一种具有超高温工程应用潜力的氮化物增强NbMoTaWHfN难熔高熵合金

万义兴; 程延海; Yongxiong Chen; Zhibin Zhang; Yanan Liu; Haijun Gong; Baolong Shen; Xiubing Liang

doi:10.1016/j.eng.2023.06.008

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工程（英文） ›› 2023, Vol. 30 ›› Issue (11) : 110-120. DOI: 10.1016/j.eng.2023.06.008

研究论文

Article

一种具有超高温工程应用潜力的氮化物增强NbMoTaWHfN难熔高熵合金

万义兴 ^a ,
程延海 ^a^,^* ,
Yongxiong Chen ^b ,
Zhibin Zhang ^b ,
Yanan Liu ^a ,
Haijun Gong ^a ,
Baolong Shen ^c^,^* ,
Xiubing Liang ^b^,^*

作者信息 +

A Nitride-Reinforced NbMoTaWHfN Refractory High-Entropy Alloy with Potential Ultra-High-Temperature Engineering Applications

Yixing Wan ^a ,
Yanhai Cheng ^a^,^* ,
Yongxiong Chen ^b ,
Zhibin Zhang ^b ,
Yanan Liu ^a ,
Haijun Gong ^a ,
Baolong Shen ^c^,^* ,
Xiubing Liang ^b^,^*

Author information +

History +

Abstract

Refractory high-entropy alloys (RHEAs) have promising applications as the new generation of high-temperature alloys in hypersonic vehicles, aero-engines, gas turbines, and nuclear power plants. This study focuses on the microstructures and mechanical properties of the NbMoTaW(HfN)_x (x = 0, 0.3, 0.7, and 1.0) RHEAs. The alloys consist of multiple phases of body-centered cubic (BCC), hafnium nitride (HfN), or multicomponent nitride (MN) phases. As the x contents increase, the grain size becomes smaller, and the strength gradually increases. The compressive yield strengths of the NbMoTaWHfN RHEA at ambient temperature, 1000, 1400, and 1800 °C were found to be 1682, 1192, 792, and 288 MPa, respectively. The high-temperature strength of this alloy is an inspiring result that exceeds the high temperature and strength of most known alloys, including high-entropy alloys, refractory metals, and superalloys. The HfN phase has a significant effect on strengthening due to its high structural stability and sluggish grain coarsening, even at ultra-high temperatures. Its superior properties endow the NbMoTaWHfN RHEA with potential for a wide range of engineering applications at ultra-high temperatures. This work offers a strategy for the design of high-temperature alloys and proposes an ultra-high-temperature alloy with potential for future engineering applications.

Keywords

Refractory high-entropy alloy / High temperature / Mechanical property / Microstructure / Strengthening mechanism

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万义兴, 程延海, Yongxiong Chen. 一种具有超高温工程应用潜力的氮化物增强NbMoTaWHfN难熔高熵合金. Engineering. 2023, 30(11): 110-120 https://doi.org/10.1016/j.eng.2023.06.008

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