中国直接还原铁发展的挑战与途径

韦承志, 张鑫, 张津, 徐良平, 李光辉, 姜涛

工程(英文) ›› 2024, Vol. 41 ›› Issue (10) : 93-109.

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工程(英文) ›› 2024, Vol. 41 ›› Issue (10) : 93-109. DOI: 10.1016/j.eng.2024.04.025
研究论文
Review

中国直接还原铁发展的挑战与途径

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Development of Direct Reduced Iron in China: Challenges and Pathways

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Abstract

The steel industry is considered an important basic sector of the national economy, and its high energy consumption and carbon emissions make it a major contributor to climate change, especially in China. The majority of crude steel in China is produced via the energy- and carbon-intensive blast furnace-basic oxygen furnace (BF-BOF) route, which greatly relies on coking coal. In recent years, China’s steel sector has made significant progress in energy conservation and emission reduction, driven by decarbonization policies and regulations. However, due to the huge output of crude steel, the steel sector still produces 15% of the total national CO2 emissions. The direct reduced iron (DRI) plus scrap-electric arc furnace (EAF) process is currently considered a good alternative to the conventional route as a means of reducing CO2 emissions and the steel industry’s reliance on iron ore and coking coal, since the gas-based DRI plus scrap-EAF route is expected to be more promising than the coal-based one. Unfortunately, almost no DRI is produced in China, seriously restricting the development of the EAF route. Here, we highlight the challenges and pathways of the future development of DRI, with a focus on China. In the short term, replacing natural gas with coke oven gas (COG) and byproduct gas from the integrated refining and chemical sector is a more economically feasible and cleaner way to develop a gas-based route in China. As the energy revolution proceeds, using fossil fuels in combination with carbon capture, utilization, and storage (CCUS) and hydrogen will be a good alternative due to the relatively low cost. In the long term, DRI is expected to be produced using 100% hydrogen from renewable energy. Both the development of deep processing technologies and the invention of a novel binder are required to prepare high-quality pellets for direct reduction (DR), and further research on the one-step gas-based process is necessary.

Keywords

Direct reduced iron / CO2 emissions / Energy sources / Hydrogen / Direct reduction process

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韦承志, 张鑫, 张津. 中国直接还原铁发展的挑战与途径. Engineering. 2024, 41(10): 93-109 https://doi.org/10.1016/j.eng.2024.04.025

参考文献

[1]
Sustainability indicators 2022 report. Report. Brussels: World Steel Association; 2022 Dec.
[2]
World steel in figures 2024. Report. Brussels: World Steel Association; 2024 May.
[3]
S.H. Zhang, B.W. Yi, F. Guo, P.Y. Zhu.Exploring selected pathways to low and zero CO2 emissions in China’s iron and steel industry and their impacts on resources and energy. J Clean Prod, 340 (2022), p. 18.
[4]
F.Q. Shangguan, Z.D. Liu, R.Y. Yin. Study on implementation path of “carbon peak” and “carbon neutrality” in steel industry in China. China Metall, 31 (9) (2021), pp. 15-20. Chinese.
[5]
J.L. Shen, Q. Zhang, L.S. Xu, S.S. Tian, P. Wang.Future CO2 emission trends and radical decarbonization path of iron and steel industry in China. J Clean Prod, 326 (2021), p. 14.
[6]
R.Y. An, B.Y. Yu, R. Li, Y.M. Wei. Potential of energy savings and CO2 emission reduction in China’s iron and steel industry. Appl Energy, 226 (2018), pp. 862-880.
[7]
J. Zhao, H. Zuo, Y. Wang, J. Wang, Q. Xue. Review of green and low-carbon ironmaking technology. Ironmaking Steelmaking, 47 (3) (2020), pp. 296-306.
[8]
L. Ren, S. Zhou, X.M. Ou. The carbon reduction potential of hydrogen in the low carbon transition of the iron and steel industry: the case of China. Renew Sustain Energy Rev, 171 (2023), Article 113026.
[9]
J. Perpinan, B. Pena, M. Bailera, V. Eveloy, P. Kannan, A. Raj, et al. Integration of carbon capture technologies in blast furnace based steel making: a comprehensive and systematic review. Fuel, 336 (2023), Article 127074.
[10]
Iron and steel technology roadmap:part of energy technology perspectives. Report. Paris: International Energy Agency; 2020 Oct.
[11]
Z.Y. Fan, S.J. Friedmann. Low-carbon production of iron and steel: technology options, economic assessment, and policy. Joule, 5 (4) (2021), pp. 829-862.
[12]
T. Wolfinger, D. Spreitzer, H. Zheng, J. Schenk. Influence of a prior oxidation on the reduction behavior of magnetite iron ore ultra-fines using hydrogen. Metall Mater Trans B, 53 (1) (2022), pp. 14-28.
[13]
J.L. Zhang, Z.J. Liu, T.J. Yang. Non-blast furnace ironmaking. Metallurgical Industry Press, Beijing (2015). Chinese.
[14]
C. Lan, Y. Hao, J. Shao, S. Zhang, R. Liu, Q. Lyu. Effect of H2 on blast furnace ironmaking: a review. Metals, 12 (11) (2022), p. 1864.
[15]
Y. Chen, H. Zuo. Review of hydrogen-rich ironmaking technology in blast furnace. Ironmaking Steelmaking, 48 (6) (2021), pp. 749-768.
[16]
H. Nogami, Y. Kashiwaya, D. Yamada. Simulation of blast furnace operation with intensive hydrogen injection. ISIJ Int, 52 (8) (2012), pp. 1523-1527.
[17]
M.A. Zarl, D. Ernst, J. Cejka, J. Schenk. A new methodological approach to the characterization of optimal charging rates at the hydrogen plasma smelting reduction process part 1: method. Materials, 15 (14) (2022), p. 4767.
[18]
J. Tang, M.S. Chu, F. Li, C. Feng, Z.G. Liu, Y. Zhou. Development and progress on hydrogen metallurgy. Int J Miner Metall Mater, 27 (6) (2020), pp. 713-723.
[19]
Y. Ma, J.W. Bae, S.H. Kim, M. Jovičević-Klug, K. Li, D. Vogel, et al. Reducing iron oxide with ammonia: a sustainable path to green steel. Adv Sci, 10 (16) (2023), Article 2300111.
[20]
D. Raabe. The materials science behind sustainable metals and alloys. Chem Rev, 123 (5) (2023), pp. 2436-2608.
[21]
T. Jang, G.Z. Qiu, J.C. Xu, D.Q. Zhu.Direct reduction of composite binder pellets and use of DRI. Electrotherm (India) Ltd, Ahmedabad (2007).
[22]
G.Z. Yao, Y.L. Li, Q. Guo, T. Qi, Z.C. Guo. Preparation of reduced iron powder for powder metallurgy from magnetite concentrate by direct reduction and wet magnetic separation. Powder Technol, 392 (2021), pp. 344-355.
[23]
World direct reduction statistics 2023. Report. Charlotte: Midrex Technologies Inc; 2023 Sep.
[24]
X.B. Zhang, M.H. Wang, M.Y. Kou. New technology of coal-based hydrogen metallurgy for green and short-flow steelmaking. Mining Metall Eng, 41 (6) (2021), pp. 174-177. Chinese.
[25]
L.K. Hong, H.Y. Qi, C.J. Sun, J.J. Gao, B.Q. Wu. Direct reduction of coal based vanadium-bearing titanomagnetite. Iron Steel, 52 (11) (2017), pp. 15-19. Chinese.
[26]
R.F. Wei, D.Q. Cang, L.L. Zhang, Y.Y. Bai. Staged reaction kinetics and characteristics of iron oxide direct reduction by carbon. Int J Miner Metall Mater, 22 (10) (2015), pp. 1025-1032.
[27]
J. Kou, T. Sun, D. Tao, Y. Cao, C. Xu.Coal-based direct reduction and magnetic separation of lump hematite ore. Miner Metall Process, 31 (3) (2014), pp. 150-161.
[28]
D.Q. Zhu, V. Mendes, T.J. Chun, J.A. Pan, Q.H. Li, J. Li, et al. Direct reduction behaviors of composite binder magnetite pellets in coal-based grate-rotary kiln process. ISIJ Int, 51 (2) (2011), pp. 214-219.
[29]
Z.H. Lu, Y. Chen, D.M. Chen, S.Q. Li. Experimental research on rotary kiln one-step process DRI productions. J Iron Steel Res Int, 23 (5) (2011), pp. 11-14. Chinese.
[30]
J. Li. A study on mechanism and process of direct reduction of pellets made from concentrate and composite binder. Central South University Press, Changsha (2007). Chinese.
[31]
Z.C. Huang. Cold-bonded pellets direct reduction technology of and use of the technology. Central South University Press, Changsha (2002). Chinese.
[32]
S.H. Geng.Fundamental research on gas-based direct reduction of iron ore with reformed coke oven gas. Shanghai University Press, Shanghai (2018). Chinese.
[33]
Y.J. Su, M.X. Cai, Y.H. Du, S.L. Chen.Esitimation of two-section series DRI process using coal gas. China Metall, 27 (5) (2017), pp. 27-32. Chinese.
[34]
Z.C. Wang, S.Y. Chen, M.S. Chu, Z.G. Liu, J.W. Zhang. Tentative study on direct reduction iron production by gasification-shaft furnace. China Metall, 23 (1) (2013), pp. 20-25. Chinese.
[35]
Z.C. Wang. Fundamental study on process of coal gasification-gas based shaft furnace direct reduction. Northeastern University Press, Shenyang (2013). Chinese.
[36]
Y.S. Zhou, H. Qian, H.Y. Qi, D.M. Liu, H.T. Feng, et al. Scheme of direct reduction iron production combined with coal gasification. Iron Steel, 47 (11) (2012), pp. 27-31. Chinese.
[37]
D.G. Yang. A study on process of direct reduction of pellets made from concentrate based on coal gasification. Central South University Press, Changsha (2012). Chinese.
[38]
Y.Q. Li, H. Chen, X.W. Li, Y.S. Zhou, Q.S. Gan. Change of carbon and sulfur contents in the pellets during direct reduction in BL shaft furnace. Baosteel Technol, 5 (2000), pp. 21-24. Chinese.
[39]
Z.T. Feng, H.C. Chu, J.L. Xu. A new use of water gas: production of sponge iron by BL method. Coal Chem Ind, 1 (2000), pp. 51-55. Chinese.
[40]
H. Chen, Y.Q. Li, Y.S. Zhou, B.Q. Chen, X.W. Li, et al. BL shaft furnace direct reduction process. Baosteel Technol, 4 (1999), pp. 25-28. Chinese.
[41]
Z.F. Cui, F.Q. Shangguan, F.J. Wang, J.C. Zhou, A.J. Xu. Analysis and prediction of scrap resources in China from 2022 to 2060. Iron Steel, 58 (6) (2023), pp. 126-133. Chinese.
[42]
R.R. Wang, Y.Q. Zhao, A. Babich, D. Senk, X.Y. Fan. Hydrogen direct reduction (H-DR) in steel industry—an overview of challenges and opportunities. J Clean Prod, 329 (2021), Article 129797.
[43]
F.M. Shen, X. Jiang, Q.J. Gao, G. Wei, H.Y. Zheng. Situation and prospect on production technology of direct reduction iron. Iron Steel, 52 (1) (2017), pp. 7-12. Chinese.
[44]
Qian LF. Midrex syngas based direct reduction technology. In: Proceedings of the 10th CSM Steel Congress & the 6th Baosteel Biennial Academic Confrence; 2015 Oct 21-23; Shanghai, China. Beijing: Metallurgical Industry Press; 2015. p. 1257-66. Chinese.
[45]
F.M. Zhang, C.Z. Cao, H. Xu. Current status and prospects of gas-based shaft furnace direct reduction technology. Iron Steel, 49 (3) (2014), pp. 1-10. Chinese.
[46]
L.Y. Yi. Fundamental research on gas-based direct reduction of iron ore pellets with carbon monoxide and hydrogen mixtures. Central South University Press, Changsha (2013). Chinese.
[47]
J. Fang.Non-blast furnace ironmaking process and theory. ( 2nd ed.), Metallurgical Industry Press, Beijing (2012). Chinese.
[48]
H.D. Ye, F.Q. Zheng, B. Hu, W.L. Li, C. Liu. Status and development trend of hydrogen-based fuel non-blast furnace iron-making technology. Sintering Pelletizing, 47 (1) (2022), pp. 10-17. Chinese.
[49]
X.Y. Guo, Y.L. Chen, Q.H. Tian, Q.M. Wang. Research progeress on hydrogen metallurgy theory and method. Chin J Nonferrous Met, 31 (7) (2021), pp. 1891-1906. Chinese.
[50]
L.Y. Yi, Z.C. Huang, H. Peng, T. Jiang. Action rules of H2 and CO in gas-based direct reduction of iron ore pellets. J Cent South Univ, 19 (8) (2012), pp. 2291-2296.
[51]
S.X. Wen. A novel direct reduction technology-energiron. Sintering Pelletizing, 34 (4) (2009), p. 27. Chinese.
[52]
S.K. Dutta, R. Sah. Direct reduced iron:production. Encyclopedia of iron, steel, and their alloys, CRC Press, New York City (2016).
[53]
T. Battle, U. Srivastava, J. Kopfle, R. Hunter, J. McClelland. The direct reduction of iron. Treatise on process metallurgy, Elsevier, Cambridge (2014).
[54]
J.H. Shao, Z.C. Guo, H.Q. Tang.Influence of temperature on sticking behavior of iron powder in fluidized bed. ISIJ Int, 51 (8) (2011), pp. 1290-1295.
[55]
L. Guo, Z. Wang, S.P. Zhong, Q.P. Bao, Z.C. Guo.Fluidization state monitoring using electric current during fluidized bed reduction of iron ore. Powder Technol, 343 (2019), pp. 683-692.
[56]
T. Wolfinger, D. Spreitzer, J. Schenk. Analysis of the usability of iron ore ultra-fines for hydrogen-based fluidized bed direct reduction—a review. Materials, 15 (7) (2022), p. 2687.
[57]
S.Y. He, H.Y. Sun, C.Q. Hu, J. Li, Q.S. Zhu, H. Li.Direct reduction of fine iron ore concentrate in a conical fluidized bed. Powder Technol, 313 (2017), pp. 161-168.
[58]
Z. Du, Y. Ge, F. Liu, C.L. Fan, F. Pan. Effect of different modification methods on fluidized bed hydrogen reduction of cohesive iron ore fines. Powder Technol, 400 (2022), Article 117226.
[59]
A.M. Nyembwe, R.D. Cromarty, A.M. Garbers-Craig. Prediction of the granule size distribution of iron ore sinter feeds that contain concentrate and micropellets. Powder Technol, 295 (2016), pp. 7-15.
[60]
M.K. Sharma, V. Solanki, G.G. Roy, P.K. Sen. Study of reduction behaviour of prefabricated iron ore-graphite/coal composite pellets in rotary hearth furnace. Ironmaking Steelmaking, 40 (8) (2013), pp. 590-597.
[61]
F.M. Zhang. Progress of rotary hearth furnace direct reduction technology. J Iron Steel Res Int, 16 (2009), pp. 1347-1352.
[62]
X.T. Yu. Sponge iron and reduced iron powder produced by Hoganas process. Powder Metall Technol, 3 (1997), pp. 31-39. Chinese.
[63]
S.Y. Wu, N.P. Xu, Y.L. Jin. Recent state of Hoganas process in China. Sintering Pelletizing, 1 (1996), pp. 36-39. Chinese.
[64]
China mineral resources 2022. Report. Beijing: Ministry of Natural Resources of the People’s Republic of China; 2022 Sep. Chinese.
[65]
China natural gas development report 2022. Report. Beijing: Petroleum Industry Press; 2022 Aug. Chinese.
[66]
F. Gao, B.L. Liu, M.L. Li, C.X. Li. Global natural gas development trend and enlightenment. China Pet Explor, 27 (6) (2022), pp. 13-21. Chinese.
[67]
R. Chen, H. Bai. Review of global natural gas market in recent years and prospects for 2025. J China Univ Pet, 35 (5) (2019), pp. 1-7.
[68]
S.W. Zhou, J.L. Zhu, T.W. Shan, Q. Fu, D. Zhang, et al. Development status and outlook of natural gas and LNG industry in China. China Offshore Oil Gas, 34 (1) (2022), pp. 1-8.
[69]
J.W. Cao, W.Q. Zhang, Y.F. Li, C.H. Zhao, Y. Zheng, et al. Current status of hydrogen production in China. Prog Chem, 33 (12) (2021), pp. 2215-2244. Chinese.
[70]
Y.J. Zhao, Q. Yi, T. Wang, J.C. Han, Y. Cui, Q. Liu, et al. Key technologies and strategic thinking for the coal-coking-hydrogen-steel industry chain in China. SSCAE, 23 (5) (2021), pp. 103-115. Chinese.
[71]
Y. Zhou, H.J. Zhou, C.M. Xu. Exploration of hydrogen sources for the low-carbon and green production in the steel industry in China. Chem Ind Eng Prog, 41 (2) (2022), pp. 1073-1077. Chinese.
[72]
Y.X. Dai, J.J. Yu, Z.C. Wang, Y. Chen. Consideration on layout of metallurgical processes of long and short flow based on coke oven gas balance. Sintering Pelletizing, 47 (3) (2022), pp. 66-72. Chinese.
[73]
J.J. Li, W.J. Cheng. Comparative life cycle energy consumption, carbon emissions and economic costs of hydrogen production from coke oven gas and coal gasification. Int J Hydrogen Energy, 45 (51) (2020), pp. 27979-27993.
[74]
I.N. Zaini, A. Nurdiawati, J. Gustavsson, W.J. Wei, H. Thunman, R. Gyllenram, et al. Decarbonising the iron and steel industries: production of carbon-negative direct reduced iron by using biosyngas. Energy Convers Manage, 281 (2023), p. 19.
[75]
A. Nurdiawati, I.N. Zaini, W.J. Wei, R. Gyllenram, W.H. Yang, P. Samuelsson.Towards fossil-free steel: life cycle assessment of biosyngas-based direct reduced iron (DRI) production process. J Clean Prod, 393 (2023), p. 15.
[76]
J.L. Zhang, H.Y. Fu, Y.X. Liu, H. Dang, L. Ye, A.N. Conejio, et al. Review on biomass metallurgy: pretreatment technology, metallurgical mechanism and process design. Int J Miner Metall Mater, 29 (6) (2022), pp. 1133-1149.
[77]
I. Shukla.Potential of renewable agricultural wastes in the smart and sustainable steelmaking process. J Clean Prod, 370 (2022), p. 13.
[78]
H.J. Zhou, Y. Zhou, C.M. Xu. Exploration of refining and chemical integration under China’s dualcarbon target. Chem Ind Eng Prog, 41 (4) (2022), pp. 2226-2230. Chinese.
[79]
F. Patisson, O. Mirgaux. Hydrogen ironmaking: how it works. Metals, 10 (7) (2020), p. 922.
[80]
D. Spreitzer, J. Schenk.Reduction of iron oxides with hydrogen—a review. Steel Res Int, 90 (10) (2019), p. 1900108.
[81]
Xu WR, Zhu RL, Mao XM, Chu MS, Tang J. Current status and main problems of hydrogen metallurgy. In: Proceedings of the 13th CSM Steel Congress; 2022 Apr 9-10; Chongqing, China. Beijing: Metallurgical Industry Press; 2022. p. 507-9. Chinese.
[82]
F. Li, M. Chu, J. Tang, Z. Liu, Z. Zhao, P. Liu, et al. Quantifying the energy saving potential and environmental benefit of hydrogen-based steelmaking process: status and future prospect. Appl Therm Eng, 211 (2022), Article 118489.
[83]
Y.Z. Wang, S. Zhou, X.W. Zhou, X.M. Ou. Cost analysis of different hydrogen production methods in China. Energy China, 43 (5) (2021), pp. 29-37. Chinese.
[84]
E. Cetinkaya, I. Dincer, G.F. Naterer. Life cycle assessment of various hydrogen production methods. Int J Hydrogen Energy, 37 (3) (2012), pp. 2071-2080.
[85]
R. Shandarr, C.A. Trudewind, P. Zapp. Life cycle assessment of hydrogen production via electrolysis—a review. J Clean Prod, 85 (2014), pp. 151-163.
[86]
M.D. Ji, J.L. Wang. Review and comparison of various hydrogen production methods based on costs and life cycle impact assessment indicators. Int J Hydrogen Energy, 46 (78) (2021), pp. 38612-38635.
[87]
J.N. Tian, J. Jiang, Y. Luo, X. Ma. Development status and trend of green hydrogen energy technology. Distrib Energy, 6 (02) (2021), pp. 8-13. Chinese.
[88]
Y.X. Han, Q. Zhang, Y.S. Sun, P. Gao, Y.J. Li. Progress in pharse transformation technology for clean and efficient utilization of refractory iron. J Iron Steel Res Int, 34 (12) (2022), pp. 1303-1313.
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