高牢度、柔性超疏水织物用于超宽带高效微波吸收

张仲; 孟雅鑫; 方新锐; 王庆; 王训该; 牛海涛; 周华

doi:10.1016/j.eng.2024.03.009

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工程（英文） ›› 2024, Vol. 41 ›› Issue (10) : 161-171. DOI: 10.1016/j.eng.2024.03.009

研究论文

Article

高牢度、柔性超疏水织物用于超宽带高效微波吸收

张仲 ^a^,^c ,
孟雅鑫 ^a ,
方新锐 ^a^,^c ,
王庆 ^a^,^c ,
王训该 ^b ,
牛海涛 ^a ,
周华 ^a^,^c

作者信息 +

Robust, Flexible, and Superhydrophobic Fabrics for High-Efficiency and Ultrawide-Band Microwave Absorption

Zhong Zhang ^a^,^c ,
Yaxin Meng ^a ,
Xinrui Fang ^a^,^c ,
Qing Wang ^a^,^c ,
Xungai Wang ^b^,^* ,
Haitao Niu ^a^,^* ,
Hua Zhou ^a^,^c^,^*

Author information +

History +

Abstract

Microwave absorption (MA) materials are essential for protecting against harmful electromagnetic radiation. In this study, highly efficient and ultrawide-band microwave-absorbing fabrics with superhydrophobic surface features were developed using a facile dip-coating method involving in situ graphene oxide (GO) reduction, deposition of TiO₂ nanoparticles, and subsequent coating of a mixture of polydimethylsiloxane (PDMS) and octadecylamine (ODA) on polyester fabrics. Owing to the presence of hierarchically structured surfaces and low-surface-energy materials, the resultant reduced GO (rGO)/TiO₂-ODA/PDMS-coated fabrics demonstrate superhydrophobicity with a water contact angle of 159° and sliding angle of 5°. Under the synergistic effects of conduction loss, interface polarization loss, and surface roughness topography, the optimized fabrics show excellent microwave absorbing performances with a minimum reflection loss (RL_min) of −47.4 dB and a maximum effective absorption bandwidth (EAB_max) of 7.7 GHz at a small rGO loading of 6.9 wt%. In addition, the rGO/TiO₂-ODA/PDMS coating was robust, and the coated fabrics could withstand repeated washing, soiling, long-term ultraviolet irradiation, and chemical attacks without losing their superhydrophobicity and MA properties. Moreover, the coating imparts self-healing properties to the fabrics. This study provides a promising and effective route for the development of robust and flexible materials with microwave-absorbing properties.

Keywords

Microwave absorption / Superhydrophobic / Fabrics / Coating / Self-healing

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张仲, 孟雅鑫, 方新锐. 高牢度、柔性超疏水织物用于超宽带高效微波吸收. Engineering. 2024, 41(10): 161-171 https://doi.org/10.1016/j.eng.2024.03.009

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