从硫化矿高酸浸出的硫酸锌溶液中萃取提锗全流程研究
包福毅,方军,朱大和,陈世明,黄华堂,李学全,刘韬,王侃,黄艳芬
中国工程科学 ›› 2001, Vol. 3 ›› Issue (12) : 58 -67.
从硫化矿高酸浸出的硫酸锌溶液中萃取提锗全流程研究
Study on Germanium Extraction From Zinc Sulfate Leached Solution
研究在硫酸锌溶液中用萃取法提取锗,萃取剂为7815(氧肟酸),稀释剂为磺化煤油,添加剂为T试剂,反萃剂为NaOH,原料液为云南会泽铅锌矿硫化锌高温、高酸、高铁浸出溶液;工艺就萃取体系的选择,金属的萃取平衡,工艺参数的确定,工艺流程的设计以及工艺流程的串级实验等进行了深入研究,取得了锗萃取率大于96%,反萃率大于97%,锗精矿含锗大于30%的结果。
This process is concerned with solvent extraction of Ge from zinc sulfate solution with 7815 (hy-droxamic acid as) extractant, sulfonated kerosene as diluent, T reagent as additive and NaOH as re-extract ant. The feed liquid is the leachate of Yunnan Huize lead-zinc ore leached at high temperature by strong sulphuric acid and ferric solution. The temperature is about 70~80℃ . The concentration of sulphuric acid and ferric inos are 90 g/L and 10〜15 g/L respectively. Selection of extraction system, metal exaction balance, process parameters, process design and the overall process experiment have been investigated. The Ge extraction is higher than 96% , are re-extraction is higher than 97% , Ge conlent in the germanium concentrate, which is ohtained by nentralization is higher than 30% .
extraction / germanium / 7815 / T-reagent
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