一种基于载银石墨烯和两亲网络的复合防污防腐一体化涂层

田澍, 张晋丽, 刘栓, 李靖宇, 蒲吉斌, 郝豫刚, 应国兵, 薛群基, 卢光明

工程（英文） ›› 2024, Vol. 42 ›› Issue (11) : 223-234.

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工程（英文） ›› 2024, Vol. 42 ›› Issue (11) : 223-234. DOI: 10.1016/j.eng.2022.09.019
研究论文

一种基于载银石墨烯和两亲网络的复合防污防腐一体化涂层

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An Integrated Anti-Fouling and Anti-Corrosion Coating Enabled by rGO/AgNPs and Amphiphilic Networks

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摘要

海洋腐蚀和生物污损是海洋工程装备面临的两大主要挑战，使用功能涂层是一种简单且有效的防护方法。然而，单一涂层很难同时具备防腐蚀和防污性能。在本工作中，我们将还原氧化石墨烯（rGO）/银纳米颗粒（AgNPs）与一种亲水聚合物结合，加入到生物基有机硅-环氧树脂中形成兼具防污和防腐蚀性能的涂层。涂层优异的防污性能源于三重协同防污机制，包括污损释放、接触抑制和水化作用；而优异的防腐蚀性能同样源于三重协同防腐蚀机制，包括形成致密的互穿网络（IPN）结构、屏障效应和钝化。结果显示，所制得的涂层可以有效抵抗蛋白质、细菌、藻类等海洋污损生物的粘附，并通过动态交联的rGO/AgNPs-亲水聚合物网络实现出色的防腐蚀和一定的自愈性能。该研究为海洋工程装备提供了一种防污防腐一体化的防护涂层。

Abstract

Marine corrosion and biofouling are challenges that affect marine industrial equipment, and protecting equipment with functional coatings is a simple and effective approach. However, it is extremely difficult to combine anti-corrosion and anti-fouling properties in a single coating. In this work, we combine reduced graphene oxide (rGO)/silver nanoparticles (AgNPs) with a hydrophilic polymer in a bio-based silicone-epoxy resin to create a coating with both anti-fouling and anti-corrosion properties. The excellent anti-fouling performance of the coating results from a ternary synergistic mechanism involving fouling release, contact inhibition, and a hydration effect, while the outstanding anti-corrosion performance is provided by a ternary synergistic anti-corrosion mechanism that includes a dense interpenetrating network (IPN) structure, a barrier effect, and passivation. The results show that the obtained coating possesses superior anti-fouling activity against protein, bacteria, algae, and other marine organisms, as well as excellent anti-corrosion and certain self-healing properties due to its dynamic cross-linked network of rGO/AgNPs and the hydrophilic polymer. This work provides an anti-corrosion and anti-fouling integrated coating for marine industrial equipment.

关键词

防污 / 防腐蚀 / 载银石墨烯 / 两亲性涂层

Keywords

Anti-fouling / Anti-corrosion / rGO/AgNPs / Amphiphilic coating

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田澍, 张晋丽, 刘栓. 一种基于载银石墨烯和两亲网络的复合防污防腐一体化涂层. Engineering. 2024, 42(11): 223-234 https://doi.org/10.1016/j.eng.2022.09.019

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