\n\\#\\# 要点提炼\n\n- **研究背景**：强调中国民族音乐文化在医科大学美育教育中的重要性。\n- **研究方法**：采用文献综述、实证研究、案例分析等方法。\n- **实验设计**：构建“4+3+5”传承模式与路径。\n- **结果与分析**：传承模式与路径取得显著成效，提升学生认知度和兴趣。\n- **总体结论**：传承模式和路径具有可行性和有效性，需进一步创新优化。\n- **论文点评**：选题新颖，方法科学，结论有说服力，但可进一步细化操作细节。\n- **论文十问**：涵盖传承意义、模式内容、具体措施、资源整合、科研创新等方面。\n- **要点提炼**：总结研究背景、方法、实验设计、结果、结论及未来建议。',
        "mindMapEn": `\\# Inheritance mode and pathway of Chinese ethnic music culture in aesthetic education of medical universities\n\n\\#\\# Abstract\n- **[Keywords]**\n  - Chinese ethnic music culture; heritage; medical university; aesthetic education; inheritance mode; pathway\n\n\\#\\# Introduction\n- **[Significance and Necessity]**\n  - Enhancing ethnic consciousness, self-confidence, and sense of identity\n  - Medical auxiliary effects of folk music\n  - Preserving and disseminating ethnic music and culture\n  - Improving comprehensive quality and promoting all-round development\n\n\\#\\# Section 1: Significance & Necessity of Inheriting Chinese Ethnic Music in Medical Universities\n\n\\#\\#\\# 1.1 Promoting Chinese Aesthetic Education Spirit\n- **[Enhancing Cultural Awareness and Innovation]**\n  - Ministry of Education's emphasis on cultural inheritance\n- **[Implementing Aesthetic Education]**\n  - Infusing aesthetics into all aspects of education\n\n\\#\\#\\# 1.2 Medical Auxiliary Efficacy of Ethnic Music\n- **[Research on Music Therapy]**\n  - Regulation of respiration, heart rate, blood flow\n- **[Traditional and Modern Practices]**\n  - "Five Tones Therapy" in ancient China\n  - Modern applications in clinical settings\n\n\\#\\#\\# 1.3 Synergistic Development of Aesthetic Education and Ethnic Music Inheritance\n- **[Educational Function of Music]**\n  - Inspiring learning enthusiasm and creative spirit\n- **[Protecting and Inheriting Ethnic Music]**\n  - Preservation in museums and educational institutions\n\n\\#\\# Section 2: Inheritance Mode and Pathway of Chinese Ethnic Music Culture\n\n\\#\\#\\# 2.1 Four Combinations in Inheritance Education\n- **[Knowledge Teaching and Practical Experience]**\n  - Integration of first and second classrooms\n- **[Intra- and Extra-Campus Collaboration]**\n  - Establishing cooperation platforms\n- **[Cultural Inheritance and Innovation Projects]**\n  - Integrating innovation into ethnic music therapy\n- **[Aesthetic and Ideological Education]**\n  - Combining aesthetics with moral education\n\n\\#\\#\\# 2.2 Three Measures for Inheritance Education\n- **[Reforming Aesthetic Education]**\n  - Focusing on aesthetics, humanity, and innovation\n- **[Curriculum and Activity Innovation]**\n  - Enhancing curriculum construction and artistic practices\n- **[Resource Optimization and Conditional Support]**\n  - Strengthening faculty, facilities, and cultural environment\n\n\\#\\#\\# 2.3 Five Paths in the Inheritance Process\n- **[Aesthetic Education Teaching]**\n  - Incorporating ethnic music into curriculum and lectures\n- **[Campus Cultural Activities]**\n  - Organizing performances and workshops\n- **[Inter-School and International Exchanges]**\n  - Promoting cultural exchange through concerts and salons\n- **[Social Practice Services]**\n  - Volunteering and community engagement\n- **[Student Innovation and Entrepreneurship]**\n  - Encouraging research and entrepreneurship in ethnic music\n\n\\#\\# Conclusion\n- **[Continuous Innovation and Development]**\n  - Addressing challenges and integrating aesthetic education with medical education\n- **[Importance of Ethnic Music in Medical Education]**\n  - Highlighting the role of ethnic music in cultivating medical students' comprehensive qualities\n\n\\#\\# References\n- **[Citations]**\n  - List of references from official documents, research papers, and books`,
        "mindMapCn": '\\# 中国民族音乐文化在医科大学美育教育中的传承模式与路径研究\n\n\\#\\# 摘要\n- **[研究背景]**：中国民族音乐文化的高校传承是美育教育的热点。\n- **[研究目的]**：在医科大学美育教育中传承中国民族音乐文化，提升大学生民族意识、民族自信等，并发挥民族音乐的医疗辅助效力。\n- **[研究成果]**：提出“4+3+5”传承模式与路径。\n\n\\#\\# 关键词\n- 中国民族音乐\n- 文化遗产\n- 医科大学\n- 美育教育\n- 传承模式\n- 路径\n\n\\#\\# 1. 在医科大学美育教育中开展中国民族音乐文化传承的意义与必要性\n\\#\\#\\# 1.1 弘扬中华美育精神\n- **[教育部重视]**：增强文化主体意识和文化创新意识。\n- **[美育浸润行动]**：弘扬中华美育精神，坚定文化自信。\n\n\\#\\#\\# 1.2 发挥民族音乐的医疗辅助效力\n- **[音乐治疗]**：特殊音乐刺激对调节人的生理、心理有辅助作用。\n- **[民族音乐治疗]**：我国提出“五音疗疾”，现代民族音乐治疗发展迅速。\n\n\\#\\#\\# 1.3 推进美育教育与中国民族音乐文化传承协同发展\n- **[育人功能]**：音乐教育激励学习热情和进取精神。\n- **[传承保护]**：高校教育作为动态保护、传承途径，具有优势。\n\n\\#\\# 2. 中国民族音乐文化的传承模式与路径\n\\#\\#\\# 2.1 传承教育中的“四个结合”\n- **[知识讲授与实践体验结合]**：第一课堂与第二课堂融合。\n- **[校内与校外结合]**：建立校地合作平台，开辟社会实践通道。\n- **[文化传承与“双创”项目结合]**：依托创新创业项目，促进科研成果转化。\n- **[审美教育与思政教育结合]**：协同并进，激发学生文化自信。\n\n\\#\\#\\# 2.2 传承教育中的“三项措施”\n- **[加强课程建设与美育活动创新]**：优化整合课堂教学、艺术实践、校园文化活动。\n- **[优化整合美育教育与民族音乐文化资源]**：加强与民族大学等沟通，邀请高水平老师指导。\n- **[加大美育教育与民族文化传承工作的条件保障]**：加强师资队伍建设、场地建设、校园文化环境建设。\n\n\\#\\#\\# 2.3 传承过程中的“五条路径”\n- **[美育教育教学]**：将中国民族音乐教育素材融入教学，激发学习兴趣。\n- **[校园文化活动]**：开展高雅艺术进校园，举办各类民族特色活动。\n- **[校际国际交流]**：与国内外大学建立交流关系，举办国际交流音乐会。\n- **[社会实践服务]**：推进“大川文艺轻骑兵”服务，普及疾病与健康基础知识。\n- **[大学生创新创业]**：参与地方非物质文化遗产传承研究，注入音乐元素到医学研究中。\n\n\\#\\# 结论\n- **[持续发展]**：需锐意创新，解决美育教育与学生专业成长需求结合等问题。\n- **[优化组合]**：找到适合医科学生专业特点的艺术种类和学习方法，实现美育教育与医学专业教育的优化组合。\n\n\\#\\# 参考文献\n- **[参考文献列表]**：列出论文引用的所有文献。'
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                        const hashes = match[1];
                        if (hashes.length > 1) {
                            line = '#' + line.substring(hashes.length);
                        }
                    }
                }
                output.push(line);
            }
        }
        return output.join('\n');
    }
    
    let mindMapUrl = 'https://www.engineering.org.cn/engi/CN/api/article-ai/generate-mindmap?language=EN&articleId=1159867208501355111&journalId=1155139928190095384';

    // 异步获取 obj 数据
    function fetchMindmapData() {
    
        if (checkHepJournalPage()) {
            let cleanUrl = window.location.href.split('?')[0];
            let paperUrl = cleanUrl;
            // 满足条件时，打印完整的 URL
            console.log("匹配成功，当前 URL:", window.location.href);
            mindMapUrl = `https://ai.magtechjournal.com/api/hep/generate-mindmap?articleId=`+paperUrl;
            console.log('尝试连接SSE:', mindMapUrl);

            return $.ajax({
                url: mindMapUrl, // 请替换为实际接口地址
                method: 'GET',
                dataType: 'json',
                success: function (data) {
                    console.log('success', data);
                    if (data.code === 0 && data.data) {
                        obj = data.data;
                        // 处理 mindMapCn 和 mindMapEn，删除根节点并提升层级
                        if (obj.mindMapCn) {
                            obj.mindMapCn = removeRootNodeAndPromote(obj.mindMapCn);
                        }
                        if (obj.mindMapEn) {
                            obj.mindMapEn = removeRootNodeAndPromote(obj.mindMapEn);
                        }
                        console.log('接口数据获取成功:', obj);
                    } else {
                        console.error('接口返回错误:', data);
                    }
                    updateMindMapButtonVisibility();
                    updateSummaryButtonVisibility();
                },
                error: function (xhr, status, error) {
                    console.error('接口请求失败:', status, error);
                    $("#markmap").html('<p style="color:red;">无法加载数据，请稍后重试。</p>');
                }
            });
        }
    
        return $.ajax({
            url: mindMapUrl, // 请替换为实际接口地址
            method: 'GET',
            dataType: 'json',
            success: function (data) {
                console.log('success', data);
                if (data.code === 200 && data.data) {
                    obj = data.data;
                    // 处理 mindMapCn 和 mindMapEn，删除根节点并提升层级
                    if (obj.mindMapCn) {
                        obj.mindMapCn = removeRootNodeAndPromote(obj.mindMapCn);
                    }
                    if (obj.mindMapEn) {
                        obj.mindMapEn = removeRootNodeAndPromote(obj.mindMapEn);
                    }
                    console.log('接口数据获取成功:', obj);
                } else {
                    console.error('接口返回错误:', data);
                }
                updateMindMapButtonVisibility();
                updateSummaryButtonVisibility();
            },
            error: function (xhr, status, error) {
                console.error('接口请求失败:', status, error);
                $("#markmap").html('<p style="color:red;">无法加载数据，请稍后重试。</p>');
            }
        });
    }
    
    // ======== AI summary define
    
    // 跟踪请求状态，防止重复请求
    const requestStatus = {
        CN: false, // 中文请求是否正在进行
        EN: false  // 英文请求是否正在进行
    };
    
    // 存储中英文 buffer
    const buffers = {
        CN: '',
        EN: ''
    };
    
    function cleanText(text) {
        const cleanResult = extractSseResults(text);
        return cleanResult;
    }
    
    // 渲染 Markdown 内容
    function renderContent(lang, text) {
    
        const md = new remarkable.Remarkable({
            html: true,
            breaks: false, // 禁用单换行转<br>，保持Markdown段落
            typographer: true
        });
    
        try {
            const cleanedText = cleanText(text);
            const content = cleanedText ? md.render(cleanedText) : '<p>Loading ... </p>';
            $("#showArticle_quickread_content_cn").html(content);
        } catch (e) {
            const cleaned = cleanText(text);
            $("#showArticle_quickread_content_cn").html(
                `<p>Loading ... </p>`
            );
        }
    }
    
    // 显示摘要对话框
    function showQuickread(lang) {
        console.log('showQuickread 调用，语言:', lang, '当前数据:', obj);
        $("#showArticle_quickread").show();
        $(".main_content_center_right").hide();
        if (lang === 'EN') {
            if (checkHepJournalPage()) {
                renderHepContent(lang, buffers['EN']);
            }else{
                renderContent(lang, buffers['EN']);
            }
            $("#showArticle_quickread_en").hide();
            $("#showArticle_quickread_cn").show();
        } else {
            // 检查 typeValue 是否存在且等于 'hep'
            if (checkHepJournalPage()) {
                renderHepContent(lang, buffers['CN']);
            }else{
                renderContent(lang, buffers['CN']);
            }
            $("#showArticle_quickread_cn").hide();
            $("#showArticle_quickread_en").show();
        }
        currentLang = lang;
    }
    
    
    // 渲染 Markdown 内容
    function renderHepContent(lang, text) {

        const md = new remarkable.Remarkable({
            html: true,
            breaks: false, // 禁用单换行转<br>，保持Markdown段落
            typographer: true
        });

        try {
            const cleanedText = extractHepSseResults(text);
            const content = cleanedText ? md.render(cleanedText) : '<p>Loading ... </p>';
            $("#showArticle_quickread_content_cn").html(content);
        } catch (e) {
            const cleaned = extractHepSseResults(text);
            $("#showArticle_quickread_content_cn").html(
                `<p>Loading ... </p>`
            );
        }
    }
    
    // 关闭摘要对话框
    function closeQuickread() {
        $("#showArticle_quickread").hide();
        $(".main_content_center_right").show();
    }
    
    function extractSseResults(sseData) {
    // 确保 sseData 是字符串并按行分割
        const lines = typeof sseData === 'string' ? sseData.split('kkk') : [];
        // 提取 result 并拼接
        const resultList = [];
        for (const line of lines) {
            // 过滤空行（空字符串或仅包含空白字符的行）
            if (!line.trim()) {
                continue;
            }
            if (line.startsWith('{"errCode":0')) {
            
                try {
                    // 解析 JSON
                    const data = JSON.parse(line);
                    // 提取 raw.result，处理 raw 可能为 null 或 undefined 的情况
                    if (data.raw && data.raw.result) {
                        resultList.push(data.raw.result);
                    }
                } catch (e) {
                    console.error(`JSON 解析错误: ${e.message}`);
                }
            }
        }
        // 拼接 result 并返回
        return resultList.join('');
    }
    
    function extractHepSseResults(sseData) {
        // 确保 sseData 是字符串并按行分割
        const lines = typeof sseData === 'string' ? sseData.split('kkk') : [];
        // 提取 result 并拼接
        const resultList = [];
        for (const line of lines) {
            // 过滤空行（空字符串或仅包含空白字符的行）
            if (!line.trim()) {
                continue;
            }
            //{"chunk_id":6,"content":"---\n","status":"processing"}
            if (line.startsWith('{"chunk_id') || line.startsWith('{"chunkId') ) {

                try {
                    // 解析 JSON
                    const data = JSON.parse(line);
                    // 提取 raw.result，处理 raw 可能为 null 或 undefined 的情况
                    if (data.content) {
                        if(data.content.startsWith("```markdown")){
                            continue;
                        }
                        resultList.push(data.content);
                    }
                } catch (e) {
                    console.error(`JSON 解析错误: ${e.message}`);
                }
            }
        }
        // 拼接 result 并返回
        return resultList.join('');
    }
        
    let currentEventSource = null; // 跟踪当前EventSource实例    
    let cnEventSource = null;
    let enEventSource = null;
    // 使用 SSE 获取数据
    function fetchSummaryData(language = 'CN') {
        // 关闭现有EventSource连接
        if (currentEventSource) {
            console.log("======= fetch ",language);
            console.log('关闭现有SSE连接');
            currentEventSource.close();
            currentEventSource = null;
        }
        
        
        if (checkHepJournalPage()) {
            let cleanUrl = window.location.href.split('?')[0];
            let paperUrl = cleanUrl;
            // 用于拼接 SSE 数据
            if(language === 'EN'){
                // 满足条件时，打印完整的 URL
                console.log("============333 type == hep 匹配成功，当前 URL:", window.location.href);
                const summaryUrl = 'https://ai.magtechjournal.com/api/hep/generate-summary-sse?articleId='+paperUrl+'&language=EN';
                console.log('尝试连接SSE:', summaryUrl);
                enEventSource = new EventSource(summaryUrl, { withCredentials: true });
                let buffer = '';
                enEventSource.onmessage = function(event) {
                    if (event.data && event.data !== 'Summary generation finished.') {
                        console.log(event.data);
                        //{"chunk_id":5,"content":"Extensive experiments \n","status":"processing"}
                        // 仅当数据不以换行符结尾且非空时添加\n
                        buffer += event.data +'kkk';

                        buffers['EN'] = buffer;
                        // console.log('E,'+currentLang);
                        if(currentLang === 'EN') {
                            // 实时渲染以提供反馈
                            renderHepContent(currentLang, buffer);
                        }

                    }
                    if(event.data.includes('Summary generation finished')){
                        console.log('+++'+event.data);
                        buffers['EN'] = buffer;
                        if(currentLang === 'EN') {
                            renderHepContent(currentLang, buffer);
                        }
                        enEventSource.close();
                        enEventSource = null;
                        console.log("enEventSource complete complete complete");
                    }
                };
                enEventSource.onerror = function(err) {
                    console.log(err);
                    console.log("enEventSource error complete");
                    enEventSource.close();
                };
            } else {
                // 满足条件时，打印完整的 URL
                console.log("============333 type == hep 匹配成功，当前 URL:", window.location.href);
                const summaryUrl = 'https://ai.magtechjournal.com/api/hep/generate-summary-sse?articleId='+paperUrl+'&language=CN';
                console.log('尝试连接SSE:', summaryUrl);
                cnEventSource = new EventSource(summaryUrl, { withCredentials: true });
                let buffer = '';
                cnEventSource.onmessage = function(event) {
                    if (event.data && event.data !== 'Summary generation finished.') {
                        console.log(event.data);
                        //{"chunk_id":5,"content":"Extensive experiments \n","status":"processing"}
                        // 仅当数据不以换行符结尾且非空时添加\n
                        buffer += event.data +'kkk';

                        buffers['CN'] = buffer;
                        // console.log('E,'+currentLang);
                        if(currentLang === 'CN') {
                            // 实时渲染以提供反馈
                            renderHepContent(currentLang, buffer);
                        }

                    }
                    if(event.data.includes('Summary generation finished')){
                        console.log('+++'+event.data);
                        buffers['CN'] = buffer;
                        if(currentLang === 'CN') {
                            renderHepContent(currentLang, buffer);
                        }
                        cnEventSource.close();
                        cnEventSource = null;
                        console.log("cnEventSource complete complete complete");
                    }
                };
                cnEventSource.onerror = function(err) {
                    console.log(err);
                    console.log("cnEventSource error complete");
                    cnEventSource.close();
                };
            }

        }else{
        
            const summaryUrl = `https://www.engineering.org.cn/engi/CN/api/article-ai/generate-summary-sse2?language=${language}&articleId=1159867208501355111&journalId=1155139928190095384`;
            console.log('尝试连接SSE:', summaryUrl);
            $("#showArticle_quickread_content_cn").html(
                '<p><span class="loading-spinner"></span> Loading summary...</p>'
            );
        
             // 用于拼接 SSE 数据
            if(language === 'CN'){
                let buffer = '';
                cnEventSource = new EventSource(summaryUrl, { withCredentials: true });
                cnEventSource.onmessage = function(event) {
                    if (event.data && event.data !== '[DONE]') {
                        // 仅当数据不以换行符结尾且非空时添加\n
                        buffer += event.data +'kkk';
                        buffers['CN'] = buffer;
                        // console.log('C,'+currentLang);
                        // 实时渲染以提供反馈
                        if(currentLang === 'CN') {
                            renderContent(currentLang, buffer);
                        }
                    }
                    
                    if(event.data.includes('执行完成')){
                        buffers['CN'] = buffer;
                        if(currentLang === 'CN') {
                            renderContent(currentLang, buffer);
                        }
                        cnEventSource.close();
                        cnEventSource = null;
                    }
                };
                
                cnEventSource.onerror = function(err) {
                    cnEventSource.close();
                    setTimeout(() => fetchSummaryData('CN'), 1000);
                };
            }else{
                let buffer = '';
                enEventSource = new EventSource(summaryUrl, { withCredentials: true });
                enEventSource.onmessage = function(event) {
                    if (event.data && event.data !== '[DONE]') {
                        // 仅当数据不以换行符结尾且非空时添加\n
                        buffer += event.data +'kkk';
                        
                        buffers['EN'] = buffer;
                        // console.log('E,'+currentLang);
                        if(currentLang === 'EN') {
                            // 实时渲染以提供反馈
                            renderContent(currentLang, buffer);
                        }
                        
                    }
                    if(event.data.includes('执行完成')){
                        buffers['EN'] = buffer;
                        if(currentLang === 'EN') {
                            renderContent(currentLang, buffer);
                        }
                        enEventSource.close();
                        enEventSource = null;
                    }
                };
                
                enEventSource.onerror = function(err) {
                    enEventSource.close();
                    setTimeout(() => fetchSummaryData('EN'), 1000);
                };
            }
        }
        
    }
    
    function checkHepJournalPage() {
        const { search, href } = window.location;
        const typeValue = new URLSearchParams(search).get('type');

        return true;
      
    }

    $(document).ready(function () {
        console.log('DOM 已加载，初始化事件监听');
        defaultLang = window.location.href.includes('/EN/') ? 'EN' : 'CN';
        // 初始化时获取数据
        fetchMindmapData();

        $("#AiSummaryBt").off('click').click(function() {
            obj.summaryCn = ''; // 重置中文数据
            obj.summaryEn = ''; // 重置英文数据
            currentLang = defaultLang; // 默认显示中文
            showQuickread(defaultLang);
            fetchSummaryData(defaultLang);
        });
    
        $("#showArticle_quickread_cn").click(function() {
            showQuickread('CN');
            currentLang='CN';
            if (buffers['CN'].length < 300) {
                 // 关闭现有EventSource连接
                if (cnEventSource) {
                    console.log('关闭现有SSE连接');
                    cnEventSource.close();
                    cnEventSource = null;
                }
                $("#showArticle_quickread_content_cn").html(
                    `<p>Loading ... </p>`
                );
               setTimeout(() => fetchSummaryData('CN'), 2000);

            }
        });
    
        $("#showArticle_quickread_en").click(function() {
            showQuickread('EN');
            if (buffers['EN'].length < 300) {
                // 关闭现有EventSource连接
                if (enEventSource) {
                    console.log('关闭现有SSE连接');
                    enEventSource.close();
                    enEventSource = null;
                }
                $("#showArticle_quickread_content_cn").html(
                    `<p>Loading ... </p>`
                );
                setTimeout(() => fetchSummaryData('EN'), 2000);

            } 
        });
    }); / 〈 〉 //渲染文章表格内容
    function renderArticleTable() {
        var articleTableList = document.getElementById("articleTextTableList");
        var articleTableDivList = null;
        if(articleTableList) {
            articleTableDivList = articleTableList.querySelectorAll("div");
        }
        //console.log(">>>>"+JSON.stringify(articleTableDivList));
        if(articleTableDivList) {
            for(tab of articleTableDivList) {
                //alert(tab.id);
                var divList = document.getElementsByTagName("div");
                for(articleDiv of divList) {

                    if(articleDiv.getAttribute("magId") && articleDiv.getAttribute("magId") == tab.id) {
                        //alert("magIdxxx:"+articleDiv.getAttribute("magId"));
                        articleDiv.innerHTML = tab.innerHTML;
                        //alert(tab.innerHTML);
                    }
                }

            }

        }
        articleTableList.innerHTML = '';
    }

    //渲染文章fig内容
    function renderArticleFig() {
        var articleFigList = document.getElementById("articleTextFigList");
        var articleFigDivList = null;
        if(articleFigList) {
            articleFigDivList = articleFigList.querySelectorAll("div");
        }

        if(articleFigDivList) {
            for(tab of articleFigDivList) {
                //alert(tab.id);
                var divList = document.getElementsByTagName("div");
                for(articleDiv of divList) {
                    if(articleDiv.getAttribute("magId") && articleDiv.getAttribute("magId") == tab.id) {
                        //alert("magIdxxx:"+articleDiv.getAttribute("magId"));
                        articleDiv.innerHTML = tab.innerHTML;
                        //alert(tab.innerHTML);
                    }
                }
            }

        }
        articleFigList.innerHTML = '';
    }


    $(function(){
          //js开始执行，将为爬虫准备的div清掉
        $("#article_text_4_crawl").empty();
        $("#cankaowenxianshdj").empty();
        
        
        $.ajax({
            url:'https://www.engineering.org.cn/engi/CN/api/site/data/article/collectionListByArticleId?journalId=1155139928190095384&articleId=1159867208501355111',
            type: 'GET',
            dataType: 'json',
            success: function(res) {
                //zhuantidiv_p
                $.each(res.listData, function(index, lis) {
                    $.each(lis.exts, function(index1, sty) {
                        if(sty.language == 'CN'){
                            if(sty.collectionTitle != null && sty.collectionTitle != ''){
                                $('#zhuantidiv').show();
                                $('#zhuantidiv_p').html('<a href="https://www.engineering.org.cn/engi/CN/collections/'+lis.id+'">'+sty.collectionTitle+'</a>');
                            }
                        }
                    });
                });
            },
            error: function(res) {
                console.log("查询阅读排行err:>>>"+JSON.stringify(res));
            },

        });
        var url = 'https://www.engineering.org.cn/engi/CN/api/site/data/article/text?articleId=1159867208501355111&language=CN';
        $.ajax({
            url: url,
            type: 'GET',
            dataType: 'json',
            success: function(res) {
                if(res.code==200 && res.data!=null && res.data.text!=null) {
                    $('#xiangqingyezhengwen').html(res.data.text);
                    //获取图片
                    if(res.data.figList!=null && res.data.figList!= ''){
                        $.each(res.data.figList, function(index, fig) {
                            var tupian ='';
                            var tielehtml ='';
                            var titleContenthtml ='';
                            var fullsize='';
                            var htmlzong ='';
                            var entitle=''
                            if(fig.figFile != null && fig.figFile != ''){
                                tupian = '<div class="main_content_center_left_zhengwen_bao_fig_img_bap"><img src="https://www.engineering.org.cn/engi/CN/file/pic?fileId='+fig.figFile+'" data-original="https://www.engineering.org.cn/engi/CN/file/pic?fileId='+fig.figFile+'" class="main_content_center_left_zhengwen_bao_fig_img" alt="" onclick="showimg(this)"></div>';
                                fullsize = '<a href="https://www.engineering.org.cn/engi/CN/file/pic?fileId='+fig.figFile+'" target="_blank">Full size  </a>';
                            }
                            if(fig.figExtMap.zh.title != null && fig.figExtMap.zh.title != ''){
                                tielehtml = '<b>'+fig.figExtMap.zh.title+'</b>';
                            }
                            if(fig.figExtMap.en.title != null && fig.figExtMap.en.title != ''){
                                entitle = '<div class="new_full_rich_table_title_cn" style="color:#666;"><b>'+fig.figExtMap.en.title+'</b></div>';
                            }
                            if(fig.figExtMap.zh.titleContent != null && fig.figExtMap.zh.titleContent != ''){
                                titleContenthtml='<p class="main_content_center_left_zhengwen_bao_fig_shuoming">'+fig.figExtMap.zh.titleContent+'</p>';
                            }
                            var caozuo = '<p class="new_full_rich_table_shuoming_caozuo">'+fullsize+'</p>';
                            htmlzong= '<div class="mag_fig_div main_content_center_left_zhengwen_bao_fig" id="'+fig.magId+'">'+tupian+'<div class="main_content_center_left_zhengwen_bao_fig_shuoming"><h5 class="cas_nav_daohang" style="width: 100%;text-align: center;font-size: 14px;float: none;">'+tielehtml+'</h5>'+entitle+titleContenthtml+'</div>'+caozuo+'</div>';
                            $('#articleTextFigList').append(htmlzong);

                        });
                    }
                    //获取表格
                    if(res.data.tabList!=null && res.data.tabList!= ''){
                        $.each(res.data.tabList, function(index, tab) {
                            var biaogetitle ='';
                            var tabsm='';
                            var tabhtml='';
                            var tablezong='';
                            var entitle = '';
                            if(tab.tableExtMap.zh.title != null){
                                biaogetitle='<h6 class="mag_nav_daohang cas_nav_daohang" style="font-size: 14px;width:100%;"><strong>'+tab.tableExtMap.zh.title+'</strong></h6>';
                            }
                            if(tab.tableExtMap.en.title != null){
                                entitle='<div class="new_full_rich_table_title_cn" style="text-align:center;"><b>'+tab.tableExtMap.en.title+'</b></div>';

                            }
                            if(tab.footFnList != null){
                                $.each(tab.footFnList, function(index2, foot) {
                                    tabsm='<div class="mag_table_wrap_foot_div new_full_rich_table_shuoming"><span class="biaocoin_shuoming_span">'+foot+'</span></div>';
                                });
                            }
                            if(tab.table != null){
                                tabhtml = '<div class="biaocoin_table">'+tab.table+'</div>';
                            }
                            tablezong = '<div id="'+tab.magId+'" class="mag_table_wrap new_full_rich_table" style="align: center;"><div class="biaocoin"><div class="biaocoin_shuoming nav_title" leave="2">'+biaogetitle+'</div>'+entitle+tabhtml+'</div>'+tabsm+'</div>';
                            $('#articleTextTableList').append(tablezong);
                        });
                    }
                    //获取参考文献
                    if(res.data.refList!=null && res.data.refList!= ''){
                        $.each(res.data.refList, function(index, refs) {
                            var suoyin = index+1;
                            var cankaowenxianhtml='';
                            var refhtml='';
                            $.each(refs.citationList, function(index1, ref) {
                                var biaoti ='';
                                var CrossrefADS='';
                                var Pubmed = '';
                                var arXiv1 = '';
                                if(ref.content != '' && ref.content != null){
                                    biaoti = '<p class="new_full_rich_cankaowenxian_title">'+ref.content+'</p>';
                                }
                                if(ref.doi != null && ref.doi != ''){
                                    CrossrefADS = '<span class="new_full_rich_cankaowenxian_zuozhe new_full_rich_cankaowenxian_lianjie" style="margin-right:10px;"><a target="__blank" href="https://doi.org/'+ref.doi+'">Crossref</a></span><span class="new_full_rich_cankaowenxian_zuozhe new_full_rich_cankaowenxian_lianjie" style="margin-right:10px;"><a target="__blank" href="https://ui.adsabs.harvard.edu/abs/'+ref.doi+'">ADS</a></span><span class="new_full_rich_cankaowenxian_zuozhe new_full_rich_cankaowenxian_lianjie" style="margin-right:10px;"><a target="__blank" href="https://scholar.google.com/scholar?q='+ref.doi+'">Google scholar</a></span>';
                                }
                                if(ref.pmid != null){
                                    Pubmed='<span class="new_full_rich_cankaowenxian_zuozhe new_full_rich_cankaowenxian_lianjie" style="margin-right:10px;"><a target="__blank" href="https://www.ncbi.nlm.nih.gov/pubmed/'+ref.pmid+'">Pubmed</a></span>'
                                }
                                if(ref.arXiv != null){
                                    arXiv1= '<a target="__blank" href="https://arxiv.org/abs/'+ref.arXiv+'">arXiv</a>';
                                }
                                
                                if(index1==0) {
                                    refhtml = biaoti+'<p class="new_full_rich_cankaowenxian_lianjie">'+CrossrefADS+Pubmed+arXiv1+'</p>';
                                
                                }else {
                                    refhtml +='<p class="new_full_rich_cankaowenxian_title">'+ref.content+'</p>';
                                }
                                
                                
                                
                            });
                            cankaowenxianhtml='<table class="main_content_center_left_one_cankaowenxian_tab" id="mag_rich_ref_'+refs.id+'" order-1-num="'+index+'" order-2-num="'+refs.year+'" order-3-num="'+refs.citedCount+'"> <tbody><tr style="border-bottom:1px dashed #d9d9d9;"><td class="main_content_center_left_one_cankaowenxian_tab_td" valign="top" width="7%">['+suoyin+']</td><td width="93%">'+refhtml+'</td></tr></tbody>';
                            $('#cankaowenxianshdj').append(cankaowenxianhtml);
                        });
                    }else{
                            $('.ckankaowenfdifn').remove()
                    }
                    if(res.data.ackList != '' && res.data.ackList != null){
                        $.each(res.data.ackList, function(index, akc) {
                            if(akc.ackExtMap.zh != null && akc.ackExtMap.zh != ''){
                                var html = '<div class="main_content_center_left_one_title zhengwem_title yijibiaotidkk"><h3 class="cas_nav_daohang"><b>'+akc.ackExtMap.zh.title+'</b></h3></div><p class="main_content_center_left_zhengwen_bao_zhengwen nozuish">'+akc.content+'</p>';
                                $('#ackListdiv').append(html)
                            }
                            
                        });
                    }
                    renderArticleFig()
                    renderArticleTable()
                    
                    /** 全文中类似这样的src替换掉 **/
                    //<img src="{{jo4FileInfo.file::+CmHHN9W16Xsfgrk4x8Okg==}}" class="mag_rich_graphic mag_rich_inline_graphic"/>
                    $('img').filter('.mag_rich_graphic').each(function(index) {
                        var src = $(this).attr('src');
                        src = src.replace("{{","");
                        src = src.replace("}}","");
                        src = src.replace("jo4FileInfo.file::","");
                        $(this).attr('src','https://www.engineering.org.cn/engi/CN/file/pic?fileId='+src);
                
                    });
                    
                    window.setTimeout(function(){

                        var menu = $('#autoMenu').data('autoMenu');
                        if (menu) {
                            // 重新生成HTML
                            $('#autoMenu').html(menu.createHtml());
                            // 重新设置活动项和绑定事件
                            menu.setActive();
                            menu.bindEvent();
                            mag_mathJax()
                        } else {
                            // 如果插件未初始化，则初始化
                            $('#autoMenu').autoMenu();
                            mag_mathJax()
                        }
                    },2000);
                    
                    
                }else{
                        $('.ckankaowenfdifn').remove()
                }

            },
            error: function(res) {
                console.log("查询阅读排行err:>>>"+JSON.stringify(res));
            },

        });
        
             var keywordsStr = "";
                        keywordsStr+=`Solid-state electrolytes`;
                            keywordsStr+=",";
                        keywordsStr+=`Solid-state sodium batteries`;
                            keywordsStr+=",";
                        keywordsStr+=`NASICON`;
                            keywordsStr+=",";
                        keywordsStr+=`Interface`;
                            keywordsStr+=",";
                        keywordsStr+=`Separator`;
                            keywordsStr+=",";
                        keywordsStr+=`Coating`;
        
        
        $.ajax({
            url: 'https://www.engineering.org.cn/engi/CN/api/site/data/article/recommendv2?journalId=1155139928190095384&articleId=1159867208501355111&keywordsStr='+keywordsStr,
            type:'GET',
            dataType:'json',
            success: function(res) {
                if(res.code!=200 || res.listData==null || res.listData.length<=0) {
                    return;
                }
                
                var index=0;
                for(var article of res.listData) {
                    if(article.id=='1159867208501355111') {
                        continue;
                    }
                    renderRecommendArticle(article,index);
                    index++;
                }
                
            }
            
            
        });
        
        
        
        /**
        $.ajax({
            url: 'https://www.engineering.org.cn/engi/CN/api/site/data/article/recommend?journalId=1155139928190095384&articleId=1159867208501355111',
            type: 'GET',
            dataType: 'json',
            success: function(res) {
                $.each(res.data, function(index, atc) {
                    var authorhtml='';
                    var titlehtml = '';
                    var kanming = '';
                    var issnht  ='';
                    var doihtml='';
                    if(atc.authors != null && atc.authors != ''){
                        $.each(atc.authors, function(index1, author) {
                            var isLast = $(this).is(':last');
                            if(author.ext.CN.stringName != null && author.ext.CN.stringName != ''){
                                if(isLast){
                                    authorhtml = authorhtml+author.ext.CN.stringName;
                                }else{
                                    authorhtml = authorhtml+author.ext.CN.stringName+', ';
                                }
                            }
                        });
                    }
                    if(atc.ext.CN.title != null && atc.ext.CN.title != ''){
                        titlehtml='<p class="new_full_rich_cankaowenxian_title"><a href="https://www.engineering.org.cn/engi/CN/'+atc.doi+'" target="_blank">'+atc.ext.CN.title+'</a></p>';
                    }
                    if(atc.ext.CN.journalTitle != null && atc.ext.CN.journalTitle != ''){
                        kanming = '<i>'+atc.ext.CN.journalTitle+'</i>. ';
                    }
                    if(atc.issue != null && atc.issue != ''){
                        var yrar = '';
                        var volume = '';
                        var issue = '';
                        var pageStart = '';
                        var pageEnd = '';
                        if(atc.issue.year!=null && atc.issue.year!=''){
                            yrar = atc.issue.year +', ';
                        }
                        if(atc.issue.volume!=null && atc.issue.volume!=''){
                            volume = 'Vol.'+atc.issue.volume;
                        }
                        if(atc.issue.issue!=null && atc.issue.issue!=''){
                            issue = '('+atc.issue.issue+'): ';
                        }
                        if(atc.issue.pageStart!=null && atc.issue.pageStart!=''){
                            pageStart =atc.issue.pageStart;
                        }
                        if(atc.issue.pageEnd!=null && atc.issue.pageEnd!=''){
                            pageEnd ='-'+atc.issue.pageEnd;
                        }
                        issnht = '<p class="new_full_rich_cankaowenxian_nianjuanqi">'+kanming+yrar+volume+issue+pageStart+pageEnd+'</p>';
                    }
                    if(atc.doi != null && atc.doi != ''){
                        doihtml = '<p class="new_full_rich_cankaowenxian_lianjie"><a href="https://doi.org/10.1007/'+atc.doi+'">https://doi.org/'+atc.doi+'</a></p>';
                    }
                    var shu = index+1;
                    var zong = '<tr><td class="main_content_center_left_one_cankaowenxian_tab_td" valign="top" style="width:28px">['+shu+']</td><td>'+authorhtml+titlehtml+issnht+doihtml+'</td></tr>';
                    $('#ckwxcankaowenxian_td').append(zong);
                });
            },
            error: function(res) {
                console.log("查询阅读排行err:>>>"+JSON.stringify(res));
            },

        });
        **/
    })
    $('#gallery').imagesLoaded(function() {
        $('#autoMenu').autoMenu();
    });





 //渲染recommend文章
    function renderRecommendArticle(article,index) {
        $.ajax({
            url:'https://www.engineering.org.cn/engi/CN/api/site/data/article/articleInfo?language=CN,EN&articleId='+article.id+"&journalId="+article.journalId,
            type:'GET',
            dataType:'json',
            success:function(res) {
                if(res.code!=200 || res.data==null) {
                    return;
                }
                    var atc = res.data;
                    var authorhtml='';
                    var titlehtml = '';
                    var kanming = '';
                    var issnht  ='';
                    var doihtml='';
                    if(atc.authors != null && atc.authors != ''){
                        $.each(res.data.authors, function(index1, author) {
                            if(author.ext==null || author.ext['CN'] == null) {
                                return;
                            }
                            var isLast = $(this).is(':last');
                            if(author.ext.EN.stringName != null && author.ext.CN.stringName != ''){
                                if(isLast){
                                    authorhtml = authorhtml+author.ext.CN.stringName;
                                }else{
                                    authorhtml = authorhtml+author.ext.CN.stringName+', ';
                                }
                            }
                        });
                    }
                    if(atc.ext!=null && atc.ext['CN']!=null && atc.ext.CN.title != null && atc.ext.CN.title != ''){
                        titlehtml='<p class="new_full_rich_cankaowenxian_title"><a href="'+atc.detailUrlCn+'" target="_blank">'+atc.ext.CN.title+'</a></p>';
                    }else if(atc.ext!=null && atc.ext['EN']!=null && atc.ext.EN.title != null && atc.ext.EN.title != '') {
                        titlehtml='<p class="new_full_rich_cankaowenxian_title"><a href="'+atc.detailUrlEn+'" target="_blank">'+atc.ext.EN.title+'</a></p>';
                    }
                    if(atc.ext.EN.journalTitle != null && atc.ext.EN.journalTitle != ''){
                        kanming = '<i>'+atc.ext.EN.journalTitle+'</i>. ';
                    }
                    if(atc.issue != null && atc.issue != ''){
                        var yrar = '';
                        var volume = '';
                        var issue = '';
                        var pageStart = '';
                        var pageEnd = '';
                        if(atc.issue.year!=null && atc.issue.year!=''){
                            yrar = atc.issue.year +', ';
                        }
                        if(atc.issue.volume!=null && atc.issue.volume!=''){
                            volume = 'Vol.'+atc.issue.volume;
                        }
                        if(atc.issue.issue!=null && atc.issue.issue!=''){
                            issue = '('+atc.issue.issue+'): ';
                        }
                        if(atc.issue.pageStart!=null && atc.issue.pageStart!=''){
                            pageStart =atc.issue.pageStart;
                        }
                        if(atc.issue.pageEnd!=null && atc.issue.pageEnd!=''){
                            pageEnd ='-'+atc.issue.pageEnd;
                        }
                        issnht = '<p class="new_full_rich_cankaowenxian_nianjuanqi">'+kanming+yrar+volume+issue+pageStart+pageEnd+'</p>';
                    }
                    if(atc.doi != null && atc.doi != ''){
                        doihtml = '<p class="new_full_rich_cankaowenxian_lianjie"><a href="https://doi.org/10.1007/'+atc.doi+'">https://doi.org/'+atc.doi+'</a></p>';
                    }
                    var shu = index+1;
                    var zong = '<tr orderNum="'+shu+'"><td class="main_content_center_left_one_cankaowenxian_tab_td" valign="top" style="width:28px">['+shu+']</td><td>'+authorhtml+titlehtml+issnht+doihtml+'</td></tr>';
                    $('#ckwxcankaowenxian_td').append(zong);
                    //排序   
                      // 1. 获取目标容器下的所有tr元素（转为数组方便排序）
                      const $container = $('#ckwxcankaowenxian_td');
                      const $trList = $container.find('tr');
                    
                      // 2. 对tr数组按orderNum属性升序排序
                      const sortedTr = $trList.sort(function(a, b) {
                        // 提取orderNum属性值，并转为数字（避免字符串排序问题，如"10"<"2"）
                        const orderA = Number($(a).attr('orderNum')) || 0; // 无属性时默认0
                        const orderB = Number($(b).attr('orderNum')) || 0;
                        // 升序：a-b；降序：b-a
                        return orderA - orderB;
                      });
                    
                      // 3. 清空原容器，重新插入排序后的tr（保持DOM结构干净）
                      $container.empty().append(sortedTr);
                    
            }
            
        });
        
        
    }


    //渲染数学公式
    function mag_mathJax(){
       MathJax.Hub.Queue(["Typeset", MathJax.Hub]);
        
        // 监听动态内容变化
        const observer = new MutationObserver(function(mutations) {
            MathJax.Hub.Queue(["Typeset", MathJax.Hub]);
        });
        
        observer.observe(document.body, {
            childList: true,
            subtree: true
        });

    }

    //渲染参考文献可视化分析
    function richRefCharts_year(){
        var catationListDom = document.getElementsByName("refCitationList");
        if(!catationListDom){
            return;
        }
        var xData = new Array();
        var yData = new Array();
        var typeData = new Array();
        var sourceData = new Array();
        var otherSourceCount = 0;
        var authorData = new Array();
        for(var i=0;i<catationListDom.length;i++) {
            var year = catationListDom[i].getAttribute("year");
            if(year != null) {
                year = year.trim();
                if(year == "") {
                    // break;
                }
            }else {
                break;
            }
            if(xData.length == 0) {
                xData[0] = year;
                yData[1] = 1;
            }else {
                var isnew = true;
                for(var j=0;j<xData.length;j++) {
                    if(xData[j] == year) {
                        yData[j] = yData[j]+1;
                        isnew = false;
                        break;
                    }
                }
                if(isnew) {
                    xData[xData.length] = year;
                    yData[yData.length] = 1;
                }
            }
        }
        var yearCountMap = new Map();
        for(var i=0;i<xData;i++) {
            yearCountMap.set(xData[i], yData[i]);
        }
        xData.sort((a,b)=>a-b);
        for(var i=0;i<xData;i++) {
            yData[i]=yearCountMap.get(xData[i]);
        }

        var dom = document.getElementById("mag_rich_ref_charts_nian_count");
        var myChart = echarts.init(dom);
        var app = {};
        var option;
        option = {
            tooltip: {
                trigger: 'axis',
                axisPointer: {
                    type: 'shadow'
                }
            },
            xAxis: {
                data: xData
            },
            yAxis: {
                type: 'value'
            },
            series: [{
                //name: '文献',
                type: 'bar',
                stack: 'browse',
                color: '#f07d2d',
                label:{
                    show:true,
                    position:'top',
                    color:'#000'
                },
                barWidth: '60%',
                data: yData
            }]
        };
        if (option && typeof option === 'object') {
            myChart.setOption(option);
        }
    }

    function richRefCharts_type() {
        var catationListDom = document.getElementsByName("refCitationList");
        if(!catationListDom){
            return;
        }
        var typeData = new Array();
        var typeDataMap = new Map();
        //typeData[0] = {name:'book 10%',value:10};
        //typeData[1] = {name:'report 90%',value:90};
        var typeDataTotal = 0;
        for(var i=0;i<catationListDom.length;i++) {
            typeDataTotal++;
            var pType = catationListDom[i].getAttribute("publicationType");
            if(typeDataMap.get(pType) != null) {
                typeDataMap.set(pType,typeDataMap.get(pType)+1);
            }else {
                typeDataMap.set(pType, 1);
            }
        }
        var idx = 0;
        for (const [key, value] of typeDataMap) {
            var par = value/typeDataTotal;
            par = par.toFixed(2);
            typeData[idx] = {name: key+" "+par+"%", value: value};
            idx++;
        }

        var dom = document.getElementById("mag_rich_ref_charts_publication_type");
        var myChart = echarts.init(dom);
        var app = {};
        var option;
        option = {
            tooltip: {
                trigger: 'item'
            },
            series: [
                {
                    type: 'pie',
                    radius: '70%',
                    data: typeData,
                    emphasis: {
                        itemStyle: {
                            shadowBlur: 10,
                            shadowOffsetX: 0,
                            shadowColor: 'rgba(0, 0, 0, 0.5)'
                        }
                    }
                }
            ]
        };

        if (option && typeof option === 'object') {
            myChart.setOption(option);
        }
    }

    //补引期刊分布
    function richRefCharts_source() {
        var dom = document.getElementById("mag_rich_ref_charts_source");
        var catationListDom = document.getElementsByName("refCitationList");
        if(!catationListDom){
            return;
        }
        var sourceDataMap = new Map();
        for(var i=0;i<catationListDom.length;i++) {
            var source = catationListDom[i].getAttribute("sourceList")
            if(!source || source == "" || source.length == 0) {
                continue;
            }
            var sourceList = source.split(",");
            for(var sName of sourceList) {
                if(sourceDataMap.get(sName)) {
                    sourceDataMap.set(sName, sourceDataMap.get(sName)+1);
                }else {
                    sourceDataMap.set(sName, 1);
                }
            }
        }

        var data = [
            //    {name: '清华大学', value: 100},
            //  {name: '浙江大学', value: 150},
            //{name: '上海交通大学', value: 90},
            // 更多数据...
        ];

        for(const [key,value] of sourceDataMap) {
            data.push({name: key, value: value});
        }

        //alert(JSON.stringify(data));
        $("#mag_rich_ref_charts_source").height(data.length*25+50);
        var myChart = echarts.init(dom);
        var app = {};
        var option;



        var option = {
            xAxis: {
                type: 'value', // 让 x 轴显示数值
                axisLabel: {
                    rotate: 45 // 可选，调整标签的旋转角度以便更好的显示
                }
            },
            yAxis: {
                type: 'category', // 让 y 轴显示类别
                data: data.map(item => item.name) // 从数据中提取类别名称作为 y 轴的数据
            },
            series: [{
                type: 'bar', // 使用柱状图类型
                data: data.map(item => item.value), // 从数据中提取数值作为柱状图的数据
                label: { // 可选，显示数值标签
                    show: true,
                    position: 'right' // 在柱状图的右侧显示数值标签
                }
            }],
            grid: {
                left: '30%',
                right: '17%',
                top: '8%',
                bottom: '15%'
                // containLabel: true
            },

        };

        if (option && typeof option === 'object') {
            myChart.setOption(option);
        }
    }


    function richRefCharts_author() {
        var authorData = [];//[{name:'zhangsan', count:21},{name:'李四', count:98}];
        var dom = document.getElementById("mag_rich_ref_charts_author");
        var catationListDom = document.getElementsByName("refCitationList");
        if(!catationListDom){
            return;
        }
        var authorMap = new Map();
        for(var i=0;i<catationListDom.length;i++) {
            var personList = catationListDom[i].getAttribute("personList");
            if(!personList|| personList == "" || personList.trim() == "") {
                continue;
            }
            var personListArr = personList.split(",");
            if(!personListArr || personListArr.length == 0) {
                continue;
            }
            for(var person of personListArr) {
                if(authorMap.get(person)) {
                    authorMap.set(person, authorMap.get(person)+1);
                }else {
                    authorMap.set(person, 1);
                }
            }
        }
        for(const [key,value] of authorMap) {
            authorData.push({name: key, count:value});
        }


        var nodes = new Array();
        if(authorData && authorData.length>0){
            authorData.sort(function(a,b){
                return b.count-a.count;
            });
            for(var authorDataIndex=0;authorDataIndex<authorData.length;authorDataIndex++){
                if(authorDataIndex<50){
                    var colorList = [
                        '#ff7f50', '#87cefa', '#da70d6', '#32cd32', '#6495ed',
                        '#ff69b4', '#ba55d3', '#cd5c5c', '#ffa500', '#40e0d0',
                        '#1e90ff', '#ff6347', '#7b68ee', '#d0648a', '#ffd700',
                        '#6b8e23', '#4ea397', '#3cb371', '#b8860b', '#7bd9a5'
                    ];
                    var color = colorList[authorDataIndex%colorList.length];
                    nodes[authorDataIndex] = {
                        id:'node'+authorDataIndex,
                        name:authorData[authorDataIndex].name,
                        value:authorData[authorDataIndex].count,
                        symbolSize:function(){
                            var size = 20+authorData[authorDataIndex].count*10;
                            if(size>50){
                                return 50;
                            }else{
                                return size;
                            }
                        }(),
                        draggable:true,
                        itemStyle:{
                            normal:{
                                //shadowBlur:10,
                                shadowColor:color,
                                color:color
                            }
                        }
                    };
                }
            }

            if(nodes.length>0){
                nodes.sort(function(a,b){
                    return a.value-b.value;
                });
            }

            var dom = document.getElementById("mag_rich_ref_charts_author");
            var myChart = echarts.init(dom, null, {
                renderer: 'canvas',
                useDirtyRect: false
            });
            var app = {};
            var option;
            option = {
                backgroundColor: '#fff',
                tooltip: {},
                animationDurationUpdate: function(idx) {
                    // 越往后的数据延迟越大
                    return idx * 100;
                },
                animationEasingUpdate: 'bounceIn',
                color: ['#fff', '#fff', '#fff'],
                series:{
                    type: 'graph',
                    layout: 'force',
                    force: {
                        repulsion: 30,
                        edgeLength: 3
                    },
                    gravity: 1.1,
                    scaling: 1.1,
                    roam: true,
                    label: {
                        normal: {
                            show: true
                        }
                    },
                    data:nodes
                }
            }

            if (option && typeof option === 'object') {
                myChart.setOption(option);
            }
        }
    }

    function generateWeixinUrl() {

    }
    function generateXueshuRul() {
        const elements = document.getElementsByClassName('ckwx_right');
        if(!elements || elements.length<=0) {
            return;
        }
        for(ele of elements) {
            //判断是否是右侧的弹出框参文献，有百度学术和google学术的跳转按钮
            var childrenDiv = ele.querySelectorAll("div");
            if(!childrenDiv) {
                continue;
            }
            var baiduA = null;
            var googleA = null;
            var articleTitle = null;
            for(ch of childrenDiv) {
                var chChList = ch.querySelectorAll("div");
                if(chChList) {
                    for(titleDiv of chChList) {
                        if(titleDiv.classList.contains("ckwx_right_div_article_title")) {
                            //console.log("文章标题>>>"+titleDiv.innerHTML);
                            articleTitle = titleDiv.innerHTML;
                            if(!articleTitle) {
                                articleTitle=" ";
                            }
                            break;
                        }
                    }
                }
                var aList = ch.querySelectorAll("a");
                if(!aList) {
                    continue;
                }
                for(a of aList) {
                    if((a.innerHTML+"").includes("百度学术")) {
                        // console.log(">>>"+a.innerHTML);
                        baiduA = a;
                    }
                    if((a.innerHTML+"").includes("谷歌学术")) {
                        // console.log(">>>"+a.innerHTML);
                        googleA = a;
                    }
                }
            }
            if(articleTitle) {
                articleTitle = articleTitle.trim();
            }
            if(!articleTitle) {
                articleTitle=" ";
            }
            if(baiduA && articleTitle) {
                var url = 'https://xueshu.baidu.com/s?wd=';
                var articleTitleEncode = encodeURIComponent(articleTitle);
                baiduA.href=url+articleTitleEncode;
            }
            if(googleA && articleTitle) {
                var url = 'https://scholar.google.com/scholar?lookup=0&q=';
                //把articleTitle中的空格变成+号
                var articleTitleEncode = encodeURIComponent(articleTitle.replace(/\s/g, '+'));
                googleA.href=url+articleTitleEncode;
                //console.log("替换空格为+号>>>"+(articleTitle.replace(' ', '+'))+"<<<<<<<")
            }
        }

    }

    $(document).ready(function() {
        mag_mathJax();
        renderArticleTable();
        //生成百度学术和谷歌学术url
        generateXueshuRul();
        //生成微信二维码图片
        generateWeixinUrl();
        //richRefCharts_year();
        //richRefCharts_type();
        //richRefCharts_source();
        //richRefCharts_author();
    });


    


    //公式序号 居右
    jQuery(".mag-xml-disp-formula").each(function() {
        var _this = jQuery(this);
        var _label= _this.children("label");
        if(typeof(_label.html())!="undefined"){
            _this.children("label").remove();
            _this.wrap("<div style='overflow:hidden;text-align: center;align-items:center;display:-webkit-flex;'><div style='float:left;text-align:center;width:90%;'></div></div>");
            _this.parent().parent().append("<span style='width:10%;text-align:right;'>"+_label.html()+"</span>");
        }
    });

    $('body').click(function(){
        $('.daochu_div').hide();
        $('.qipao').hide();
    })
    $('.qipao').click(function(event){
        event.stopPropagation();
    })

    /*参考文献显示隐藏*/
    $('.biaotijiantoush1').click(function(event){
        if($(this).attr('class')=='glyphicon glyphicon-triangle-top biaotijiantoush biaotijiantoush1'){
            $(this).parents('.mag_main_zhengwen_left_div_ckwx_table_benwenyiny').next('.mag_main_zhengwen_left_div_ckwx_table_ckwx_xiangqing').stop().slideUp();
            $(this).attr('class','glyphicon glyphicon-triangle-bottom biaotijiantoush biaotijiantoush1');
        }else if($(this).attr('class')=='glyphicon glyphicon-triangle-bottom biaotijiantoush biaotijiantoush1'){
            $(this).parents('.mag_main_zhengwen_left_div_ckwx_table_benwenyiny').next('.mag_main_zhengwen_left_div_ckwx_table_ckwx_xiangqing').stop().slideDown();
            $(this).attr('class','glyphicon glyphicon-triangle-top biaotijiantoush biaotijiantoush1');
        }
        event.stopPropagation();
    });


    function piaofuFn(a,fnId){
        var content='<div>'+$("#mag-rich-fn-"+fnId).html()+'</div>';
        piaofu(a,content);
    }

    function piaofuCnctst(a,cnctst_id){
        if($("#mag_rich_cnctst_info_"+cnctst_id) && $("#mag_rich_cnctst_info_"+cnctst_id).length && $("#mag_rich_cnctst_info_"+cnctst_id).length>0){
            var content='<div>'+$("#mag_rich_cnctst_info_"+cnctst_id).html()+'</div>';
            piaofu(a,content);
        }else{
            var div=document.createElement("div");
            div.style.display='none';
            div.id="mag_rich_cnctst_info_"+cnctst_id;
            document.body.appendChild(div);

            mag_ajax_update({
                selector:"#mag_rich_cnctst_info_"+cnctst_id,
                url:mag_currentQikanUrl() + "/CN/lexeme/showCnctstOnRich.do",
                data:{cnctst_id:cnctst_id,articleId:$("#articleId").val(),Count:5},
                success:function(){
                    var content='<div>'+$("#mag_rich_cnctst_info_"+cnctst_id).html()+'</div>';
                    piaofu(a,content);
                }
            });
        }
    }
    // 埋点管理器 - 防止重复调用
    const TrackingManager = {
        // 记录已发送的埋点事件
        sentEvents: new Set(),
        // 记录埋点调用次数
        callCount: 0,

        // 生成事件唯一标识
        generateEventKey(eventType, params) {
            const paramStr = Object.entries(params)
                .filter(([key]) => key !== 'timestamp') // 排除时间戳，避免每次都不同
                .sort(([a], [b]) => a.localeCompare(b))
                .map(([key, value]) => `${key}=${value}`)
                .join('|');

            return `${eventType}|${paramStr}`;
        },

        // 发送埋点并检查重复
        async sendEvent(eventType, params) {
            this.callCount++;
            console.log(`埋点调用 #${this.callCount}: ${eventType}`, params);

            const eventKey = this.generateEventKey(eventType, params);

            // 检查是否已发送过相同事件
            if (this.sentEvents.has(eventKey)) {
                console.warn(`重复埋点事件被拦截: ${eventType}`, params);
                return false;
            }

            // 记录已发送事件
            this.sentEvents.add(eventKey);

            try {
                // 实际发送埋点
                return await this._sendTrackingRequest(eventType, params);
            } catch (error) {
                // 发生错误时移除记录，允许重试
                this.sentEvents.delete(eventKey);
                throw error;
            }
        },

        // 实际发送埋点请求
        _sendTrackingRequest(eventType, params) {
            // 构建基础埋点数据
            const baseParams = {
                tenantId: "1045748351789510663",
                journalId: "1155139928190095384",
                articleId: "1159867208501355111",
                eventType: eventType,
                timestamp: new Date().toISOString(),
                userId: this._getUserId() || "unknown",
            };

            // 合并自定义参数
            const finalParams = { ...baseParams, ...params };

            // 将参数对象转换为URL查询字符串
            const queryString = Object.entries(finalParams)
                .map(([key, value]) => `${key}=${encodeURIComponent(value)}`)
                .join('&');

            // 完整的埋点URL
            const trackUrl = `https://www.engineering.org.cn/engi/CN/statistics/point/articleDetailPoint?${queryString}`;

            return new Promise((resolve, reject) => {
                const img = new Image();
                img.onload = () => {
                    console.log(`埋点发送成功: ${eventType}`, trackUrl);
                    resolve(true);
                };
                img.onerror = () => {
                    console.warn(`埋点发送失败: ${eventType}`, trackUrl);
                    reject(new Error('埋点请求失败'));
                };
                img.src = trackUrl;
            });
        },

        // 获取用户ID
        _getUserId() {
            return localStorage.getItem('userId') || sessionStorage.getItem('userId');
        }
    };

    // 统一的埋点函数
    async function trackEvent(eventType, customParams = {}) {
        return TrackingManager.sendEvent(eventType, customParams);
    }

    // 页面加载完成后自动发送埋点事件
    document.addEventListener('DOMContentLoaded', async () => {
        // 检查是否已经初始化过
        if (window.__trackingInitialized) {
            console.warn('埋点初始化已执行过，跳过重复执行');
            return;
        }

        window.__trackingInitialized = true;

        try {
            // 发送pageview事件
            await trackEvent('pageview', {
                pageTitle: document.title,
                screenWidth: window.innerWidth,
                screenHeight: window.innerHeight,
                userAgent: navigator.userAgent,
                referrer: document.referrer,
            });

            // 记录页面加载时间
            const pageLoadTime = performance.timing.loadEventEnd - performance.timing.navigationStart;
            await trackEvent('page_load_time', {
                loadTime: pageLoadTime,
            });

            // 示例：3秒后发送time_spent事件
            const startTime = Date.now();
            setTimeout(async () => {
                const elapsedTime = Date.now() - startTime;
                await trackEvent('time_spent', {
                    milliseconds: elapsedTime,
                });
            }, 3000);
        } catch (error) {
            console.error('埋点发送过程中出错:', error);
        }
    });

    $("#mag_rich_ref_charts").hide();


    $(function(){
        //$('#autoMenu').autoMenu();
    })
    $("#autoMenu").niceScroll({
        cursorcolor: "#ccc", //滚动条的颜色
        cursoropacitymax: 0, //滚动条的透明度，从0-1
        touchbehavior: false, //使光标拖动滚动像在台式电脑触摸设备 true滚动条拖动不可用
        cursorwidth: "6px", //滚动条的宽度  单位默认px
        cursorborder: "0", // 游标边框css定义
        cursorborderradius: "3px", //滚动条两头的圆角
        autohidemode: true, //是否隐藏滚动条  true的时候默认不显示滚动条，当鼠标经过的时候显示滚动条
        zindex: "auto", //给滚动条设置z-index值
        railvalign:'defaul',
        railpadding: {
            top: 0,
            right: -6,
            left: 0,
            bottom: 0
        }, //滚动条的位置
    });
    $("#ckwxcankaowenxian").niceScroll({
        cursorcolor: "#ccc", //滚动条的颜色
        cursoropacitymax: 0, //滚动条的透明度，从0-1
        touchbehavior: false, //使光标拖动滚动像在台式电脑触摸设备 true滚动条拖动不可用
        cursorwidth: "6px", //滚动条的宽度  单位默认px
        cursorborder: "0", // 游标边框css定义
        cursorborderradius: "3px", //滚动条两头的圆角
        autohidemode: true, //是否隐藏滚动条  true的时候默认不显示滚动条，当鼠标经过的时候显示滚动条
        zindex: "auto", //给滚动条设置z-index值
        railvalign:'defaul',
        railpadding: {
            top: 0,
            right: -6,
            left: 0,
            bottom: 0
        }, //滚动条的位置
    }); let score;
    let tempData2;
    let targetUrl = '';

    document.addEventListener('DOMContentLoaded', function() {
        return ;
        score = null;

        fetch(`https://www.engineering.org.cn/engi/CN/api/journal/article/getAltmetricToken?articleId=1159867208501355111`)
            .then(response => {
                if (!response.ok) throw new Error('第一个接口调用失败');
                return response.json();
            })
            .then(data1 => {
                data1.articleId = String(data1.articleId);
                console.log('第一个接口返回:', data1);
                if (data1.status !== 200 || !data1.token) throw new Error('第一个接口token无效');

                return fetch(`https://www.engineering.org.cn/engi/CN/api/journal/article/getAltmetricInfo?articleId=1159867208501355111&token=${data1.token}`);
            })
            .then(response => {
                if (!response.ok) throw new Error('第二个接口调用失败');
                return response.json();
            })
            .then(data2 => {
                console.log('第二个接口返回:', data2);

                if (!data2 || typeof data2 !== 'object') {
                    throw new Error('第二个接口返回格式不正确');
                }

                // 逻辑分支1：没有request对象时，直接查score（不走后续接口）
                if (!data2.request || typeof data2.request !== 'object') {
                    console.log('无request对象，直接查询score');
                    // 这里假设score从data2中获取，实际根据接口返回调整
                    score = data2.score !== undefined ? data2.score : null;
                    displayScore(score);
                    return null; // 返回null终止后续链式调用
                }

                // 逻辑分支2：有request对象时，检查current_art
                console.log('存在request对象，检查current_art状态');
                const currentArt = data2.request.current_art;

                // 2.1 current_art为false时，直接查score（不走后续接口）
                if (currentArt === false) {
                    console.log('current_art为false，直接查询score');
                    score = data2.score !== undefined ? data2.score : null;
                    displayScore(score);
                    return null; // 返回null终止后续链式调用
                }

                // 2.2 current_art为true时，走原逻辑（调用第三方和第三个接口）
                if (currentArt === true) {
                    console.log('current_art为true，执行原逻辑');
                    if (!data2.request.token) {
                        throw new Error('第二个接口request中缺少token');
                    }
                    if (!data2.request.doi) {
                        throw new Error('第二个接口request中缺少doi');
                    }

                    tempData2 = data2;
                    const doi = data2.request.doi;
                    const encodedDoi = encodeURIComponent(doi);
                    const url = `https://api.altmetric.com/v1/doi/${encodedDoi}`;

                    return fetch(url, { method: 'GET', mode: 'cors' })
                        .then(altmetricResponse => {
                            console.log(`第三方接口返回状态: ${altmetricResponse.status}`);
                            return altmetricResponse.json().catch(() => {
                                return { status: altmetricResponse.status, error: '非JSON响应' };
                            });
                        });
                }

                // 2.3 current_art未定义时，默认直接查score
                console.log('current_art未定义，默认查询score');
                score = data2.score !== undefined ? data2.score : null;
                displayScore(score);
                return null;
            })
            .then(altmetricData => {
                // 如果前面返回null，直接终止
                if (altmetricData === null) {
                    console.log('流程已终止，不执行后续接口调用');
                    return;
                }

                // 后续逻辑：处理第三方接口返回并调用第三个接口
                console.log('第三方接口返回:', altmetricData);
                score = altmetricData.score !== undefined ? altmetricData.score : null;
                displayScore(score);

                const formData = new FormData();
                formData.append('articleId', tempData2?.request?.id || '');
                formData.append('token', tempData2?.request?.token || '');
                formData.append('altmetricInfo', JSON.stringify(altmetricData));

                return fetch(`https://www.engineering.org.cn/engi/CN/api/journal/article/submitArticlePlumxInfo`, {
                    method: 'POST',
                    body: formData
                })
                    .then(response => {
                        console.log(`第三个接口返回状态: ${response.status}`);
                        return response.json().catch(() => ({ status: response.status, error: '非JSON响应' }));
                    });
            })
            .then(data3 => {
                if (data3) {
                    console.log('第三个接口返回:', data3);
                }
                if (targetUrl && typeof targetUrl === 'string' && targetUrl.trim() !== '') {
                    window.open(targetUrl, '_blank');
                }
            })
            .catch(error => {
                console.error('接口调用出错:', error);
                displayScore(null);
                if (targetUrl && typeof targetUrl === 'string' && targetUrl.trim() !== '') {
                    window.open(targetUrl, '_blank');
                }
            });
    });

    function displayScore(scoreValue) {
        if(scoreValue && scoreValue>0){
            if(scoreValue - parseInt(scoreValue) > 0){
                $("#altmetric-shu").html(parseInt(scoreValue)+1);
            }else{
                $("#altmetric-shu").html(parseInt(scoreValue));
            }
            $("#altmetric-div").show();
        }


    }



    (function ($) {
        var Menu = (function () {
            /**
             * @constructor
             */
            var Plugin = function(element, options) {
                this.$element = $(element);
                this.settings = $.extend({}, $.fn.autoMenu.defaults, typeof options === 'object' && options)
                this.init();
            }
            /**
             */
            Plugin.prototype = {
                init: function () {
                    var opts = this.settings;
                    this.$element.html(this.createHtml());
                    this.setActive();
                    this.bindEvent();
                },
                createHtml: function(){
                    var that = this;
                    var opts = that.settings;
                    var width = typeof opts.width === 'number' && opts.width;
                    var height = typeof opts.height === 'number' && opts.height;
                    var padding = typeof opts.padding === 'number' && opts.padding;
                    that.$element.width('100%');
                    var html = '<ul class="cas_nav_ul">';
                    var num = 0;
                    var shu="";
                    $('.cas_nav_daohang').each(function(){
                        var _this = $(this);
                        if(_this.get(0).tagName == opts.levelOne.toUpperCase()){
                            _this.attr('id',num);
                            shu= num
                            var nodetext = that.handleTxt(_this.html());
                            html += '<li class="yiji dianjinav_'+shu+'" name="'+ num +'" title="'+ nodetext +'"><a href="#'+ num +'" onclick="li_click(this)">'+ nodetext +'</a></li>';
                            num++;
                        }else if(_this.get(0).tagName == opts.levelTwo.toUpperCase()){
                            _this.attr('id',num);
                            var nodetext = that.handleTxt(_this.html());
                            html += '<li class="sub dianjinav_'+shu+'" name="'+ num +'" title="'+ nodetext +'"><a href="#'+ num +'" onclick="li_click(this)">'+ nodetext +'</a></li>';
                            num++;
                        }else if(_this.get(0).tagName == opts.levelThree.toUpperCase()){
                            _this.parents('.mag_rich_body_p').attr('id',num);
                            var nodetext = that.handleTxt(_this.html());
                            html += '<li class="sub_sanji dianjinav_'+shu+'" name="'+ num +'" title="'+ nodetext +'"><img src="https://cjournal.hep.com.cn/hep_journal_fop_en/img/img_nav.png" class="cas_nav_img_icon" alt="" /><a href="#'+ num +'" onclick="li_click(this)">'+ nodetext +'</a></li>';
                            num++;
                        }else if(_this.get(0).tagName == opts.levelFour.toUpperCase()){
                            _this.attr('id',num);
                            var nodetext = that.handleTxt(_this.html());
                            html += '<li class="sub_sanji dianjinav_'+shu+'" name="'+ num +'" title="'+ nodetext +'"><img src="https://cjournal.hep.com.cn/hep_journal_fop_en/img/table_nav.png" class="cas_nav_img_icon" alt="" /><a href="#'+ num +'" onclick="li_click(this)">'+ nodetext +'</a></li>';
                            num++;
                        }else if(_this.get(0).tagName == opts.levelFive.toUpperCase()){
                            _this.parent('.main_content_center_left_div_img_shuoming').siblings('.cas_zw_img_img').attr('id',num);
                            var nodetext = that.handleTxt(_this.html());
                            html += '<li class="sub_sanji dianjinav_'+shu+'" name="'+ num +'" title="'+ nodetext +'"><img src="https://cjournal.hep.com.cn/hep_journal_fop_en/img/video.png" style="width:18px;height:12px;" class="cas_nav_img_icon" alt="" /><a href="#'+ num +'" onclick="li_click(this)">'+ nodetext +'</a></li>';
                            num++;
                        }
                    })
                    html += '</ul>';
                    return html;
                },
                handleTxt: function(txt){
                    //姝ｅ垯琛ㄨ揪寮忓幓闄TML鐨勬爣绛�
                    return txt.replace(/<\/?[^>]+>/g,"").trim();
                },
                setActive: function(){
                    var $el = this.$element,
                        opts = this.settings,
                        items = opts.levelOne + ',' + opts.levelTwo +',' + opts.levelThree+',' + opts.levelFour+',' + opts.levelFive,
                        $items = $(items),
                        offTop = opts.offTop,
                        headLen = $('.cas_nav_daohang').length,
                        allEle = $('.cas_nav_daohang'),
                        top = $(document).scrollTop()+$('.yicangdsjk').height(),
                        currentId;
                    for (var i=headLen-1; i>=0; i--) {
                        if ($(window).scrollTop() >= allEle.eq(i).offset().top-$('.yicangdsjk').height() + allEle.eq(i).height()-allEle.eq(i).height()-150) {
                            var index = i;
                            $('#autoMenu ul li').eq(index).addClass('active').siblings('li').removeClass('active').siblings('.erji_div').children('li').removeClass('active');
                            return false;
                        } else {
                            $('#autoMenu ul li').eq(0).addClass('active').siblings('li').removeClass('active').siblings('.erji_div').children('li').removeClass('active');
                        }
                    }
                    $items.each(function(){
                        var m = $(this),
                            itemTop = m.offset().top;
                        if(top > itemTop-offTop){
                            currentId = m.attr('id');
                        }else{
                            return false;
                        }
                    })
                    var currentLink = $el.find('.active');
                },
                bindEvent: function(){
                    var _this = this;
                    $(window).scroll(function(){
                        _this.setActive();
                        var nav = $("#autoMenu");
                        var articleNav = nav.find('.active');
                        if (articleNav && articleNav.length > 0) {
                            var navItemtop = articleNav.position().top+89;
                            var navItemtop1 = articleNav.position().top;
                            var navItemHeight = articleNav.height();
                            var navItemBottom = navItemtop + navItemHeight  + 20;
                            console.log(navItemtop);
                            var scrollNav = $('#autoMenu');
                            var navScrollPos = scrollNav.scrollTop();
                            if (navItemBottom >= $(window).height()) {
                                scrollNav.scrollTop(navScrollPos + navItemHeight);
                            }
                            else if (navItemtop1 < 20) {
                                scrollNav.scrollTop(navScrollPos - navItemHeight);
                            }
                        }
                    });
                    _this.$element.on('click','.btn-box',function(){
                        if($(this).find('span').hasClass('icon-minus-sign')){
                            $(this).find('span').removeClass('icon-minus-sign').addClass('icon-plus-sign');
                            _this.$element.find('ul').fadeOut();
                        }else{
                            $(this).find('span').removeClass('icon-plus-sign').addClass('icon-minus-sign');
                            _this.$element.find('ul').fadeIn();
                        }

                    })
                }

            };
            return Plugin;
        })();


        /**
         * 杩欓噷鏄皢Plugin瀵硅薄 杞负jq鎻掍欢鐨勫舰寮忚繘琛岃皟鐢�
         * 瀹氫箟涓€涓彃浠� plugin
         */
        $.fn.autoMenu = function (options) {
            return this.each(function () {
                var $el = $(this),
                    menu = $el.data('autoMenu'),
                    option = $.extend({}, $.fn.autoMenu.defaults, typeof options === 'object' && options);
                if (!menu) {
                    //灏嗗疄渚嬪寲鍚庣殑鎻掍欢缂撳瓨鍦╠om缁撴瀯閲岋紙鍐呭瓨閲岋級
                    $el.data('autoMenu',new Menu(this, option));
                }

                /**
                 * 濡傛灉鎻掍欢鐨勫弬鏁版槸涓€涓瓧绗︿覆锛屽垯 璋冪敤 鎻掍欢鐨� 瀛楃涓叉柟娉曘€�
                 * 濡� $('#id').plugin('doSomething') 鍒欏疄闄呰皟鐢ㄧ殑鏄� $('#id).plugin.doSomething();
                 */
                if ($.type(options) === 'string') menu[option]();
            });
        };

        /**
         * 鎻掍欢鐨勯粯璁ゅ€�
         */
        $.fn.autoMenu.defaults = {
            levelOne : 'h3', //涓€绾ф爣棰�
            levelTwo : 'h4',  //浜岀骇鏍囬锛堟殏涓嶆敮鎸佹洿澶氱骇锛�
            levelThree : 'h5',  //浜岀骇鏍囬锛堟殏涓嶆敮鎸佹洿澶氱骇锛�
            levelFour : 'h6',  //浜岀骇鏍囬锛堟殏涓嶆敮鎸佹洿澶氱骇锛�
            levelFive : 'h7',  //浜岀骇鏍囬锛堟殏涓嶆敮鎸佹洿澶氱骇锛�
            padding: 20, //鍐呴儴闂磋窛
            offTop : 100, //婊氬姩鍒囨崲瀵艰埅鏃剁椤堕儴鐨勮窛绂�

        };

        /**
         * 浼橀泤澶勶細 閫氳繃data-xxx 鐨勬柟寮� 瀹炰緥鍖栨彃浠躲€�
         * 杩欐牱鐨勮瘽 鍦ㄩ〉闈笂灏变笉闇€瑕佹樉绀鸿皟鐢ㄤ簡銆�
         * 鍙互鏌ョ湅bootstrap 閲岄潰鐨凧S鎻掍欢鍐欐硶
         */

    })(jQuery);




    $(function(){
        var wid = $('.main_content_center_left').width();
        $('.main_content_center_left_yinyong_bao').width(wid*$('.main_content_center_left_yinyong_div').length);
        for(var t =0;t<$('.main_content_center_left_yinyong_div').length;t++){
            $('.main_content_center_left_yinyong_div').eq(t).width(wid);
        }
        var wid = $('.main_content_center_left').width();
        var bodywidth= $('body').width();
        var yemianwidth= $('.main_content').width();
        $('.qipao').width(wid-40);
        var zhongs = (bodywidth-yemianwidth)/2+15;
        $('.qipao').css({'left':zhongs+5});

    })
    function li_click(a){
        var index = $('.cas_nav_ul li a').index($(a));

        var top_height= $('.yicangdsjk').height();
        var ddIndex = $(a).stop().attr('href').lastIndexOf('#');
        var ddId = $(a).stop().attr('href').substring(ddIndex+1);
        console.log(ddId)
        var windowTop = $('#' + ddId + '').offset().top-50-top_height;
        $('body,html').animate({scrollTop: windowTop}, 'fast');
    }
    var gao = "";
    var win_height="";
    var diheight="";
    var heigthzhengwen= "";
    var document_height="";
    window.onload=function(){
        heigthzhengwen=$('.main_content_center').find('.main_content_center_left').height();
        gao = $('.huoquoffset').offset().top;
        document_height = $('body').height();
        diheight= $('.main_content_bottom').offset().top;
        var win_height = $(window).height();
        var pisus =$('.yicangdsjk').css('position');
        var t = document.documentElement.scrollTop || document.body.scrollTop-$('.yicangdsjk').height();
        if(pisus=="fixed" && t>$('.yicangdsjk').height()){
            $('#huoqudndkk').height(win_height-$('.yicangdsjk').height()-30);
        }else{
            $('#huoqudndkk').height(win_height-30);
        }

        var width= $('.main_content_center_right').width();
        $('#autoMenu').height($('#huoqudndkk').height()-30);
        $('#ckwxcankaowenxian').height($('#huoqudndkk').height()-30);
        var wid = $('.main_content_center_left').width();
        var bodywidth= $('body').width();
        var yemianwidth= $('.main_content').width();
        $('.qipao').width(wid-30);
        var zhongs = (bodywidth-yemianwidth)/2+15;
        $('.qipao').css({'left':zhongs});
        for(var a = 0;a<$('.main_content_center_left_zhengwen_bao_fig_img').length;a++){
            var widt= $('.main_content_center_left_zhengwen_bao_fig_img').eq(a).width();
            var fwit = $('.main_content_center_left').width();
            if(widt>fwit){
                if(600>fwit){
                    $('.main_content_center_left_zhengwen_bao_fig_img').eq(a).css('width','100%');
                }else{
                    $('.main_content_center_left_zhengwen_bao_fig_img').eq(a).css('width','600px');
                }
            }else if(widt<fwit){
                if(600>widt){
                    $('.main_content_center_left_zhengwen_bao_fig_img').eq(a).css('width',widt+'px');
                }else{
                    $('.main_content_center_left_zhengwen_bao_fig_img').eq(a).css('width','600px');
                }
            }
        }
        for(var i =0;i<$('.yiji').length;i++){
            if($('.yiji').eq(i).next('li').hasClass("sub") || $('.yiji').eq(i).next('li').hasClass("sub_sanji")){
                $('.yiji').eq(i).append('<i class="glyphicon glyphicon-triangle-bottom nav_i" onclick="click_nav_daidn(this);"></i>');
            }
        }
    }
    var zhid =1;
    function closedk(a) {
        var height = $('.yicangdsjk').height();
        var height1 = $('#huoqudndkk').height();
        $('.yicangdsjk').fadeOut();
        $('#huoqudndkk').css('top','0');
        $('#huoqudndkk').height(height1+height);
        zhid =0;
    }
    function click_nav_daidn(a){
        var name_num=$(a).parent('li').attr("name");
        var cla= ".dianjinav_"+name_num;
        if($(a).attr("class")=="glyphicon glyphicon-triangle-bottom nav_i"){
            for(var i =0;i<$(cla).length;i++){
                $(a).parent('li').siblings(cla).slideUp();
            }
            $(a).attr('class','glyphicon glyphicon-triangle-top nav_i');
        }else if($(a).attr("class")=="glyphicon glyphicon-triangle-top nav_i"){
            for(var i =0;i<$(cla).length;i++){
                $(a).parent('li').siblings(cla).slideDown();
            }
            $(a).attr('class','glyphicon glyphicon-triangle-bottom nav_i');
        }
    }
    function resetLayout() {
        var bdidhjfwidth =  document.body.clientWidth;
        var width1=$('.main_content_center_right').width();
        var now_doc_height = $('body').height();
        var t = document.documentElement.scrollTop || document.body.scrollTop;
        if( bdidhjfwidth > 1050){
            if(t>$('.huoquoffset').offset().top){
                if(zhid==1){
                    $('.yicangdsjk').slideDown();
                }
                $('#huoqudndkk').addClass('fixed');
                $('#huoqudndkk').css('width',width1);
            }else{
                $('#huoqudndkk').removeClass('fixed');
                $('.yicangdsjk').slideUp();
            }
        }else{
            if($('.shoujihadhjsdj') && $('.shoujihadhjsdj').length && $('.shoujihadhjsdj').length>0){
                var odhdjf = $('.shoujihadhjsdj').offset().top;
                if(t>=odhdjf){
                    $('.yicangdsjk').slideDown();
                }else{
                    $('.yicangdsjk').slideUp();
                }
            }
        }

    }
    $(window).scroll(function () {
        var heigthzhengwen_jian= $('.main_content_center').find('.main_content_center_left').height();
        resetLayout();
        $('#autoMenu').autoMenu();
        var heigh=$('.main_content_top').offset().top;
        var t = document.documentElement.scrollTop || document.body.scrollTop;
        var top_height= $('.yicangdsjk').height();
        var shishidibu= $('.main_content_bottom').offset().top;
        var c ="";
        $('#autoMenu').height($('#huoqudndkk').height()-40);
        $('#ckwxcankaowenxian').height($('#huoqudndkk').height()-40);
        var nav_off_top = $('.huoquoffset').offset().top;
        if(t>heigh){
            if(zhid == 1){
                $('#huoqudndkk').css('top',top_height+20);
            }
            var win_height = $(window).height();
            if(zhid == 1){
                $('#huoqudndkk').height(win_height-top_height-50);
            }else{
                $('#huoqudndkk').height(win_height-top_height-80);
            }
            c = $('.main_content_bottom').height();
        }
        if(heigthzhengwen==heigthzhengwen_jian){
            var b = shishidibu-t-$('.yicangdsjk').height()-50;
            if(t>diheight-$('.main_content_bottom').height()-$('.yicangdsjk').height()*7-30){
                if(zhid == 1){
                    $('#huoqudndkk').height(b);
                }
                $('#autoMenu').height($('#huoqudndkk').height()-40);
                $('#ckwxcankaowenxian').height($('#huoqudndkk').height()-40);
            }
        }else{
            var cha =heigthzhengwen-heigthzhengwen_jian;
            if(zhid == 1){
                var b = shishidibu-t-$('.yicangdsjk').height()-90;
            }else{
                var b = shishidibu-t-$('.yicangdsjk').height();
            }
            if(t>diheight-cha-$('.main_content_bottom').height()-$('.yicangdsjk').height()*9-30){
                $('#huoqudndkk').height(b);
                $('#autoMenu').height($('#huoqudndkk').height()-40);
                $('#ckwxcankaowenxian').height($('#huoqudndkk').height()-40);
            }
        }


    })
    $(window).resize(function() {
        resetLayout()
        var width1=$('.main_content_center_right').width();
        $('#huoqudndkk').css('width',width1);
        var wid = $('.main_content_center_left').width();
        $('.main_content_center_left_yinyong_bao').width(wid*$('.main_content_center_left_yinyong_div').length);
        for(var t =0;t<$('.main_content_center_left_yinyong_div').length;t++){
            $('.main_content_center_left_yinyong_div').eq(t).width(wid);
        }
        var wid = $('.main_content_center_left').width();
        var bodywidth= $('body').width();
        var yemianwidth= $('.main_content').width();
        $('.qipao').width(wid-40);
        var zhongs = (bodywidth-yemianwidth)/2+15;
        $('.qipao').css({'left':zhongs+5});
    });
    /* 寮曠敤鏈枃涓嬩竴绡� */
    var index = 0;
    function xiayipian(){
        var a = $('.main_content_center_left_yinyong_div').length;
        var wid = $('.main_content_center_left').width();
        var zong = $('.main_content_center_left_yinyong_bao').width();
        var left = $('.main_content_center_left_yinyong_bao').css('left');
        var left1 = left.replace(/px/ig, '');
        var left2 = left1.replace(/-/ig, '');
        if(index*1+1 != a){
            $('.main_content_center_left_yinyong_bao').animate({left:"-="+wid});
            index = index+1;
        }else{
           // alert("鏈€鍚庝竴涓�");

        }
    }
    /* 寮曠敤鏈枃涓婁竴绡� */
    function shangyipian(){
        var wid = $('.main_content_center_left').width();
        var zong = $('.main_content_center_left_yinyong_bao').width();
        var left = $('.main_content_center_left_yinyong_bao').css('left');
        var left1 = left.replace(/px/ig, '');
        var left2 = left1.replace(/-/ig, '');
        if(index*1-1 >= 0){
            $('.main_content_center_left_yinyong_bao').animate({left:"+="+wid});
            index = index-1;
        }else{
           // alert("绗竴涓�")
        }
    }
    /* 涓嬫媺妗嗛€夋嫨瀵艰埅 */
    function Jump(a){
        var id = $(a).attr('value');
        var windowTop = $('#' + id +'').offset().top-10;
        $('body,html').animate({scrollTop: windowTop}, 'fast');
    }

    function slide_up(a){
        if($(a).html()== "+"){
            $(a).parent('.Author_contribution').next('.Author_contribution_content').stop().slideDown("slow");
            $(a).html('-')
        }else if($(a).html()== "-"){
            $(a).parent('.Author_contribution').next('.Author_contribution_content').stop().slideUp("slow");
            $(a).html('+')
        }
    }

    function Author_details_put_away(a){
        $(a).parent('.Author_contribution_content').stop().slideUp("slow");
        $(a).parent('.Author_contribution_content').prev('.Author_contribution').find('i').attr('class','glyphicon glyphicon-menu-down');
    }

    function zhaiyaozhan(a){
        if($(a).attr('class') == "glyphicon glyphicon-minus main_content_center_left_one_title_i"){
            $(a).parent('.main_content_center_left_one_title').next('.zhaiyaojs').stop().slideUp("slow");
            $(a).attr('class','glyphicon glyphicon-plus main_content_center_left_one_title_i');
        }else if($(a).attr('class') == "glyphicon glyphicon-plus main_content_center_left_one_title_i"){
            $(a).parent('.main_content_center_left_one_title').next('.zhaiyaojs').stop().slideDown("slow");
            $(a).attr('class','glyphicon glyphicon-minus main_content_center_left_one_title_i');
        }
    }

    function daochu_div(a,event){
        var top = $(a).offset().top;
        var left = $(a).offset().left;
        $('.daochu_div').css({'top':top+30,'left':left});
        $('.daochu_div').stop().slideDown("slow");
        event.stopPropagation();
    }

    $('body').click(function(){
        $('.daochu_div').hide();
        $('.qipao').hide();
    })
    $('.qipao').click(function(event){
        event.stopPropagation();
    })



    function guanbiann(){
        $('.new_full_rich_model').hide();
        $('.new_full_rich_motaikuang').hide();
    }


    function  dianjitab(a,b){
        $(a).css({'background':'#dceefb','border-top':'2px solid #2992e2'}).siblings('.main_content_center_right_duoweidu_div').css({'background':'#f0f7fc','border-top':'2px solid #f0f7fc'});
        $(b).stop().slideDown("slow").siblings('.yuedushu').stop().slideUp("slow");
    }

    function shouqidk(a){
        $(a).parent('.yuedushu').stop().slideUp("slow");
        for(var i = 0 ;i<$('.main_content_center_right_duoweidu_div').length;i++){
            $('.main_content_center_right_duoweidu_div').eq(i).css({'background':'#f0f7fc','border-top':'2px solid #f0f7fc'});
        }
    }

    function zuihoutab (a,b){
        $(a).css({'background':'#fff','border-top':'2px solid #0d6797','color':'#0d6797'}).siblings('.main_content_center_right_div_tab_top_div').css({'background':'#ebf0f4','border-top':'2px solid #ebf0f4','color':'#333'});
        $(b).stop().slideDown("slow").siblings('.main_content_center_right_div_tab_con').stop().slideUp("slow");
    }

    var x11 ="";
    function mouseMove(ev){
        Ev= ev || window.event;
        var mousePos = mouseCoords(ev);
        x11 = mousePos.x;
    }
    function mouseCoords(ev){
        if(ev.pageX || ev.pageY){
            return {x:ev.pageX, y:ev.pageY};
        }
        return{
            x:ev.clientX + document.body.scrollLeft - document.body.clientLeft,
            y:ev.clientY + document.body.scrollTop - document.body.clientTop
        };
    }
    document.onmousemove = mouseMove;

    //鏂规硶2
    //Firefox鏀寔灞炴€ageX,涓巔ageY灞炴€э紝杩欎袱涓睘鎬у凡缁忔妸椤甸潰婊氬姩璁＄畻鍦ㄥ唴浜�,
    //鍦–hrome鍙互閫氳繃document.body.scrollLeft锛宒ocument.body.scrollTop璁＄畻鍑洪〉闈㈡粴鍔ㄤ綅绉伙紝
    //鑰屽湪IE涓嬪彲浠ラ€氳繃document.documentElement.scrollLeft 锛宒ocument.documentElement.scrollTop
    function getMousePos(event) {
        var e = event || window.event;
        var scrollX = document.documentElement.scrollLeft || document.body.scrollLeft;
        var scrollY = document.documentElement.scrollTop || document.body.scrollTop;
        var x = e.pageX || e.clientX + scrollX;
        var y = e.pageY || e.clientY + scrollY;
        //alert('x: ' + x + '\ny: ' + y);
        return { 'x': x, 'y': y};
    }


    function showimg(thiss){
        $('.new_full_rich_motaikuang').show();
        $('.new_full_rich_model').show();
        $('.zuo').show();
        $('.you').show();
        $('.cas_motaikuang').show();
        $('.cas_model').show();
        var mTop = $(thiss).offset().top;
        $('.new_full_rich_model').css("top",mTop+100);
        var scr=$(thiss).attr('src');
        $('.tp').attr('src',scr);
        var nr=$(thiss).parent('.main_content_center_left_zhengwen_bao_fig_img_bap').next('.main_content_center_left_zhengwen_bao_fig_shuoming').html();
        $('.neirong').html(nr);
        var arr=[];
        for(var i=0;i<$('.main_content_center_left_zhengwen_bao_fig_img_bap').length;i++){
            var img_src=$('.main_content_center_left_zhengwen_bao_fig_img_bap').eq(i).children('img').attr('src');
            var zong=$('.main_content_center_left_zhengwen_bao_fig_img_bap').eq(i).next('.main_content_center_left_zhengwen_bao_fig_shuoming').html();
            var puse = {};
            puse.shuzi=i+1;
            puse.src=img_src;
            puse.zongde=zong;
            arr[i]=puse;
        }
        var a = arr.length;
        $('.zongdea').html(a);
        for(var y=0;y<arr.length;y++){
            if(arr[y].src==scr){
                $('.yige').html(arr[y].shuzi);
            }
        }
    }
    function shang(){
        var arr=[];
        for(var i=0;i<$('.main_content_center_left_zhengwen_bao_fig_img_bap').length;i++){
            var img_src=$('.main_content_center_left_zhengwen_bao_fig_img_bap').eq(i).children('img').attr('src');
            var zong=$('.main_content_center_left_zhengwen_bao_fig_img_bap').eq(i).next('.main_content_center_left_zhengwen_bao_fig_shuoming').html();
            var puse = {};
            puse.shuzi=i+1;
            puse.src=img_src;
            puse.zongde=zong;
            arr[i]=puse;
        }
        var tptp=$('.tp').attr('src');
        for(var y=0;y<arr.length;y++){
            if(arr[y].src==tptp){
                if(arr[y].src==arr[0].src){
                   // alert("No figure ahead!");
                    return false;
                }else{
                    var fzsrc=arr[y-1].src;
                    var fzshuzi=arr[y-1].shuzi;
                    var fzcontent=arr[y-1].zongde;
                    $('.tp').attr('src',fzsrc);
                    $('.yige').html(fzshuzi);
                    $('.neirong').html(fzcontent);
                }
            }
        }

    }

    function xia(){
        var arr=[];
        for(var i=0;i<$('.main_content_center_left_zhengwen_bao_fig_img_bap').length;i++){
            var img_src=$('.main_content_center_left_zhengwen_bao_fig_img_bap').eq(i).children('img').attr('src');
            var zong=$('.main_content_center_left_zhengwen_bao_fig_img_bap').eq(i).next('.main_content_center_left_zhengwen_bao_fig_shuoming').html();
            var puse = {};
            puse.shuzi=i+1;
            puse.src=img_src;
            puse.zongde=zong;
            arr[i]=puse;
        }
        var tptp=$('.tp').attr('src');
        for(var y=0;y<arr.length;y++){
            if(arr[y].src==tptp){
                if(arr[y].src==arr[arr.length-1].src){
                    //alert("No figure after!");
                    return false;
                }else{
                    var fzsrc=arr[y+1].src;
                    var fzshuzi=arr[y+1].shuzi;
                    var fzcontent=arr[y+1].zongde;
                    $('.tp').attr('src',fzsrc);
                    $('.yige').html(fzshuzi);
                    $('.neirong').html(fzcontent);
                }
            }
        }

    }
    function fanhuidingbu(){
        $('body,html').animate({scrollTop: 0}, 'fast');
    }
    function shu_fanhuidinfgbu(a){
        $(a).html("Top");
        $(a).css({'font-size':'13px','line-height':'18px'})
    }
    function zhedieyouce(){
        if(zd_html=="Full size"){
            width111 = $('.main_content_center_right').width();
            $('.main_content_center_right').hide();
            $('.main_content_center_left').width('100%');
            zd_html="Section";
        }else if(zd_html=="Section"){
            $('#huoqudndkk').width(width111);
            $('.main_content_center_right').show();
            $('.main_content_center_left').width('60%');
            zd_html="Full size";
        }

    }

    var zd_html="Full size";

    function shu_fanhuidinfgbu(a){
        $(a).html("Top");
        $(a).css({'font-size':'13px','line-height':'18px'})
    }

    function u_shu_fanhuidinfgbu(a){
        $(a).html('<i class="glyphicon glyphicon-arrow-up"></i>');
        $(a).css({'font-size':'14px','line-height':'40px'})
    }
    function shu_zedieyouce(a){
        $(a).html(zd_html);
        zd_html=$(a).html();
        $(a).css({'font-size':'13px','line-height':'18px'})
    }
    function u_shu_zedieyouce(a){
        $(a).css({'font-size':'14px','line-height':'40px'})
        $(a).html('<i class="glyphicon glyphicon-transfer"></i>');
    }
    // 首先定义日期转换函数
    function convertChineseToEnglishDate(chineseDate) {
        // 提取年、月、日 - 支持多种中文日期格式
        const matches = chineseDate.match(/(\d{4})[年\-\\/](\d{1,2})[月\-\\/](\d{1,2})[日]?/);
        if (!matches || matches.length < 4) {
            console.warn('无效的日期格式:', chineseDate);
            return chineseDate; // 返回原内容如果格式不匹配
        }

        const year = matches[1];
        const month = parseInt(matches[2]);
        const day = parseInt(matches[3]);

        const monthNames = [
            'Jan', 'Feb', 'Mar', 'Apr', 'May', 'Jun',
            'Jul', 'Aug', 'Sept', 'Oct', 'Nov', 'Dec'
        ];

        return `${day} ${monthNames[month - 1]} ${year}`;
    }

    // 使用jQuery循环处理所有riqizhuahuan类元素
    $(document).ready(function() {
        $('.riqizhuahuan').each(function() {
            // 获取当前元素的HTML内容
            const chineseDate = $(this).html().trim();

            // 调用转换函数
            const englishDate = convertChineseToEnglishDate(chineseDate);

            // 将转换后的日期设置回元素
            $(this).html(englishDate);

            // 如果需要，可以添加一个类表示已转换
            $(this).addClass('converted-to-english');
        });
    });

    function referenceOrderByType(type){
        if(type==1){//原文顺序
            var divTestJQ = $(".main_content_center_left_one_cankaowenxian"); //取得容器对象
            var divJQ = $(".main_content_center_left_one_cankaowenxian_tab", divTestJQ); //取容器需要重排的对象
            var EntityList = []; //定义一个数组用于存放要排序的对象
            divJQ.each(function () {
                var thisJQ = $(this);
                EntityList.push({ Name: parseInt(thisJQ.attr("order-1-num"), 10), JQ: thisJQ }); //把要排序的对象和排序的值一起放到一个新的对象里，并存入到数组
            });
            EntityList.sort(function (a, b) { //利用数组的排序方法重新排序对象
                //return b.Name - a.Name; //从大到小
                return a.Name - b.Name; //从小到大
            });
            for (var i = 0; i < EntityList.length; i++) {
                EntityList[i].JQ.appendTo(divTestJQ); //把排序完的对象重新插入到容器对象
            };
        }else if(type==2){//文献年度倒序
            var divTestJQ = $(".main_content_center_left_one_cankaowenxian"); //取得容器对象
            var divJQ = $(".main_content_center_left_one_cankaowenxian_tab", divTestJQ); //取容器需要重排的对象
            var EntityList = []; //定义一个数组用于存放要排序的对象
            divJQ.each(function () {
                var thisJQ = $(this);
                EntityList.push({ Name: parseInt(thisJQ.attr("order-2-num"), 10), JQ: thisJQ }); //把要排序的对象和排序的值一起放到一个新的对象里，并存入到数组
            });
            EntityList.sort(function (a, b) { //利用数组的排序方法重新排序对象
                return b.Name - a.Name; //从大到小
                //return a.Name - b.Name; //从小到大
            });
            for (var i = 0; i < EntityList.length; i++) {
                EntityList[i].JQ.appendTo(divTestJQ); //把排序完的对象重新插入  到容器对象
            };
        }else if(type==3){//文献被引倒序
            var divTestJQ = $(".main_content_center_left_one_cankaowenxian"); //取得容器对象
            var divJQ = $(".main_content_center_left_one_cankaowenxian_tab", divTestJQ); //取容器需要重排的对象
            var EntityList = []; //定义一个数组用于存放要排序的对象
            divJQ.each(function () {
                var thisJQ = $(this);
                EntityList.push({ Name: parseInt(thisJQ.attr("order-3-num"), 10), JQ: thisJQ }); //把要排序的对象和排序的值一起放到一个新的对象里，并存入到数组
            });
            EntityList.sort(function (a, b) { //利用数组的排序方法重新排序对象
                return b.Name - a.Name; //从大到小
                //return a.Name - b.Name; //从小到大
            });
            for (var i = 0; i < EntityList.length; i++) {
                EntityList[i].JQ.appendTo(divTestJQ); //把排序完的对象重新插入到容器对象
            };
        }
    }

    function downloadCitationFile1(type){
        downloadCitationFile(type);
    }

    function downloadCitationFile(type) {
        var tenantId = '1045748351789510663';
        var journalId = '1155139928190095384';
        var language = 'CN';
        var doi = '10.1016/j.eng.2021.04.028';
        var url = "https://www.engineering.org.cn/engi/CN/article/citation/download?tenantId="+tenantId+"&journalId="+journalId+"&language="+language+"&doi="+doi+"&citationType="+type;
        console.log("下载引用管理文件url："+url);
        // 创建一个临时的a标签
        var element = document.createElement('a');
        element.setAttribute('href', url);
        element.setAttribute('target', "__blank");

        // 隐藏a标签
        element.style.display = 'none';
        document.body.appendChild(element);

        // 模拟点击事件来下载文件
        element.click();

        // 下载后移除a标签
        document.body.removeChild(element);


    }

    function saveParamsAndJump (domain,tenantId,journalId,articleId) {
        // 改用 sessionStorage（刷新页面不丢失，关闭标签页后失效）
        sessionStorage.setItem('articleId', articleId || '');
        // 跳转页面
        window.location.href = domain + '/metrics/' + tenantId+"/"+journalId+"/"+articleId;
    }

    document.addEventListener('DOMContentLoaded', function() {
        // 初始渲染
        MathJax.Hub.Queue(["Typeset", MathJax.Hub]);
        
        // 监听动态内容变化
        const observer = new MutationObserver(function(mutations) {
            MathJax.Hub.Queue(["Typeset", MathJax.Hub]);
        });
        
        observer.observe(document.body, {
            childList: true,
            subtree: true
        });
    });



  $(function(){
        getPreviewArticle();
        getNextArticle();
        if($("#trendmd-journal-id") && $("#trendmd-journal-id").length && $("#trendmd-journal-id").length>0){
			window.setTimeout(function(){
				var script = document.createElement("script");
				script.type = "text/javascript";
				script.src = "https://js.trendmd.com/trendmd.min.js";
				script.setAttribute("defer","");
				script.setAttribute("data-trendmdconfig",'{"journal_id":"'+$("#trendmd-journal-id").val()+'", "element":"#trendmd-suggestions"}');
				document.getElementsByTagName("head")[0].appendChild(script);
			},1000);
		}
        
    })

    function getPreviewArticle() {
        var url = "https://www.engineering.org.cn/engi/CN/api/site/data/article/preArticle?articleId=1159867208501355111&issueId=1159861699803144227";
        $.ajax({
            url: url,
            type: 'GET',
            dataType:'json',
            success: function(res) {
                if(res.code==200 && res.data!=null) {
                    $("#pre_article_a").attr("href", 'https://www.engineering.org.cn/engi/CN/'+res.data.id);
                }
            },
            error: function(res) {}
            
            
        });
        
        
    }
    
    function getNextArticle() {
        var url = "https://www.engineering.org.cn/engi/CN/api/site/data/article/nextArticle?articleId=1159867208501355111&issueId=1159861699803144227";
        $.ajax({
            url: url,
            type: 'GET',
            dataType:'json',
            success: function(res) {
                if(res.code==200 && res.data!=null) {
                    $("#next_article_a").attr("href", 'https://www.engineering.org.cn/engi/CN/'+res.data.id);
                }
            },
            error: function(res) {}
            
            
        });
        
    }
    
    
    
    $(function() {
        getCitationDetailByWos();
    })
   function getCitationDetailByWos() {
        var url = "https://www.engineering.org.cn/engi/CN/api/site/data/article/articleCitedList?pageSize=1&source=WOS&journalId=1155139928190095384&articleId=1159867208501355111";
        $.ajax({
            url: url,
            type: 'GET',
            dataType:'json',
            success: function(res) {
                 
                if(res.code==200 &&res.listData!=null) {
                    for(var citation of res.listData) {
                        $("#citation_count").text(citation.citedCount);
                        break;
                    }
                    
                }else {
                    getCitationDetailByCrossRef();   
                    
                }
            },
            error: function(res) {}
            
            
        });
        
    }


 function getCitationDetailByCrossRef() {
        var url = "https://www.engineering.org.cn/engi/CN/api/site/data/article/articleCitedList?pageSize=1&source=Crossref&journalId=1155139928190095384&articleId=1159867208501355111";
        $.ajax({
            url: url,
            type: 'GET',
            dataType:'json',
            success: function(res) {
                if(res.code==200 && res.listData!=null) {
                    for(var catation of res.listData) {
                        $("#citation_count").text(catation.citedCount);
                        break;
                    }   
                }
            },
            error: function(res) {}
            
            
        });
        
    }
   
   
   
    $(function() {
        processJson();
    })
    
    //数据库字段不全的情况下，查询json报文取字段
    function processJson() {
        var url = "https://www.engineering.org.cn/engi/CN/api/site/data/article/json?articleId=1159867208501355111&language=CN";
        $.ajax({
            url: url,
            type: 'GET',
            dataType: 'json',
            success: function(res) {
                if(res.code!=null && res.data!=null && res.data.article!=null) {
                       var article = res.data.article;
                       //处理通信作者显示不全问题
                       if(article.articleExtMap!=null) {
                            for(var ext of article.articleExtMap) {
                                if(ext.lang=='en') {
                                    var extInfo = ext.ext;
                                    if(extInfo!=null) {
                                        var authorNotes = extInfo.authorNotes;
                                        var noteText = "";
                                        if(authorNotes!=null && authorNotes!='' && authorNotes.length>0) {
                                            for(var note of authorNotes) {
                                                if(noteText!="") {
                                                    noteText = noteText+"<br/>";
                                                }
                                                noteText+=note;
                                            }
                                           // $("#correspAuthorsNoteText").html(noteText);
                                        }
                                        
                                        let subTitleEn = extInfo.subTitle ? `<br/>—${extInfo.subTitle}` : '';
                                        if(subTitleEn){
                                            $("#subTitle_en").html(subTitleEn);
                                        }
                                    }
                                    
                                }
                                
                                if(ext.lang=="zh"){
                                    if(ext.ext){
                                        let subTitleCn = ext.ext.subTitle ? `<br/>——${ext.ext.subTitle}` : '';
                                        if(subTitleCn){
                                            $("#subTitle_cn").html(subTitleCn);
                                        }
                                    }
                                }
                                
                            }
                           
                       }//if 
                }
            },
            error: function(res) {}
        });
    }
     

    function doDownloadPdf() {
        console.log("下载pdf文件");
        var pdfFileId = "H7KzKDxAzVQkNyhVBO+i3Q==";
        if(pdfFileId==null || pdfFileId=='') {
            return;
        }
        var articleTitle = "钠超离子导体型固体电解质的改性及其在钠离子电池中的应用";
        var url = "https://www.engineering.org.cn/engi/CN/file/fetch?fileId="+pdfFileId+"&fileName="+articleTitle+".pdf";
        //下载pdf文件
        var domain = "https://www.engineering.org.cn/engi/CN";
        var url = `${domain}/file/fetch?fileId=${pdfFileId}&fileName=${encodeURIComponent(articleTitle)}.pdf`;
        // 4. 安全下载（创建a标签模拟点击，不跳转页面）
        try {
            const link = document.createElement('a');
            link.href = url;
            // 指定下载文件名
            link.download = `${articleTitle}.pdf`;
            // 新窗口打开（兼容部分浏览器限制）
            link.target = '_blank';
            // 防止页面跳转
           
           // link.rel = 'noopener noreferrer';
            
            // 模拟点击触发下载
            document.body.appendChild(link);
            link.click();
            // 下载后移除元素
            document.body.removeChild(link);
            
            console.log("PDF下载请求已发送：", url);
        } catch (error) {
            console.error("PDF下载失败：", error);
            alert("PDF下载失败，请稍后重试");
        }
        
    } 网站版权 © 《中国工程科学》杂志社有限责任公司 电话: 0086-10-58582252 京公网安备 11010502051620号 京ICP备11030251号-2 Powered by Beijing Magtech Co. Ltd var _hmt = _hmt || [];
(function() {
  var hm = document.createElement("script");
  hm.src = "https://hm.baidu.com/hm.js?2834c7e9ed0ad756f893817022d2bb56";
  var s = document.getElementsByTagName("script")[0]; 
  s.parentNode.insertBefore(hm, s);
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  gtag('js', new Date());
  gtag('config', 'G-40JBR51S7J');

Received	Published
2020-05-06	2022-01-24
Issue Date
2024-06-13

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English

摘要

Abstract

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引用本文

1. 引言

2. 材料和方法

3. 结果与讨论

4. 结论

参考文献

基金资助

Sample	Density (g∙cm^‒3)
NZSP-Mg₀	3.27
NZSP-Mg_0.05	3.27
NZSP-Mg_0.10	3.23
NZSP-Mg_0.15	3.15
NZSP-Mg_0.20	3.11