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Synthesis and ultraviolet/aggregation-induced emission investigation of novel tetraphenylvinyl hydrazone

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2061-2073 doi: 10.1007/s11705-023-2366-0

摘要： Herein, three novel tetraphenylethylene hydrazone chemosensors TC12, SC16, and TC16 are prepared for the selective detection of F−. Two NH and one C=N units are incorporated into the sensors for better colorimetric responses, whereas the tetraphenyl unit is in charge of the aggregation-induced emission effect. Among them, compounds SC16 and TC16 form stable gels with some organic solvents. All the tetrahydrofuran/H2O solutions of the three compounds exhibit aggregation-induced emission effect, whereby the fluorescence emission increases by varying degrees with the volume of poor solvent water. Moreover, good aggregation-induced emission effects are observed in the self-assembly of SC16 and TC16. As a sample chemosensor, TC12 in tetrahydrofuran responds to F− selectively with high sensitivity, with the colorimetric and fluorometric detection limits of 8.25 × 10−7 mol·L–1 and 2.69 × 10−7 mol·L–1, respectively. The reversible gel-sol-gel phase transition and color changes indicate that both SC16-dimethyl sulfoxide and TC16-ethyl acetate gels specifically respond to F– with good sensitivity. The detection results are well supported by ultraviolet-visible spectroscopy, fluorescent spectroscopy, and 1H nuclear magnetic resonance. More importantly, the driving forces of gelation are visually clarified through the single crystal X-ray analysis of compound TOMe.

关键词： organogelator     tetraphenylvinyldrazone     single crystal     aggregation-induced emission effect     ion sensing    

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具有聚集诱导发光活性的抗冻水凝胶用于低温环境下多级信息的加密和解密 Article

睢晓洁, 汪晓东, 蔡诚诚, 马君怡, 杨静, 张雷

《工程（英文）》 2023年 第23卷 第4期   页码 82-89 doi: 10.1016/j.eng.2022.03.021

摘要：

抗冻水凝胶可以在零下温度环境中调节内部水分子的冻结行为，从而保持其优异特性（如智能响应性和液体运输）以及拓展其在寒冷条件下的应用。本文开发了一系列具有聚集诱导发光（AIE）活性的抗冻水凝胶，可实现在零下温度的信息加密和解密。通过改变水凝胶内的甜菜碱含量，该水凝胶可呈现出不同的冻结温度（Tf）。当温度高于/低于Tf时，编码于水凝胶内的AIE荧光分子不发射/发射荧光，从而可以实现信息的加密和解密。此外，通过调控水凝胶的冻结程序或者在水凝胶内原位引入具有光热效应的硫化铜纳米颗粒并结合特定的照射条件，可以实现信息的多级加密和解密，从而增强信息的安全性。最后，由于解密的信息图案对温度波动具有不可逆性，因此该具有AIE活性的抗冻水凝胶可作为无需外界供能的防伪标签，用于实时和可视化监测冷冻运输（−80 ℃）过程中生物样本（如间充质干细胞和红细胞）的活性。

关键词： 抗冻水凝胶     聚集诱导发光     加密     解密     防伪    

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Effects of humic acid and surfactants on the aggregation kinetics of manganese dioxide colloids

Xiaoliu HUANGFU,Yaan WANG,Yongze LIU,Xixin LU,Xiang ZHANG,Haijun CHENG,Jin JIANG,Jun MA

《环境科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 105-111 doi: 10.1007/s11783-014-0726-1

摘要： The aggregation of common manganese dioxide (MnO ) colloids has great impact on their surface reactivity and therefore on their fates as well as associated natural and synthetic contaminants in engineered (e.g. water treatment) and natural aquatic environments. Nevertheless, little is known about the aggregation kinetics of MnO colloids and the effect of humic acid (HA) and surfactants on these. In this study, the early stage aggregation kinetics of MnO nanoparticles in NaNO and Ca(NO ) solutions in the presence of HA and surfactants (i.e., sodium dodecyl sulfate (SDS), and polyvinylpyrrolidone (PVP)) were modeled through time-resolved dynamic light scattering. In the presence of HA, MnO colloids were significantly stabilized with a critical coagulation concentration (CCC) of ~300 mmol·L NaNO and 4 mmol·L Ca(NO ) . Electrophoretic mobility (EPM) measurements confirmed that steric hindrance may be primarily responsible for increasing colloidal stability in the presence of HA. Moreover, the molecular and/or chemical properties of HA might impact its stabilizing efficiency. In the case of PVP, only a slight increase of aggregation kinetics was observed, due to steric reactions originating from adsorbed layers of PVP on the MnO surface. Consequently, higher CCC values were obtained in the presence of PVP. However, there was a negligible reduction in MnO colloidal stability in the presence of 20 mg·L SDS.

关键词： humic acid     surfactant     aggregation kinetics     drinking water     manganese dioxide colloids    

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Influence of extracellular polymeric substances from activated sludge on the aggregation kinetics of

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1450-2

摘要：

• The NPs aggregation in the electrolyte solution is consistent with the DLVO theory.

关键词： Silver nanoparticles     Silver sulfide nanoparticles     Extracellular polymeric substances     Aggregation kinetics     Influence mechanisms    

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Trapezoidal Intuitionistic Fuzzy Aggregation Operator Based on Choquet Integral and Its Application to

Xi-hua Li,Xiao-hong Chen

《工程管理前沿（英文）》 2015年 第2卷 第3期   页码 266-276 doi: 10.15302/J-FEM-2015048

摘要： The Choquet integral can serve as a useful tool to aggregate interacting criteria in an uncertain environment. In this paper, a trapezoidal intuitionistic fuzzy aggregation operator based on the Choquet integral is proposed for multi-criteria decision-making problems. The decision information takes the form of trapezoidal intuitionistic fuzzy numbers and both the importance and the interaction information among decision-making criteria are considered. On the basis of the introduction of trapezoidal intuitionistic fuzzy numbers, its operational laws and expected value are defined. A trapezoidal intuitionistic fuzzy aggregation operator based on the Choquet integral is then defined and some of its properties are investigated. A new multi-criteria decision-making method based on a trapezoidal intuitionistic fuzzy Choquet integral operator is proposed. Finally, an illustrative example is used to show the feasibility and availability of the proposed method.

关键词： multi-criteria decision making     trapezoidal intuitionistic fuzzy numbers     Choquet integral     fuzzy measure     aggregation operator    

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Controlling interstory drift ratio profiles via topology optimization strategies

《结构与土木工程前沿（英文）》 2023年 第17卷 第2期   页码 165-178 doi: 10.1007/s11709-022-0892-3

摘要： An approach to control the profiles of interstory drift ratios along the height of building structures via topology optimization is proposed herein. The theoretical foundation of the proposed approach involves solving a min–max optimization problem to suppress the maximum interstory drift ratio among all stories. Two formulations are suggested: one inherits the bound formulation and the other utilizes a p-norm function to aggregate all individual interstory drift ratios. The proposed methodology can shape the interstory drift ratio profiles into inverted triangular or quadratic patterns because it realizes profile control using a group of shape weight coefficients. The proposed formulations are validated via a series of numerical examples. The disparity between the two formulations is clear. The optimization results show the optimal structural features for controlling the interstory drift ratios under different requirements.

关键词： interstory drift ratio     aggregation function     bound formulation     min–max problem     topology optimization    

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Protein aggregation in association with delayed neuronal death in rat model of brain ischemia

GE Pengfei, FU Shuanglin, LI Wenchen, WANG Chonghao, ZHOU Chuibing, LUO Yinan, LUO Tianfei

《医学前沿（英文）》 2008年 第2卷 第1期   页码 70-74 doi: 10.1007/s11684-008-0013-2

摘要： To investigate the relationship between protein aggregation and delayed neuronal death, we adopted rat models of 20 min ischemia. Brain ischemia was produced using the 2-vessel occlusion (2VO) model in rats Light microscopy, transmission electronic microscopy and Western blot analysis were performed for morphological analysis of neurons, and protein detection. The results showed delayed neuronal death took place at 72 h after ischemia-reperfusion, protein aggregates formed at 4 h after reperfusion and reached the peak at 24 h after reperfusion, and Western blot analysis was consistent with transmission electronic microscopy. We conclude that protein aggregation is one of the important factors leading to delayed neuronal death.
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Decoding and quantitative detection of antibiotics by a luminescent mixed-lanthanide-organic framework

《环境科学与工程前沿（英文）》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1589-5

摘要：

● A series of mixed-LOFs and portable LOF-fibers were synthesized.

关键词： Antibiotics     Sensor     Luminescence     Lanthanide-organic frameworks    

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Novel approach to control adsorbent aggregation: iron fixed bentonite-fly ash for Lead (Pb) and Cadmium

Teza Mwamulima, Xiaolin Zhang, Yongmei Wang, Shaoxian Song, Changsheng Peng

《环境科学与工程前沿（英文）》 2018年 第12卷 第2期 doi: 10.1007/s11783-017-0979-6

摘要： In the present study, a novel approach was used to control zero valent iron aggregation and separation problems by fixing zero valent iron (ZVI) on bentonite-fly ash pellets. For this purpose, porous low cost bentonite-fly ash (BFA) pellets with size of 2.00 cm in length and 0.35 cm in diameter were prepared and fixed with ZVI to manufacture zero valent iron bentonite-fly ash (ZVI-BFA) pellets. Importantly, unlike powdered adsorbents, ZVI-BFA can easily be separated from final effluents when exhausted without any disintegration. The performance of the developed novel adsorbent was investigated for the removal of Pb and Cd from aqueous media. At 100 mg·L and 1 g adsorbent, a maximum of 89.5% of Cd and 95.6% of Pb was removed by ZVI-BFA as compared to 56% and 95% removal by BFA. At 200 mg·L , Cd and Pb removal by ZVI-BFA was 56% and 99.8% respectively as compared to only 28% and 96% by BFA. Further, the removal kinetics was best fitted for pseudo-second order model. The study provides the basis for improving the removal capacity of porous materials by iron fixation while taking separation ability into consideration.

关键词： Zero valent iron     Bentonite     Fly ash     Heavy metals removal     Synthesis    

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Autogenous healing mechanism of cement-based materials

《结构与土木工程前沿（英文）》   页码 948-963 doi: 10.1007/s11709-023-0960-3

摘要： Autogenous self-healing is the innate and fundamental repair capability of cement-based materials for healing cracks. Many researchers have investigated factors that influence autogenous healing. However, systematic research on the autogenous healing mechanism of cement-based materials is lacking. The healing process mainly involves a chemical process, including further hydration of unhydrated cement and carbonation of calcium oxide and calcium hydroxide. Hence, the autogenous healing process is influenced by the material constituents of the cement composite and the ambient environment. In this study, different factors influencing the healing process of cement-based materials were investigated. Scanning electron microscopy and optical microscopy were used to examine the autogenous healing mechanism, and the maximum healing capacity was assessed. Furthermore, detailed theoretical analysis and quantitative detection of autogenous healing were conducted. This study provides a valuable reference for developing an improved healing technique for cement-based composites.

关键词： autogenous healing     cement-based materials     healing mechanism     aggregation effect    

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Molecular dynamics simulations of initial Pd and PdO nanocluster growth in a magnetron gas aggregation

Pascal Brault, William Chamorro-Coral, Sotheara Chuon, Amaël Caillard, Jean-Marc Bauchire, Stève Baranton, Christophe Coutanceau, Erik Neyts

《化学科学与工程前沿（英文）》 2019年 第13卷 第2期   页码 324-329 doi: 10.1007/s11705-019-1792-5

摘要： Molecular dynamics simulations are carried out for describing growth of Pd and PdO nanoclusters using the ReaxFF force field. The resulting nanocluster structures are successfully compared to those of nanoclusters experimentally grown in a gas aggregation source. The PdO structure is quasi-crystalline as revealed by high resolution transmission microscope analysis for experimental PdO nanoclusters. The role of the nanocluster temperature in the molecular dynamics simulated growth is highlighted.

关键词： molecular dynamics     cluster growth     plasma sputtering     nanocatalyst    

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Treatment of gingival hyperplasia induced by cyclosporine A

MA Jingzhi, LI Ming, CAO Yingguang

《医学前沿（英文）》 2008年 第2卷 第3期   页码 290-294 doi: 10.1007/s11684-008-0055-5

摘要： The clinical therapy for cyclosporine A (CsA)-induced gingival hyperplasia (GH) and the pathological changes in hyperplastic gingival tissues were investigated. Nine cases of CsA-induced GH after renal transplantation were subjected to periodontal non-surgical treatment and surgical treatment and were followed up. Gingival index (GI), dental plaque index (PLI) and GH degree (GHD) at different time points were measured. Under light and electron microscopy, the pathological changes in hyperplastic gingival tissues were observed. The CsA concentrations in gingival tissues and blood were determined by using fluorescence polarization immunoassay with TDFL monoclonal antibody. The results showed that GI, PLI and GHD in patients with GH declined after periodontal treatment. Two patients suffered from different degrees of GH during the 6 months to 54 months post-transplantation. Under transmission electron microscopy, fibroblasts in the hyperplastic gingival tissues were enlarged, cytoplasmic rough endoplasmic reticula were abundant and expanded slightly, and a few fibroblasts with early apoptotic changes were seen. The concentrations of CsA in hyperplastic gingival tissues were from 351.00 to 1345.47 ng/mL, which were significantly higher than in the blood of the same patients taken at the same time points. It was concluded that GI and PLI declined after periodontal treatment in combination with surgical treatment in patients taking CsA for a long time, but in some patients, GH recurred. The fact that the concentration of CsA in hyperplastic gingival tissues is higher than in blood awaits further studies.

关键词： post-transplantation     Gingival     cytoplasmic     CsA-induced     further    

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Influence of fluid-structure interaction on vortex induced vibration and lock-in phenomena in long span

Nazim Abdul NARIMAN

《结构与土木工程前沿（英文）》 2016年 第10卷 第4期   页码 363-384 doi: 10.1007/s11709-016-0353-y

摘要： In this paper, deck models of a cable stayed bridge are generated in ABAQUS-finite element program once using only CFD model (one-way fluid-structure interaction) and another by using both the CFD model and the CSD model together (two-way fluid-structure interaction) in a co-simulation. Shedding frequencies for the associated wind velocities in the lock-in region are calculated in both approaches. The results are validated with Simiu and Scanlan results. The lift and drag coefficients are determined for the two approaches and the latter results are validated with the flat plate theory results by Munson and coauthors. A decrease in the critical wind velocity and the shedding frequencies considering two-way approach was determined compared to those obtained in the one-way approach. The results of the lift and drag forces in the two-way approach showed appreciable decrease in their values. It was concluded that the two-way approach predicts earlier vortex induced vibration for lower critical wind velocities and lock-in phenomena will appear at lower natural frequencies of the long span bridges. This helps the designers to efficiently plan and consider for the design and safety of the long span bridge against this type of vibration.

关键词： vortex-induced vibration     fluid-structure interaction     Strouhal number     lock-in     kinetic energy    

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Formation of microporous polymeric membranes via thermally induced phase separation: A review

Min Liu,Shenghui Liu,Zhenliang Xu,Yongming Wei,Hu Yang

《化学科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 57-75 doi: 10.1007/s11705-016-1561-7

摘要： A review of recent research related to microporous polymeric membranes formed via thermally induced phase separation (TIPS) and the morphologies of these membranes is presented. A summary of polymers and suitable diluents that can be used to prepare these microporous membranes via TIPS are summarized. The effects of different kinds of polymer materials, diluent types, cooling conditions, extractants and additive agents on the morphology and performance of TIPS membranes are also discussed. Finally new developments in TIPS technology are summarized.

关键词： polymer     microporous membrane     thermally induced phase separation    

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An overview of vortex-induced vibration (VIV) of bridge decks

Teng WU, Ahsan KAREEM

《结构与土木工程前沿（英文）》 2012年 第6卷 第4期   页码 335-347 doi: 10.1007/s11709-012-0179-1

摘要： A brief overview of vortex-induced vibration (VIV) of circular cylinders is first given as most of VIV studies have been focused on this particular bluff cross-section. A critical literature review of VIV of bridge decks that highlights physical mechanisms central to VIV from a renewed perspective is provided. The discussion focuses on VIV of bridge decks from wind-tunnel experiments, full-scale observations, semi-empirical models and computational fluids dynamics (CFD) perspectives. Finally, a recently developed reduced order model (ROM) based on truncated Volterra series is introduced to model VIV of long-span bridges. This model captures successfully salient features of VIV at “lock-in” and unlike most phenomenological models offers physical significance of the model kernels.

关键词： vortex-induced vibration (VIV)     Volterra series     bridge    

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标题 作者 时间 类型 操作

Synthesis and ultraviolet/aggregation-induced emission investigation of novel tetraphenylvinyl hydrazone

期刊论文

具有聚集诱导发光活性的抗冻水凝胶用于低温环境下多级信息的加密和解密

睢晓洁, 汪晓东, 蔡诚诚, 马君怡, 杨静, 张雷

期刊论文

Effects of humic acid and surfactants on the aggregation kinetics of manganese dioxide colloids

Xiaoliu HUANGFU,Yaan WANG,Yongze LIU,Xixin LU,Xiang ZHANG,Haijun CHENG,Jin JIANG,Jun MA

期刊论文

Influence of extracellular polymeric substances from activated sludge on the aggregation kinetics of

期刊论文

Trapezoidal Intuitionistic Fuzzy Aggregation Operator Based on Choquet Integral and Its Application to

Xi-hua Li,Xiao-hong Chen

期刊论文

Controlling interstory drift ratio profiles via topology optimization strategies

期刊论文

Protein aggregation in association with delayed neuronal death in rat model of brain ischemia

GE Pengfei, FU Shuanglin, LI Wenchen, WANG Chonghao, ZHOU Chuibing, LUO Yinan, LUO Tianfei

期刊论文

Decoding and quantitative detection of antibiotics by a luminescent mixed-lanthanide-organic framework

期刊论文

Novel approach to control adsorbent aggregation: iron fixed bentonite-fly ash for Lead (Pb) and Cadmium

Teza Mwamulima, Xiaolin Zhang, Yongmei Wang, Shaoxian Song, Changsheng Peng

期刊论文

Autogenous healing mechanism of cement-based materials

期刊论文

Molecular dynamics simulations of initial Pd and PdO nanocluster growth in a magnetron gas aggregation

Pascal Brault, William Chamorro-Coral, Sotheara Chuon, Amaël Caillard, Jean-Marc Bauchire, Stève Baranton, Christophe Coutanceau, Erik Neyts

期刊论文

Treatment of gingival hyperplasia induced by cyclosporine A

MA Jingzhi, LI Ming, CAO Yingguang

期刊论文

Influence of fluid-structure interaction on vortex induced vibration and lock-in phenomena in long span

Nazim Abdul NARIMAN

期刊论文

Formation of microporous polymeric membranes via thermally induced phase separation: A review

Min Liu,Shenghui Liu,Zhenliang Xu,Yongming Wei,Hu Yang

期刊论文

An overview of vortex-induced vibration (VIV) of bridge decks

Teng WU, Ahsan KAREEM

期刊论文