利用木质素合成化学品和升级生物油的电化学生物精炼技术

胡锐, 赵玉莹, 唐晨, 石岩, 罗刚, 范佳珺, James H. Clark, 张士成

工程（英文） ›› 2023, Vol. 27 ›› Issue (8) : 178-198.

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工程（英文） ›› 2023, Vol. 27 ›› Issue (8) : 178-198. DOI: 10.1016/j.eng.2022.10.013
研究论文
Review

利用木质素合成化学品和升级生物油的电化学生物精炼技术

作者信息 +

Electrochemical Biorefinery toward Chemicals Synthesis and Bio-Oil Upgrading from Lignin

Author information +
History +

摘要

木质素的难降解性及其结构固有的非均质性是阻碍木质素基化学品生产工艺推广的主要瓶颈。最近的研究表明，通过电化学生物炼制（一种通过电化学氧化或还原实现木质素增值转化的工艺）进行木质素解聚和木质素衍生生物油升级是一种很有前景的途径。本文介绍了通过电化学生物精炼木质素合成化学品和升级生物油的研究进展，涉及木质素的生物合成途径、木质素电化学转化的反应途径、内层和外层电子传递机制、电化学的基本动力学和热力学，以及最新的实例分析，重点介绍了木质素电化学氧化和还原转化的各自特点和局限性。最后，讨论了与木质素电化学生物炼制相关的挑战和前景。目前的研究结果表明，要提高木质素电化学生物炼制的效率、选择性和稳定性，仍需做更多的工作。将各种类型的木质素电化学转化策略与其他现有或正在发展的木质素价值化技术相结合似乎是最有前景的发展方向之一。本文旨在为木质素电化学生物炼制的发展提供更多参考和讨论。

Abstract

Recalcitrance and the inherent heterogeneity of lignin structure are the major bottlenecks to impede the popularization of lignin-based chemicals production processes. Recent works suggested a promising pathway for lignin depolymerization and lignin-derived bio-oil upgrading via an electrochemical biorefinery (a process in which lignin valorization is performed via electrochemical oxidation or reduction). This review presents the progress on chemicals synthesis and bio-oil upgrading from lignin by an electrochemical biorefinery, relating to the lignin biosynthesis pathway, reaction pathway of lignin electrochemical conversion, inner-sphere and outer-sphere electron transfer mechanism, basic kinetics and thermodynamics in electrochemistry, and the recent embodiments analysis with the emphasis on the respective feature and limitation for lignin electrochemical oxidative and reductive conversion. Lastly, the challenge and perspective associated with lignin electrochemical biorefinery are discussed. Present-day results indicate that more work should be performed to promote efficiency, selectivity, and stability in pursuing a lignin electrochemical biorefinery. One of the most promising developing directions appears to be integrating various types of lignin electrochemical conversion strategies and other existing or evolving lignin valorization technologies. This review aims to provide more references and discussion on the development for lignin electrochemical biorefinery.

关键词

木质素 / 电化学生物炼制 / 反应途径 / 电子转移机制 / 动力学 / 热力学

Keywords

Lignin / Electrochemical biorefinery / Reaction pathway / Electron transfer mechanism / Kinetics / Thermodynamics

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胡锐, 赵玉莹, 唐晨. 利用木质素合成化学品和升级生物油的电化学生物精炼技术. Engineering. 2023, 27(8): 178-198 https://doi.org/10.1016/j.eng.2022.10.013

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