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Integration of microbial reductive dehalogenation with persulfate activation and oxidation (Bio-RD-PAO

《环境科学与工程前沿（英文）》 2022年第16卷第2期 doi: 10.1007/s11783-021-1457-8

摘要：

•Bio-RD-PAO can effectively and extensively remove organohalides.

关键词： Bio-RD-PAO Microbial reductive dehalogenation Persulfate Organohalide respiration Complete attenuation

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Functionalized activated carbon for the adsorptive removal of perchlorate from water solutions

Rovshan MAHMUDOV, Chinglung CHEN, Chin-Pao HUANG

《化学科学与工程前沿（英文）》 2015年第9卷第2期页码 194-208 doi: 10.1007/s11705-015-1517-3

摘要： Two types of activated carbon, namely, Filtrasorb 400 and Nuchar SA, were functionalized by quaternary ammonium salts (quats), as to enhance perchlorate adsorption. Results showed that the adsorption of quats on Nuchar SA increased with increase in chain length (hydrophobicity) of quats. Filtrasorb 400, however, had limited uptake of long-chain quats such as dodecyltrimethylammonium and hexadecyltrimethylammoium (HDTMA). Results indicated that perchlorate removal by the functionalized activated carbon was directly related to the chain length of the modifying quats. Perchlorate removal by functionalized activated carbon increased with increase in chain length of the modifying quats and became less pH-dependent. Modified Nuchar SA had higher overall perchlorate removal capacity than the modified Filtrasorb F400, but was more strongly affected by pH than Filtrasorb 400. Activated carbon treated with HDTMA exhibited the best perchlorate removal capacity among all quats studied. Results indicated that tailoring the activated carbon surface with HDTMA rendered the activated carbon surface positively charged, which resulted in substantial increase in perchlorate removal compared to unfunctionalized activated carbons.

关键词： perchlorate activated carbon removal functionalization quaternary ammonium salts

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Interactions between nano-TiO

Mingyu LIN,Yao Hsiang TSENG,Chin-Pao HUANG

《化学科学与工程前沿（英文）》 2015年第9卷第2期页码 242-257 doi: 10.1007/s11705-015-1513-7

摘要： Nano-sized titanium dioxide (nano-TiO ) has wide industrial applications and therefore considerable chances of exposure are created for human beings and ecosystems. To better understand the interactions between nano-TiO and aquatic organisms, we first studied TiO uptake by algae exemplified by were exposed to nano-TiO in a series of concentrations and at various pH. TiO uptake was quantified using a sedimentation curve analysis technique. After exposure of algae to TiO , the variation of zeta potential was measured and the morphology of algae-TiO aggregate was observed with scanning electron microscopy and the optical microscopy. The steady-state TiO uptake was found to be pH-dependent and the isotherms can be described well by Freundlich model. TiO deposited on algal surfaces causes the shift of pH of TiO -covered algae from that of algae toward that of TiO . The attraction between TiO -covered algal cells induces the agglomeration of algae and TiO and thus the formation of algae-TiO aggregates in the size of 12 to 50 μm. The 2-D fractal dimension of the aggregates is pH-dependent and ranges from 1.31 to 1.67. The theoretical analysis of the Gibbs energy of interaction indicates that both TiO uptake by algae and the formation of algae-TiO aggregate are influenced by the interaction between TiO particles.

关键词： nano-TiO₂ Pseudokirchneriella subcapitata algal cells titanium dioxide uptake

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Influence of welding residual stresses on the ductile crack growth resistance of circumferentially cracked pipe

rd NYHUS, Zhiliang ZHANG

《结构与土木工程前沿（英文）》 2012年第6卷第3期页码 217-223 doi: 10.1007/s11709-012-0169-3

摘要： Welding residual stress is one of the main concerns for fabrication and operation of steel structures due to its potential effect on structural integrity. This paper focuses on the effect of welding residual stress on the ductile crack growth resistance of circumferentially cracked steel pipes. Two-dimensional axi-symmetry model has been used to simulate the pipe. Residual stresses were introduced into the model by using so-called eigenstrain method. The complete Gurson model has been employed to calculate the ductile crack growth resistance. Results show that residual stresses reduce the ductile crack growth resistance. However, the effect of residual stresses on ductile crack growth resistance decreases with the increase of crack growth. The effect of residual stress has also been investigated for cases with different initial void volume fraction, material hardening and crack sizes.

关键词： residual stress ductile crack growth resistance complete Gurson model eigenstrain method

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Surgical robotics: A look-back of latest advancement and bio-inspired ways to tackle existing challenges

Yang LIU, Jing LIU

《机械工程前沿（英文）》 2012年第7卷第4期页码 376-384 doi: 10.1007/s11465-012-0352-1

摘要：

This article is dedicated to present a review on existing challenges and latest developments in surgical robotics in attempts to overcome the obstacles lying behind. Rather than to perform an exhaustive evaluation, we would emphasize more on the new insight by digesting the emerging bio-inspired surgical technologies with potentials to revolutionize the field. Typical approaches, possible applications, advantages and technical challenges were discussed. Evolutions of surgical robotics and future trends were analyzed. It can be found that, the major difficulties in the field of surgical robots may not be properly addressed by only using conventional approaches. As an alternative, bio-inspired methods or materials may shed light on new innovations. While endeavors to deal with existing strategies still need to be made, attentions should be paid to also borrow ideas from nature.

关键词： minimally invasive surgery surgical robotics haptic feedback miniaturization bio-inspiration bionics

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Bio-based Technologies for Resource Recovery

Aijie Wang, David Stuckey

《环境科学与工程前沿（英文）》 2018年第12卷第4期 doi: 10.1007/s11783-018-1079-y

摘要：

关键词： valign= top class= J_zhaiyao

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Combustion characteristics and kinetics of bio-oil

Ruixia ZHANG, Zhaoping ZHONG, Yaji HUANG

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 119-124 doi: 10.1007/s11705-009-0068-x

摘要： The combustion characteristics of bio-oils derived from rice husk and corn were studied by thermogravimetry analysis. According to the thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA) curves of bio-oils in air and nitrogen atmosphere, we analyzed the combustion characteristics of different kinds of bio-oils in different atmospheres and worked out the combustion kinetics parameters of the bio-oil, providing reliable base data for the burning of bio-oil. The thermogravimetry indicated that the combustion process of bio-oil was divided into three stages. At the same time, the combustion process can be described by different order reaction models, and with the method of Coats-Redfern, the activation energy and frequency factor of different kinds of bio-oils were obtained.

关键词： bio-oil combustion characteristics combustion kinetics

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生物柴油技术进展与产业前景

冀星,郗小林,孔林河,李俊峰,李丽

《中国工程科学》 2002年第4卷第9期页码 86-93

摘要：

综述了世界各国生物柴油技术的研究、应用及产业发展状况，分析了生物柴油制备、应用中存在的问题，论述了发展生物柴油产业对我国石油安全、国民经济建设以及对农业产业结构调整的贡献和生物柴油对环境的作用及可能造成的冲击，展望了该产业的发展前景，对该产业的发展提出了建议。

关键词：生物柴油生物柴油制备生物柴油产业

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Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2019年第13卷第4期页码 702-717 doi: 10.1007/s11705-019-1861-9

摘要： The work studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercritical conditions using methanol, ethanol and isopropanol as solvent and hydrogen donor. Characterisation of the bio-oil and the upgraded bio-oils was carried out including moisture content, elemental content, pH, heating value, gas chromatography-mass spectrometry (GCMS), Fourier transform infrared radiation, C nuclear magnetic resonance spectroscopy, and thermogravimetric analysis to evaluate the effects of blending and supercritical reactions. The GCMS analysis indicated that the supercritical methanol reaction removed the acids in the bio-oil consequently the pH increased from 2.39 in the crude bio-oil to 4.04 after the supercritical methanol reaction. The ester contents increased by 87.49% after the supercritical methanol reaction indicating ester formation could be the major deacidification mechanism for reducing the acidity of the bio-oil and improving its pH value. Simply blending crude bio-oil with isopropanol was effective in increasing the C and H content, reducing the O content and increasing the heating value to 27.55 from 17.51 MJ·kg in the crude bio-oil. After the supercritical isopropanol reaction, the heating value of the liquid product slightly further increased to 28.85 MJ·kg .

关键词： bio-oil blending supercritical upgrading characterisation

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volatile organic sulfur compounds in off-gas mixture from a wastewater treatment plant using a two-stage bio-trickling

Shihao Sun, Tipei Jia, Kaiqi Chen, Yongzhen Peng, Liang Zhang

《环境科学与工程前沿（英文）》 2019年第13卷第4期 doi: 10.1007/s11783-019-1148-x

摘要：

A two-stage BTF system was established treating odorous off-gas mixture from a WWTP.

The two-stage BTF system showed resistance for the lifting load of H₂S and VOSC.

Miseq Illumina sequencing showed separated functional microbial community in BTFs.

Avoiding H₂S inhibition and enhancement of VOSC degradation was achieved.

Key control point was discussed to help industrial application of the system.

关键词： Odor Two-stage bio-trickling filter process Bio-trickling filter Hydrogen sulfide Volatile organic sulfur compound

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A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2021年第15卷第1期页码 4-17 doi: 10.1007/s11705-020-1933-x

摘要： This review article summarizes the key published research on the topic of bio-oil upgrading using catalytic and non-catalytic supercritical fluid (SCF) conditions. The precious metal catalysts Pd, Ru and Pt on various supports are frequently chosen for catalytic bio-oil upgrading in SCFs. This is reportedly due to their favourable catalytic activity during the process including hydrotreating, hydrocracking, and esterification, which leads to improvements in liquid yield, heating value, and pH of the upgraded bio-oil. Due to the costs associated with precious metal catalysts, some researchers have opted for non-precious metal catalysts such as acidic HZSM-5 which can promote esterification in supercritical ethanol. On the other hand, SCFs have been effectively used to upgrade crude bio-oil without a catalyst. Supercritical methanol, ethanol, and water are most commonly used and demonstrate catalyst like activities such as facilitating esterification reactions and reducing solid yield by alcoholysis and hydrolysis, respectively.

关键词： bio-oil upgrading supercritical review

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Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes

《化学科学与工程前沿（英文）》 2023年第17卷第5期页码 504-515 doi: 10.1007/s11705-022-2260-1

摘要： Phenolic resins were employed to prepare electrospun porous carbon nanofibers with a high specific surface area as free-standing electrodes for high-performance supercapacitors. However, the sustainable development of conventional phenolic resin has been challenged by petroleum-based phenol and formaldehyde. Lignin with abundant phenolic hydroxyl groups is the main non-petroleum resource that can provide renewable aromatic compounds. Hence, lignin, phenol, and furfural were used to synthesize bio-based phenolic resins, and the activated carbon nanofibers were obtained by electrospinning and one-step carbonization activation. Fourier transform infrared and differential scanning calorimetry were used to characterize the structural and thermal properties. The results reveal that the apparent activation energy of the curing reaction is 89.21 kJ·mol^–1 and the reaction order is 0.78. The activated carbon nanofibers show a uniform diameter, specific surface area up to 1100 m²·g^–1, and total pore volume of 0.62 cm³·g^–1. The electrode demonstrates a specific capacitance of 238 F·g^–1 (0.1 A·g^–1) and good rate capability. The symmetric supercapacitor yields a high energy density of 26.39 W·h·kg^–1 at 100 W·kg^–1 and an excellent capacitance retention of 98% after 10000 cycles. These results confirm that the activated carbon nanofiber from bio-based phenolic resins can be applied as electrode material for high-performance supercapacitors.

关键词： lignin bio-based phenolic resins electrospinning activated carbon nanofibers supercapacitors

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Characterization of humic substances in bio-treated municipal solid waste landfill leachate

Guangxia QI, Dongbei YUE, Yongfeng NIE

《环境科学与工程前沿（英文）》 2012年第6卷第5期页码 711-716 doi: 10.1007/s11783-012-0421-z

摘要： Considerable organic matter remains in municipal solid waste landfill leachate after biological treatments. Humic substances (HSs) dominate the organic matter in bio-treated landfill leachate. In this study, the HSs from landfill leachate treated by membrane bioreactor (MBR-HSs) were analyzed via elemental analysis, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, and charge polarized magic-angle spinning- C-nuclear magnetic resonance. The characteristic absorption in the UV wavelength range indicated the presence of high C=C and C=O double bonds within the MBR-HSs. Compared with commercial HSs, MBR-HSs had lower carbon content [48.14% for fulvic acids (FA) and 49.52% for humic acids (HA)], higher nitrogen content (4.31% for FA and 6.16% for HA), lower aromatic structure content, and higher carbohydrate and carboxylic atoms of carbon content. FA predominantly had an aliphatic structure, and HA had less condensed or substituted aromatic ring structures than natural HA. The aromatic carbon content of MBR-HSs was lower than that of humus-derived HSs but higher than that of waste-derived HSs, indicating that MBR-HSs appeared to be more similar to humus-derived HSs than waste-derived HA.

关键词： bio-treated landfill leachate humic substances elemental analysis spectroscopic characteristics

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SERS nanoprobes for bio-application

Han-Wen Cheng,Jin Luo,Chuan-Jian Zhong

《化学科学与工程前沿（英文）》 2015年第9卷第4期页码 428-441 doi: 10.1007/s11705-015-1536-0

摘要： The ability to tune the size, shape, composition and surface properties impart nanoparticles with the desired functions for bio-application. This article highlights some of the recent examples in the exploration of metal (e.g., gold and silver) nanoparticles, especially those with magnetic properties and bio-conjugated structures, as theranostic nanoprobes. Such nanoprobes exhibit tunable optical, spectroscopic, magnetic, and electrical properties for signal amplifications. Examples discussed in this article will focus on the nanoproble-enhanced colorimetric detection and surface enhanced Raman scattering (SERS) detection of biomarkers or biomolecules such as proteins and DNAs. The understanding of factors controlling the biomolecular interactions is essential for the design of SERS nanoprobes with theranostic functions.

关键词： surface-enhanced Raman scattering functional nanoprobes bio-conjugation metal nanoparticles magnetic properties theranostic materials

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Combustion and emissions of the diesel engine using bio-diesel fuel

YUAN Yinnan, MEI Deqing, WANG Zhong, ZHANG Tian

《机械工程前沿（英文）》 2008年第3卷第2期页码 189-192 doi: 10.1007/s11465-008-0021-6

摘要： The combustion and heat release of engines using diesel fuel and bio-diesel fuel have been investigated. The results illustrate that the combustion happens in advance and the ignition delay period is shortened. The initial heat release peak declines a little, the corresponding crankshaft angle changes in advance, and the combustion duration is prolonged. The economic performance and emission features of diesel engines using diesel fuel and bio-diesel fuel are compared. The results also show that the specific fuel consumption of bio-diesel increases by about 12% .The emissions, such as CO, HC, and particulate matter decrease remarkably whereas NO increases a little.

关键词： advance combustion consumption economic performance combustion duration