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淀粉 2

加速湿热老化 1

断裂性质 1

生物基材料 1

研究进展 1

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1

纤维 1

聚乳酸 1

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Preparation of starch esters with crosslinking structures derived from dianhydride

Huijuan CHU, Hongliang WEI, Jing ZHU, Shouyin HU

《化学科学与工程前沿(英文)》 2011年 第5卷 第1期   页码 51-54 doi: 10.1007/s11705-010-0534-5

摘要: Starch is a kind of natural polymer used in many industrial fields because of its low cost, availability and biodegradation. Potato starch was modified by esterification with pyromellitic dianhydride, and the products were obtained with crosslinking structures. Orthogonal experiments showed that reactive temperature was the primary influencing factor. The product prepared at 40°C for 3 h with the mass ratio of starch and dianhydride of 16∶1 and pH value of 7.5 exhibited a degree of substitution of 11%. FTIR and UV analysis verified the formation of starch esters.

关键词: potato starch     pyromellitic dianhydride     esterification     crosslink    

Performance of an ANAMMOX reactor treating wastewater generated by antibiotic and starch production processes

Hong YAO, Hao LIU, Yongmiao HE, Shujun ZHANG, Peizhe SUN, Chinghua HUANG

《环境科学与工程前沿(英文)》 2012年 第6卷 第6期   页码 875-883 doi: 10.1007/s11783-012-0459-y

摘要: A pilot-scale anaerobic ammonia oxidation (ANAMMOX) reactor was used to treat mixed wastewater resulting from a chlortetracycline and starch production process. The results, collected over the course of 272 days, show that the ratio of influent ammonium to nitrite, pH, and temperature can all affect the efficiency of nitrogen removal. The ratio of influent ammonium to nitrite was maintained at about 1:1 at a concentration below 200 mg·L for both influent ammonium and nitrite. The total nitrogen (TN) loading rate was 0.15–0.30 kgN·m ·d , pH remained at 7.8–8.5, and temperature was recorded at 33±1°C. The rate of removal of ammonia, nitrite, and TN were over 90%, 90%, and 80%, and the effluent ammonium, nitrite and TN concentrations were below 50, 30, and 100 mg·L .

关键词: anaerobic ammonia oxidation     antibiotic and starch production     ratio of ammonia to nitrite     total nitrogen    

Performance of inverse fluidized bed bioreactor in treating starch wastewater

M. RAJASIMMAN, C. KARTHIKEYAN

《化学科学与工程前沿(英文)》 2009年 第3卷 第3期   页码 235-239 doi: 10.1007/s11705-009-0020-0

摘要: Aerobic digestion of starch industry wastewater was carried out in an inverse fluidized bed bioreactor using low-density (870 kg/m ) polypropylene particles. Experiments were carried out at different initial substrate concentrations of 2250, 4475, 6730, and 8910 mg COD/L and for various hydraulic retention times (HRT) of 40, 32, 24, 16, and 8 h. Degradation of organic matter was studied at different organic loading rates (OLR) by varying the HRT and the initial substrate concentration. From the results it was observed that the maximum COD removal of 95.6% occurred at an OLR of 1.35 kg COD/(m ·d) and the minimum of 51.8% at an OLR of 26.73 kg COD/(m ·d). The properties of biomass accumulation on the surface of particles were also studied. It was observed that constant biomass loading was achieved over the entire period of operation.

关键词: inverse fluidization     low-density particles     polypropylene     starch     biofilm    

Preparation and swelling properties of a starch-g-poly(acrylic acid)/organo-mordenite hydrogel composite

Yan Zhang,Pingqiang Gao,Lin Zhao,Yizhong Chen

《化学科学与工程前沿(英文)》 2016年 第10卷 第1期   页码 147-161 doi: 10.1007/s11705-015-1546-y

摘要: A novel hydrogel composite was prepared via inverse suspension polymerization using starch, acrylic acid and organo-mordenite micropowder with the crosslinker, , ′-methylenebisacrylamide and the initiator, potassium persulfate. Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy confirmed that the acrylic acid was grafted onto the backbone of the corn starch, that the organo-mordenite participated in the polymerization, and that the addition of organo-mordenite improved the surface morphology of the hydrogel composite. The swelling capacity of the hydrogel composite was evaluated in distilled water, and solutions with different pH values, and various salt solutions. It was found that the incorporation of 10 wt-% organo-mordenite enhanced the water absorbency by 144% (from 268 to 655 g·g ) and swelling was extremely sensitive to the pH values, the concentration of the salt solution and cation type. Swelling kinetics and water diffusion mechanism of the hydrogel composite in distilled water were also discussed. Moreover, the hydrogel composite showed excellent reversibility of water absorption even after five repetitive cycles and the hydrogel composite exhibited significant environmental-responsiveness by changing the swelling medium from distilled water to 0.1 mol·L NaCl solution. In addition, the loading and release of urea by the hydrogel composite were tested and the nutrient-slow-release capability of this material was found to be suitable for many potential applications.

关键词: hydrogel composite     environmental-responsiveness     organo-mordenite     starch     acrylic acid    

Wastewater-nitrogen removal using polylactic acid/starch as carbon source: Optimization of operating

Yan GUO, Chuanfu WU, Qunhui WANG, Min YANG, Qiqi HUANG, Markus MAGEP, Tianlong ZHENG

《环境科学与工程前沿(英文)》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0845-y

摘要: The use of PLA/starch blends for nitrogen removal was achieved. The influence of different operating parameters on responses was verified using RSM. The conditions for desired responses were successfully optimized simultaneously. Blends material may have a promising application prospect in the future. Nitrogen removal from ammonium-containing wastewater was conducted using polylactic acid (PLA)/starch blends as carbon source and carrier for functional bacteria. The exclusive and interactive influences of operating parameters (i.e., temperature, pH, stirring rate, and PLA-to-starch ratio (PLA proportion)) on nitrification ( ), denitrification ( ), and COD release rates ( ) were investigated through response surface methodology. Experimental results indicated that nitrogen removal could be successfully achieved in the PLA/starch blends through simultaneous nitrification and denitrification. The carbon release rate of the blends was controllable. The sensitivity of , , and to different operating parameters also differed. The sequence for each response was as follows: for , pH>stirring rate>PLA proportion>temperature; for , pH>PLA proportion>temperature>stirring rate; and for , stirring rate>pH>PLA proportion>temperature. In this study, the following optimum conditions were observed: temperature, 32.0°C; pH 7.7; stirring rate, 200.0 r·min ; and PLA proportion, 0.4. Under these conditions, , , and were 134.0 μg-N·g-blend ·h , 160.9 μg-N·g-blend ·h , and 7.6 × 10 μg-O·g-blend ·h , respectively. These results suggested that the PLA/starch blends may be an ideal packing material for nitrogen removal.

关键词: Nitrogen removal     Polylactic acid     Starch     Carbon source     Response surface methodology    

Microbial community structure and dynamics of starch-fed and glucose-fed chemostats during two years

Min GOU,Jing ZENG,Huizhong WANG,Yueqin TANG,Toru SHIGEMATSU,Shigeru MORIMURA,Kenji KIDA

《环境科学与工程前沿(英文)》 2016年 第10卷 第2期   页码 368-380 doi: 10.1007/s11783-015-0815-9

摘要: The microbial community structures of two mesophilic anaerobic chemostats, one fed with glucose, the other with starch as sole carbon sources, were studied at various dilution rates (0.05–0.25 d for glucose and 0.025–0.1 d for starch) during two years continuous operation. In the glucose-fed chemostat, the aceticlastic methanogen spp. and hydrogenotrophic methanogen spp. predominated at low dilution rates, whereas spp. and the hydrogenotrophic spp. predominated together when dilution rates were greater than 0.1 d . Bacteria affiliated with the phyla Bacteroidetes, Spirochaetes, and Actinobacteria predominated at dilution rates of 0.05, 0.1, and 0.15 d , respectively, while Firmicutes predominated at higher dilution rates (0.2 and 0.25 d ). In the starch-fed chemostat, the aceticlastic and hydrogenotrophic methanogens coexisted at all dilution rates. Although bacteria belonging to only two phyla were mainly responsible for starch degradation (Spirochaetes at the dilution rate of 0.08 d and Firmicutes at other dilution rates), different bacterial genera were identified at different dilution rates. With the exception of Archaea in the glucose-fed chemostat, the band patterns revealed by denaturing gradient gel electrophoresis (DGGE) of the microbial communities in the two chemostats displayed marked changes during long-term operation at a constant dilution rate. The bacterial community changed with changes in the dilution rate, and was erratic during long-term operation in both glucose-fed and starch-fed chemostats.

关键词: microbial community     glucose degradation     starch degradation     dilution rate     continuous methane fermentation     phylogenetic analysis    

Annotation and validation of genes involved in photosynthesis and starch synthesis from a

Yang ZHANG,Xin CHEN,Haiyan WANG,Zhiqiang XIA,Peng LING,Wenquan WANG

《农业科学与工程前沿(英文)》 2016年 第3卷 第4期   页码 308-320 doi: 10.15302/J-FASE-2016113

摘要: A full-length cDNA library from leaf and root tissues of cassava ( ) Arg7 and one accession of its wild ancestor W14 ( ssp. ) has been constructed. The library is comprised of four sub-libraries, containing 32640 recombinant clones, 6028 cDNA clones from their 5′ ends, and 128 clones from the 3′ ends were sequenced. In total, 5013 high-quality expressed sequence tags (ESTs) and 1259 unigenes were obtained. Of these, 746 unigenes were identified by their sequence homologies to ESTs from model plants, and 323 unigenes were mapped onto 114 different KEGG pathways. From these, 24 differentially expressed genes involved in starch metabolism and photosynthesis were identified and five of them were selected to compare their expression level between Arg7 and W14. Notably, Arg7 has a higher net photosynthesis rate in leaves, higher ribulose-1,5-bisphosphate carboxy-lase oxygenase activities in leaves, and higher AGPase activity in roots. This resource is the first EST collection from wild cassava and should be of value for gene discovery, genome annotation and studies of evolution.

关键词: Manihot esculenta     expressed sequence tag     unigene     pathway     expression pattern    

Advancements in non-starch polysaccharides research for frozen foods and microencapsulation of probiotics

Pavan Kumar SOMA, Patrick D. WILLIAMS, Y. Martin LO,

《化学科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 413-426 doi: 10.1007/s11705-009-0254-x

摘要: Conventionally used in the food industry as stabilizing, thickening, gelling, and suspending or dispersing agents, non-starch polysaccharides such as xanthan gum are known to improve the texture of certain frozen products. Another polysaccharide that has received significant attention in recent years is chitosan, a natural biopolymer derived from chitin. In the wake of growing interest in finding ideal encapsulating agents for probiotics, non-starch polysaccharides have been investigated. Scattered research can be found on the effect of each individual polysaccharide, but there remains a void in the literature in terms of closely comparing the characteristics of non-starch polysaccharides for these applications, especially when more than one biopolymer is employed. A good understanding of the tools capable of elucidating the underlying mechanisms involved is essential in ushering further development of their applications. Therefore, it is this review’s intention to focus on the selection criteria of non-starch polysaccharides based on their rheological properties, resistance to harsh conditions, and ability to improve sensory quality. A variety of critical tools is also carefully examined with respect to the attainable information crucial to frozen food and microencapsulation applications.

关键词: development     literature     attainable information     biopolymer     capable    

淀粉基膳食食品的设计及其结构研究 Review

柏玉香, 李晓晓, 纪杭燕, 王禹, 郑丹妮, 王艳丽, 金征宇

《工程(英文)》 2021年 第7卷 第5期   页码 663-673 doi: 10.1016/j.eng.2020.12.007

摘要:

碳水化合物是食物的主要成分之一,也是人类膳食的主要能量来源,通常包括糖类、淀粉和纤维。在这三大来源中,淀粉是储量最丰富的碳水化合物之一。研究淀粉不仅可以加深人们对淀粉在人体中的功能的理解,而且有助于开发设计新的淀粉基膳食食品。本文首先综述了国内外对快消化淀粉(RDS)、慢消化淀粉(SDS)和抗性淀粉(RS)等的最新研究进展,然后介绍了淀粉基膳食食品消化率的体内和体外测定方法。在此基础上,提出了通过直接添加变性淀粉或改变加工条件来设计新型淀粉基膳食食品的研究策略。最后,本文对淀粉类食品未来的研究方向进行了展望。

关键词:     淀粉     纤维     膳食食品    

Simultaneous saccharification and fermentation of wheat bran flour into ethanol using coculture of amylotic

K. Manikandan, T. Viruthagiri

《化学科学与工程前沿(英文)》 2009年 第3卷 第3期   页码 240-249 doi: 10.1007/s11705-009-0205-6

摘要: Studies on simultaneous saccharification and fermentation (SSF) of wheat bran flour, a grain milling residue as the substrate using coculture method were carried out with strains of starch digesting and nonstarch digesting and sugar fermenting in batch fermentation. Experiments based on central composite design (CCD) were conducted to maximize the glucose yield and to study the effects of substrate concentration, pH, temperature, and enzyme concentration on percentage conversion of wheat bran flour starch to glucose by treatment with fungal α-amylase and the above parameters were optimized using response surface methodology (RSM). The optimum values of substrate concentration, pH, temperature, and enzyme concentration were found to be 200 g/L, 5.5, 65°C and 7.5 IU, respectively, in the starch saccharification step. The effects of pH, temperature and substrate concentration on ethanol concentration, biomass and reducing sugar concentration were also investigated. The optimum temperature and pH were found to be 30°C and 5.5, respectively. The wheat bran flour solution equivalent to 6% ( / ) initial starch concentration gave the highest ethanol concentration of 23.1 g/L after 48 h of fermentation at optimum conditions of pH and temperature. The growth kinetics was modeled using Monod model and Logistic model and product formation kinetics using Leudeking-Piret model. Simultaneous saccharificiation and fermentation of liquefied wheat bran starch to bioethanol was studied using coculture of amylolytic fungus and nonamylolytic sugar fermenting .

关键词: simultaneous saccharification and fermentation (SSF)     starch     coculture fermentation     statistical experimental design     bioethanol     Monod model    

生物基全降解复合材料

刘小刚,王莉,李十中,樊琛语

《中国工程科学》 2011年 第13卷 第2期   页码 90-95

摘要:

淀粉/聚乳酸复合具有相对较好的力学性能和生物降解性能,价格也与石油基塑料最为接近,是极具应用前景的全生物降解塑性材料。在分析国内外聚乳酸、淀粉及其复合材料研究现状的基础上,对该类材料的技术发展方向和工业化前景进行了展望。

关键词: 研究进展     生物基材料     降解     淀粉     聚乳酸    

Implications of static

John NSOR-ATINDANA, Maoshen CHEN, Liu WEI, Khin Myat NOE, Yue LI, Fang ZHONG

《农业科学与工程前沿(英文)》 2018年 第5卷 第3期   页码 340-350 doi: 10.15302/J-FASE-2018209

摘要:

Interest in understanding the digestion behavior of starch in the presence of dietary fibers is growing due to the ability of dietary component to control the release and absorption of glucose. This presents an outstanding opportunity to improve the quality of food products by incorporating dietary fiber into starchy food products. The physicochemical properties of different fibers and their behavior in the gastrointestinal tract (GIT) differ. To test the efficacy of these different fibers on starch digestion, static in vitro digestion models under conditions that mimic the human GIT are frequently used. Indeed, many efforts have been committed to the development of various static in vitro protocols for starch digestion. Though not considered as the gold standard in digestibility studies in food science and technology, static simulated models provide a useful alternative to in vivo techniques for rapid screening of the digestibility of food products under conditions that simulate the human GIT. This review presents the current status and development of digestion techniques for simulating digestion conditions in the human GIT, with particular interest on starch digestion in the presence of dietary fiber in the three phases of digestions including the oral, gastric and the intestinal steps. This summary can benefit investigators in developing static in vitro digestion models designed to simulate starch digestion with relevant values of the quantifiable parameters, including pH, enzymes and simulated digestive fluids.

关键词: dietary fiber     in vitro digestion     nutrition     simulation     starch    

Comparative transcriptomics revealed enhanced light responses, energy transport and storage in domestication of cassava (

Zhiqiang XIA,Xin CHEN,Cheng LU,Meiling ZOU,Shujuan WANG,Yang ZHANG,Kun PAN,Xincheng ZHOU,Haiyan WANG,Wenquan WANG

《农业科学与工程前沿(英文)》 2016年 第3卷 第4期   页码 295-307 doi: 10.15302/J-FASE-2016126

摘要: Cassava is a staple food, feed and bioenergy crop important to the world especially in the tropics. Domesticated cassava is characterized by powerful carbohydrate accumulation but its wild progenitor is not. Here, we investigated the transcriptional differences of eight cDNA libraries derived from developing leaf, stem and storage root of cassava cv. Arg7 and an ancestor line, W14, using next generation sequencing system. A total of 41302 assembled transcripts were obtained and from these, 25961 transcripts with FPKM≥3 in at least one library were named the expressed genes. A total of 2117, 1963 and 3584 transcripts were found to be differentially expressed in leaf, stem and storage root (150 d after planting), respectively, between Arg7 and W14 and ascribed to 103, 93 and 119 important pathways in leaf, stem and storage root, respectively. The highlight of this work is that the genes involved in light response, such as those for photosystem I (PSA) and photosystem II (PSB), other genes involved in light harvesting, and some of the genes in the Calvin cycle of carbon fixation were specially upregulated in leaf. Genes for transport and also for key rate-limiting enzymes (PFK, PGK and PK, GAPDH) coupling ATP consumption in glycolysis pathway were predominantly expressed in stem, and genes for sucrose degradation (INVs), amylose synthesis (GBSS) and hydrolysis (RCP1, AMYs), the three key steps of starch metabolism, and transport associated with energy translocation (ABC, AVPs and ATPase) and their upstream transcription factors had enhanced expression in storage root in domesticated cassava. Co-expression networks among the pathways in each organs revealed the relationship of the genes involved, and uncovered some of the important hub genes and transcription factors targeting genes for photosynthesis, transportation and starch biosynthesis.

关键词: cassava     comparative transcriptomics     energy transport     photosynthesis     starch synthesis    

淀粉基API胶合木胶接结构破坏模式及失效机理

时君友,徐文彪,王淑敏

《中国工程科学》 2014年 第16卷 第4期   页码 40-44

摘要:

以淀粉基水性高分子异氰酸酯(API)胶合木胶接结构为研究对象,以胶接的压缩剪切强度为评估指标,通过加速湿热老化试验对胶接结构的破坏模式和失效机理进行了研究。结果表明:胶接结构的断裂性质为韧性断裂,且随着老化时间的增加,其破坏模式为由内聚破坏向内聚破坏+界面破坏转变。在湿热老化试验前期温度对压缩剪切试样性能起主要作用,在老化后期湿度起主要作用。

关键词: 胶接结构     加速湿热老化     断裂性质     破坏模式    

Comparison study on strategies to prepare nanocrystalline Li

Qiang XIAO, Xiaodan TANG, Yefeng LIU, Yijun ZHONG, Weidong ZHU

《化学科学与工程前沿(英文)》 2013年 第7卷 第3期   页码 297-302 doi: 10.1007/s11705-013-1346-1

摘要: A comparison study has been conducted on the strategies for synthesizing nanocrystalline Li ZrO and K-doped Li ZrO absorbents for CO capture at high temperatures, including solid-state and liquid-phase methods, citrate route, and starch-assisted sol-gel method combined with freeze-drying technique. The absorption properties, including uptake rate and absorption capacity, of synthesized absorbents were investigated by thermogravimetric analysis (TGA) at different CO partial pressures. The nanosized Li ZrO crystals synthesized by the citrate route exhibit a faster uptake and a higher, nearly stoichiometric absorption capacity than those synthesized by the solid-state and liquid-phase methods. The doping of K into Li ZrO can significantly improve the uptake rate of CO , especially at low CO partial pressures. For the synthesis of K-doped Li ZrO , the citrate route has poor reproducibility and scalability, whereas the starch-assisted sol-gel method combined with freeze-drying technique is reproducible and easily scaled up, and the thus synthesized absorbents possess excellent CO capture properties.

关键词: CO2 capture     Li2ZrO3     K-doped Li2ZrO3     citrate     starch     freeze-drying technique    

标题 作者 时间 类型 操作

Preparation of starch esters with crosslinking structures derived from dianhydride

Huijuan CHU, Hongliang WEI, Jing ZHU, Shouyin HU

期刊论文

Performance of an ANAMMOX reactor treating wastewater generated by antibiotic and starch production processes

Hong YAO, Hao LIU, Yongmiao HE, Shujun ZHANG, Peizhe SUN, Chinghua HUANG

期刊论文

Performance of inverse fluidized bed bioreactor in treating starch wastewater

M. RAJASIMMAN, C. KARTHIKEYAN

期刊论文

Preparation and swelling properties of a starch-g-poly(acrylic acid)/organo-mordenite hydrogel composite

Yan Zhang,Pingqiang Gao,Lin Zhao,Yizhong Chen

期刊论文

Wastewater-nitrogen removal using polylactic acid/starch as carbon source: Optimization of operating

Yan GUO, Chuanfu WU, Qunhui WANG, Min YANG, Qiqi HUANG, Markus MAGEP, Tianlong ZHENG

期刊论文

Microbial community structure and dynamics of starch-fed and glucose-fed chemostats during two years

Min GOU,Jing ZENG,Huizhong WANG,Yueqin TANG,Toru SHIGEMATSU,Shigeru MORIMURA,Kenji KIDA

期刊论文

Annotation and validation of genes involved in photosynthesis and starch synthesis from a

Yang ZHANG,Xin CHEN,Haiyan WANG,Zhiqiang XIA,Peng LING,Wenquan WANG

期刊论文

Advancements in non-starch polysaccharides research for frozen foods and microencapsulation of probiotics

Pavan Kumar SOMA, Patrick D. WILLIAMS, Y. Martin LO,

期刊论文

淀粉基膳食食品的设计及其结构研究

柏玉香, 李晓晓, 纪杭燕, 王禹, 郑丹妮, 王艳丽, 金征宇

期刊论文

Simultaneous saccharification and fermentation of wheat bran flour into ethanol using coculture of amylotic

K. Manikandan, T. Viruthagiri

期刊论文

生物基全降解复合材料

刘小刚,王莉,李十中,樊琛语

期刊论文

Implications of static

John NSOR-ATINDANA, Maoshen CHEN, Liu WEI, Khin Myat NOE, Yue LI, Fang ZHONG

期刊论文

Comparative transcriptomics revealed enhanced light responses, energy transport and storage in domestication of cassava (

Zhiqiang XIA,Xin CHEN,Cheng LU,Meiling ZOU,Shujuan WANG,Yang ZHANG,Kun PAN,Xincheng ZHOU,Haiyan WANG,Wenquan WANG

期刊论文

淀粉基API胶合木胶接结构破坏模式及失效机理

时君友,徐文彪,王淑敏

期刊论文

Comparison study on strategies to prepare nanocrystalline Li

Qiang XIAO, Xiaodan TANG, Yefeng LIU, Yijun ZHONG, Weidong ZHU

期刊论文