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Mechanism of dichloromethane disproportionation over mesoporous TiO
Yuzhou Deng, Shengpan Peng, Haidi Liu, Shuangde Li, Yunfa Chen
《环境科学与工程前沿（英文）》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1113-8
• Mechanism of DCM disproportionation over mesoporous TiO2 was studied. • DCM was completely eliminated at 350℃ under 1 vol.% humidity. • Anatase (001) was the key for disproportionation. • A competitive oxidation route co-existed with disproportionation. • Disproportionation was favored at low temperature.
关键词： Dichloromethane Disproportionation Mechanism Anatase (001) Water dissociation
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