700 °C 及以上蒸汽温度下先进USC发电厂用耐热材料的研究和开发
Research and Development of Heat-Resistant Materials for Advanced USC Power Plants with Steam Temperatures of 700 °C and Above
欧洲、美国、日本已开展蒸汽温度为700 °C 及以上的先进超超临界(A-USC) 发电厂用材料开发项目,以实现更高能效和低二氧化碳排放量。近年来中国、印度等也开展了上述项目的开发和研究。这些项目涉及采用镍基合金更换马氏体9%~12%Cr 钢以用于最高温度的锅炉和涡轮部件,从而在700 °C 及以上温度下提供充足的蠕变强度。为尽量减少对昂贵的镍基合金的需求,马氏体9%~12%Cr 钢可用于A-USC 电厂中的次高温部件(最高温度不超过650 °C)。本文综述了A-USC 电厂厚型材锅炉和涡轮部件用镍基合金和马氏体9%~12%Cr 钢的研究和开发,主要关注高温下基底金属和焊缝的长期蠕变断裂强度、焊缝强度损失、蠕变疲劳性质和显微结构演化。
Materials-development projects for advanced ultra-supercritical (A-USC) power plants with steam temperatures of 700 °C and above have been performed in order to achieve high efficiency and low CO2 emissions in Europe, the US, Japan, and recently in China and India as well. These projects involve the replacement of martensitic 9%−12% Cr steels with nickel (Ni)-base alloys for the highest temperature boiler and turbine components in order to provide sufficient creep strength at 700 °C and above. To minimize the requirement for expensive Ni-base alloys, martensitic 9%−12% Cr steels can be applied to the next highest temperature components of an A-USC power plant, up to a maximum of 650 °C. This paper comprehensively describes the research and development of Ni-base alloys and martensitic 9%−12% Cr steels for thick section boiler and turbine components of A-USC power plants, mainly focusing on the long-term creep-rupture strength of base metal and welded joints, strength loss in welded joints, creep-fatigue properties, and microstructure evolution during exposure at elevated temperatures.
镍基合金 / 9 %~12 % Cr 钢 / 蠕变强度 / 蠕变疲劳性质 / 焊缝 / 晶界 / 显微结构 / γ′ / M23C6 碳化物
Ni-base alloy / 9%−12% Cr steel / creep strength / creep-fatigue property / welded joint / grain boundary / microstructure / γ′ / M23C6 carbide
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