Flotation separation of arsenopyrite from several sulphide minerals with organic depressants

王福良

中国工程科学 ›› 2008, Vol. 10 ›› Issue (4) : 11 -16.

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中国工程科学 ›› 2008, Vol. 10 ›› Issue (4) : 11 -16.

Flotation separation of arsenopyrite from several sulphide minerals with organic depressants

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Flotation separation of arsenopyrite from several sulphide minerals with organic depressants

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In this paper, the separation of arsenopyrite from chalcopyrite, pyrite, galena with organic depressants (guergum and sodium humic) was discussed, and the functioning mechanism of those organic depressants discussed. The experimental results of monomineral flotation indicated that both guergum and sodium humic have depressing effect on arsenopyrite in the presence of ethyl xanthate. Guergum and sodium humic showed different depressing ability to pyrite, chalcopyrite and galena, and the higher the pH-vualue in pulp, the stronger the depressing ability. Ultraviolet-Visible Spectrophotometric study showed that the adsorption layer of xanthate on surface of minerals had been desorbed by the two organic depressants, and the selective desorption of the collector layer was found from different minerals. The xanthate cover on minerals surface was set free when dosage of the organic depressants was high enough. For artificially-mixed minerals, the separation of arsenopyrite from other sulphides was successfully realized by controlling dosage of the organic depressants. And sodium humic had been used successfully to decrease arsenic content in sulphide concentrates in a commercial Lead-Zinc concentrator.

Abstract

In this paper, the separation of arsenopyrite from chalcopyrite, pyrite, galena with organic depressants (guergum and sodium humic) was discussed, and the functioning mechanism of those organic depressants discussed. The experimental results of monomineral flotation indicated that both guergum and sodium humic have depressing effect on arsenopyrite in the presence of ethyl xanthate. Guergum and sodium humic showed different depressing ability to pyrite, chalcopyrite and galena, and the higher the pH-vualue in pulp, the stronger the depressing ability. Ultraviolet-Visible Spectrophotometric study showed that the adsorption layer of xanthate on surface of minerals had been desorbed by the two organic depressants, and the selective desorption of the collector layer was found from different minerals. The xanthate cover on minerals surface was set free when dosage of the organic depressants was high enough. For artificially-mixed minerals, the separation of arsenopyrite from other sulphides was successfully realized by controlling dosage of the organic depressants. And sodium humic had been used successfully to decrease arsenic content in sulphide concentrates in a commercial Lead-Zinc concentrator.

关键词

arenic / arsenopyrite / organic depressant / flotation

Key words

arenic / arsenopyrite / organic depressant / flotation

Author summay

王梦恕(1938-),男,河南温县人,中国工程院院士,教授级高级工程师;杨会军(1969-),男,甘肃天水市人,中铁隧道集团有限公司科研所高级工程师,兰州大学博士,从事隧道与地下工程科研、施工

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王福良 Flotation separation of arsenopyrite from several sulphide minerals with organic depressants[J]. 中国工程科学, 2008, 10(4): 11-16 DOI:

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