从工业废水中高效回收金属——基于电势振荡和旋流模式的电化学系统

Li Chen; Gong Zhang; Huijuan Liu; Shiyu Miao; Qingbai Chen; Huachun Lan; Jiuhui Qu

doi:10.1016/j.eng.2023.12.002

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工程（英文） ›› 2024, Vol. 38 ›› Issue (7) : 184-193. DOI: 10.1016/j.eng.2023.12.002

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从工业废水中高效回收金属——基于电势振荡和旋流模式的电化学系统

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Efficient Metal Recovery from Industrial Wastewater: Potential Oscillation and Turbulence Mode for Electrochemical System

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Abstract

Efficient metal recovery from industrial wastewater facilitates addressing of the environmental hazards and resource requirements of heavy metals. The conventional electrodeposition recovery method is hampered by the limitations of interfacial ion transport in charge-transfer reactions, creating challenges for simultaneous rapid and high-quality metal recovery. Therefore, we proposed integrating a transient electric field (TE) and swirling flow (SF) to synchronously enhance bulk mass transfer and promote interfacial ion transport. We investigated the effects of the operation mode, transient frequency, and flow rate on metal recovery, enabling determination of the optimal operating conditions for rapid and efficient sequential recovery of Cu in TE&SF mode. These conditions included low and high electric levels of 0 and 4 V, a 50% duty cycle, 1 kHz frequency, and 400 L·h⁻¹ flow rate. The kinetic coefficients of TE&SF electrodeposition were 3.5-4.3 and 1.37-1.97 times that of single TE and SF electrodeposition, respectively. Simulating the deposition process under TE and SF conditions confirmed the efficient concurrence of interfacial ion transport and charge transfer under TE and SF synergy, which achieved rapid and high-quality metal recovery. Therefore, the combined deposition strategy is considered an effective technique for reducing metal pollution and promoting resource recycling.

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Ion transport / Reaction kinetics / Transient electric field / Swirling flow

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Li Chen, Gong Zhang, Huijuan Liu. 从工业废水中高效回收金属——瞬态电场与旋流耦合模式下的电化学系统. Engineering. 2024, 38(7): 184-193 https://doi.org/10.1016/j.eng.2023.12.002

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