零相频下离子导体的焦耳加热及其电解反应抑制

Lei Shi, Zongyi Han, Yixuan Feng, Changgeng Zhang, Qi Zhang, He Zhu, Shiping Zhu

工程(英文) ›› 2023, Vol. 25 ›› Issue (6) : 138-143.

PDF(1852 KB)
PDF(1852 KB)
工程(英文) ›› 2023, Vol. 25 ›› Issue (6) : 138-143. DOI: 10.1016/j.eng.2022.03.004
研究论文
Letter

零相频下离子导体的焦耳加热及其电解反应抑制

作者信息 +

Joule Heating of Ionic Conductors Using Zero-Phase Frequency Alternating Current to Suppress Electrochemical Reactions

Author information +
History +

摘要

众所周知,当电流通过电导体时会产生热量。我们日常生活和工业中的各种应用都利用电子导体的加热,但很少有人关注离子导体用于加热的潜力。这是因为“不可避免的”电化学反应会导致不必要的导体电解、电极腐蚀和表面结垢。本文报道了没有电化学反应的离子导体的焦耳加热。采用零相频率的电流来抑制高电压下离子导体的电解。各种离子导体(液体和固体)的演示显示出无电化学反应的高效能量转换。这种加热方法简单、直接、快速、清洁、均匀,在工业和家庭的许多应用中具有巨大潜力。

Abstract

It is well known that heat is generated when an electric current passes through an electrical conductor. While various applications in our daily lives and industries utilize the heating of electronic conductors, little attention has been paid to the potential of ionic conductors for heating purposes. This is because of the “inevitable” electrochemical reactions, which can result in unwanted electrolysis of conductors, corrosion of electrodes, and surface fouling. This paper reports the Joule heating of ionic conductors without electrochemical reactions. Electricity with a zero-phase frequency is employed to suppress the electrolysis of ionic conductors at high voltages. Demonstrations with various ionic conductors, both liquids and solids, show highly efficient energy conversion free of electrochemical reactions. This heating method is simple, direct, fast, clean, and uniform, and it has great potential in numerous industrial and household applications.

Keywords

Joule heating / Ionic conductors / Electrolytes / Zero-phase frequency / Electrochemical corrosion

引用本文

导出引用
Lei Shi, Zongyi Han, Yixuan Feng. 零相频下离子导体的焦耳加热及其电解反应抑制. Engineering. 2023, 25(6): 138-143 https://doi.org/10.1016/j.eng.2022.03.004

参考文献

[1]
Wang C, Ping W, Bai Q, Cui H, Hensleigh R, Wang R, et al. A general method to synthesize and sinter bulk ceramics in seconds. Science 2020;368(6490):521‒6.
[2]
Balandin AA. Thermal properties of graphene and nanostructured carbon materials. Nat Mater 2011;10(8):569‒81.
[3]
An BW, Gwak EJ, Kim K, Kim YC, Jang J, Kim JY, et al. Stretchable, transparent electrodes as wearable heaters using nanotrough networks of metallic glasses with superior mechanical properties and thermal stability. Nano Lett 2016;16(1):471‒8.
[4]
Zhu X, Xu Q, Li H, Liu M, Li Z, Yang K, et al. Fabrication of high-performance silver mesh for transparent glass heaters via electric-field-driven microscale 3D printing and UV-assisted microtransfer. Adv Mater 2019;31(32):1902479.
[5]
Dudchenko AV, Chen C, Cardenas A, Rolf J, Jassby D. Frequency-dependent stability of CNT Joule heaters in ionizable media and desalination processes. Nat Nanotechnol 2017;12(6):557‒63.
[6]
Keplinger C, Sun JY, Foo CC, Rothemund P, Whitesides GM, Suo Z. Stretchable, transparent, ionic conductors. Science 2013;341(6149):984‒7.
[7]
Rustomji CS, Yang Y, Kim TK, Mac J, Kim YJ, Caldwell E, et al. Liquefied gas electrolytes for electrochemical energy storage devices. Science 2017;356(6345):aal4263.
[8]
Xu K. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem Rev 2004;104(10):4303‒418.
[9]
Manthiram A, Yu XW, Wang SF. Lithium battery chemistries enabled by solid-state electrolytes. Nat Rev Mater 2017;2(4):16103.
[10]
Bachman JC, Muy S, Grimaud A, Chang HH, Pour N, Lux SF, et al. Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction. Chem Rev 2016;116(1):140‒62.
[11]
Shi L, Zhu T, Gao G, Zhang X, Wei W, Liu W, et al. Highly stretchable and transparent ionic conducting elastomers. Nat Commun 2018;9(1):2630.
[12]
Sakr M, Liu SL. A comprehensive review on applications of Ohmic heating (OH). Renew Sustain Energy Rev 2014;39:262‒9.
[13]
Jaeger H, Roth A, Toepfl S, Holzhauser T, Engel KH, Knorr D, et al. Opinion on the use of Ohmic heating for the treatment of foods. Trends Food Sci Technol 2016;55:84‒97.
[14]
Cappato LP, Ferreira MVS, Guimaraes JT, Portela JB, Costa ALR, Freitas MQ, et al. Ohmic heating in dairy processing: relevant aspects for safety and quality. Trends Food Sci Technol 2017;62:104‒12.
[15]
De Mello AJ, Habgood M, Lancaster NL, Welton T, Wootton RCR. Precise temperature control in microfluidic devices using Joule heating of ionic liquids. Lab Chip 2004;4(5):417‒9.
[16]
Suo L, Borodin O, Gao T, Olguin M, Ho J, Fan X, et al. “Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries. Science 2015;350 (6263):938‒43.
[17]
Li JC, Ma C, Chi MF, Liang CD, Dudney NJ. Solid electrolyte: the key for high-voltage lithium batteries. Adv Energy Mater 2015;5(4):1401408.
[18]
Wang J, Yamada Y, Sodeyama K, Chiang CH, Tateyama Y, Yamada A. Superconcentrated electrolytes for a high-voltage lithium-ion battery. Nat Commun 2016;7(1):12032.
[19]
Read JA, Cresce AV, Ervin MH, Xu K. Dual-graphite chemistry enabled by a high voltage electrolyte. Energy Environ Sci 2014;7(2):617‒20.
[20]
Li SY, Zhao DN, Wang P, Cui XL, Tang FJ. Electrochemical effect and mechanism of adiponitrile additive for high-voltage electrolyte. Electrochim Acta 2016;222:668‒77.
[21]
Shi L, Jia K, Gao Y, Yang H, Ma Y, Lu S, et al. Highly stretchable and transparent ionic conductor with novel hydrophobicity and extreme-temperature tolerance. Research 2020;2020:2505619.
[22]
Bansal B, Chen XD. Effect of temperature and power frequency on milk fouling in an Ohmic heater. Food Bioprod Process 2006;84(4):286‒91.
[23]
Winter M, Brodd RJ. What are batteries, fuel cells, and supercapacitors? Chem Rev 2004;104(10):4245‒70.
[24]
Mei BA, Munteshari O, Lau J, Dunn B, Pilon L. Physical interpretations of Nyquist plots for EDLC electrodes and devices. J Phys Chem C 2018;122(1):194‒206.
[25]
Silva VLM, LMNBFSantos, Silva AMS. Ohmic heating: an emerging concept in organic synthesis. Chemistry 2017;23(33):7853‒65.
[26]
Samaranayake CP, Sastry SK, Zhang H. Pulsed Ohmic heating—a novel technique for minimization of electrochemical reactions during processing. J Food Sci 2005;70(8):e460‒5.
[27]
Plutschack MB, Pieber B, Gilmore K, Seeberger PH. The Hitchhiker’s guide to flow chemistry II. Chem Rev 2017;117(18):11796‒893.
[28]
Wegner J, Ceylan S, Kirschning A. Flow chemistry—a key enabling technology for (multistep) organic synthesis. Adv Synth Catal 2012;354(1):17‒57.
[29]
Wiles C, Watts P. Continuous flow reactors: a perspective. Green Chem 2012;14(1):38‒54.
PDF(1852 KB)

Accesses

Citation

Detail

段落导航
相关文章

/