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Solar fuel from photo-thermal catalytic reactions with spectrum-selectivity: a review

Sanli TANG, Jie SUN, Hui HONG, Qibin LIU

《能源前沿(英文)》 2017年 第11卷 第4期   页码 437-451 doi: 10.1007/s11708-017-0509-z

摘要: Solar fuel is one of the ideal energy sources in the future. The synergy of photo and thermal effects leads to a new approach to higher solar fuel production under relatively mild conditions. This paper reviews different approaches for solar fuel production from spectrum-selective photo-thermal synergetic catalysis. The review begins with the meaning of synergetic effects, and the mechanisms of spectrum-selectivity and photo-thermal catalysis. Then, from a technical perspective, a number of experimental or theoretical works are sorted by the chemical reactions and the sacrificial reagents applied. In addition, these works are summarized and tabulated based on the operating conditions, spectrum-selectivity, materials, and productivity. A discussion is finally presented concerning future development of photo-thermal catalytic reactions with spectrum-selectivity.

关键词: photo-thermal catalysis     spectrum-selectivity     solar fuel     full-spectrum    

Ultrathin microcrystalline hydrogenated Si/Ge alloyed tandem solar cells towards full solar spectrum

Yu Cao, Xinyun Zhu, Xingyu Tong, Jing Zhou, Jian Ni, Jianjun Zhang, Jinbo Pang

《化学科学与工程前沿(英文)》 2020年 第14卷 第6期   页码 997-1005 doi: 10.1007/s11705-019-1906-0

摘要: Thin film solar cells have been proved the next generation photovoltaic devices due to their low cost, less material consumption and easy mass production. Among them, micro-crystalline Si and Ge based thin film solar cells have advantages of high efficiency and ultrathin absorber layers. Yet individual junction devices are limited in photoelectric conversion efficiency because of the restricted solar spectrum range for its specific absorber. In this work, we designed and simulated a multi-junction solar cell with its four sub-cells selectively absorbing the full solar spectrum including the ultraviolet, green, red as well as near infrared range, respectively. By tuning the Ge content, the record efficiency of 24.80% has been realized with the typical quadruple junction structure of a-Si:H/a-Si Ge :H/µc-Si:H/µc-Si Ge :H. To further reduce the material cost, thickness dependent device performances have been conducted. It can be found that the design of total thickness of 4 m is the optimal device design in balancing the thickness and the . While the design of ultrathin quadruple junction device with total thickness of 2 m is the optimized device design regarding cost and long-term stability with a little bit more reduction in . These results indicated that our solar cells combine the advantages of low cost and high stability. Our work may provide a general guidance rule of utilizing the full solar spectrum for developing high efficiency and ultrathin multi-junction solar cells.

关键词: thin films     solar cells     quadruple junction solar cell     amorphous silicon     silicon germanium alloy     quantum efficiency    

全光谱 LED 照明用荧光粉发展现状及趋势

陈晓霞,张霞 ,刘荣辉,刘元红,周裔朋,庄卫东

《中国工程科学》 2020年 第22卷 第2期   页码 71-78 doi: 10.15302/J-SSCAE-2020.02.011

摘要:

随着人们对照明品质要求的提高,全光谱发光二极管(LED)照明成为发展热点。本文对全光谱 LED 用关键材料——荧光粉进行了详细分析,对比了每种体系的发光性能并给出了各类型的代表材料,重点阐述了紫光–近紫外光激发的多种颜色荧光粉的优劣势、研究进展以及实际应用情况,对该领域存在问题及其发展趋势、重点产业发展方向进行了分析和展望。目前可供全光谱使用的紫光–近紫外光激发的荧光粉存在蓝粉和青粉普遍发射光谱窄、光效偏低和热稳定性较差,黄粉及远红光荧光粉对紫光或近紫外光的吸收较低导致发光效率不佳,单一基质白光荧光粉的红光发射不足等问题,其中发光光效和热稳定性仍然是制约各类荧光粉应用的关键因素。研究提出,可重点突破适合紫光–近紫光激发高光效和高热稳定性的宽谱蓝粉、青粉、黄绿粉、黄粉、长波红粉以及单一基质白光荧光粉的制备和应用技术,开发与现有应用产品体系相匹配的高效及连续化制备技术,由此促进全光谱 LED 的进一步发展。

关键词: 全光谱LED     高品质照明     紫光芯片     荧光粉    

Mirror system based therapy for autism spectrum disorders

CHEN Wei, ZHANG Jing, DING Jun

《医学前沿(英文)》 2008年 第2卷 第4期   页码 344-347 doi: 10.1007/s11684-008-0065-3

摘要: This paper reviews the present theories and empirical research of autisms’ cognitive research and mirror systems and introduces a new hypothesis about the causes of autism spectrum disorders (ASD): autistic mirror neuron dysfunction hypothesis. ASD subjects show obvious lack of the activation of the mirror system during the task of observation or emotional cognition. It is significant to investigate the mirror system for revealing the causes of autism and it is also helpful for developing new ways to diagnose or treat this disorder.

关键词: emotional cognition     observation     activation     spectrum     empirical research    

Investigating the raveling test for full-depth reclamation

Robert HILL, Andrew BRAHAM

《结构与土木工程前沿(英文)》 2018年 第12卷 第2期   页码 222-226 doi: 10.1007/s11709-017-0423-9

摘要: Full-Depth Reclamation (FDR) is a sustainable method of building pavement structure compared to more traditional rehabilitation methods. Traffic is generally returned to an FDR project before a surface course is applied, as water in the FDR needs time to evaporate from the structure. This should not be done too quickly or raveling occurs. Currently, there is no test to quantify the timing of return to traffic. In this study, the “Raveling test of cold mixed bituminous emulsion samples” (ASTM D7196) was used to compare asphalt emulsion and asphalt foam FDR. Asphalt emulsion samples were cured at ambient and 40 °C temperatures, while asphalt foam samples were cured at ambient temperatures. Raveling test data was collected from 0 to 48 hours of curing, however, samples were often not able to withstand fifteen minutes of testing. Therefore, the “time lasted” (the time the raveling head loses contact with the surface of the sample) was recorded. In general, the asphalt emulsion samples that were cured in the oven at 40 °C had a longer time lasted and showed higher potential for determination of return to traffic. In addition, the asphalt emulsion samples had a longer time lasted than the asphalt foam samples at ambient temperatures.

关键词: raveling     full depth reclamation    

Detection of geosmin and 2-methylisoborneol by liquid-liquid extraction-gas chromatograph mass spectrum(LLE-GCMS) and solid phase extraction-gas chromatograph mass spectrum (SPE-GCMS)

MA Xiaoyan, CHEN Beibei, LI Qingsong, ZHANG Qiaoli, GU Guofen

《环境科学与工程前沿(英文)》 2007年 第1卷 第3期   页码 286-291 doi: 10.1007/s11783-007-0048-7

摘要: Two sample preparation methods were introduced and compared in this paper to establish a simple, quick and exact analysis of geosmin and 2-methylisoborneol. LC-18 column was employed in solid phase extraction (SPE), 1.0 mL of hexane was adopted in liquid-liquid extraction (LLE), and the extracts were analyzed by gas chromatograph mass spectrum (GCMS) in selected ion mode. Mean recoveries of SPE were low for 2-methylisoborneol (2-MIB) and geosmin (GSM) with values below 50%. For LLE, the recoveries were satisfyingly above 50% for 2-MIB and 80% for GSM. Detection limits of the LLE method were as low as 1.0 ng/L for GSM and 5.0 ng/L for 2-MIB. A year-long investigation on odor chemicals of drinking water in Shanghai demonstrated that in the summer, there was a serious odor problem induced by a high concentration of 2-MIB. The highest concentration of 152.82 ng/L appeared in July in raw water, while GSM flocculation was minimal with concentrations below odor threshold.

关键词: summer     flocculation     simple     Shanghai     spectrum    

Contact fatigue life prediction of a bevel gear under spectrum loading

Pan JIA, Huaiju LIU, Caichao ZHU, Wei WU, Guocheng LU

《机械工程前沿(英文)》 2020年 第15卷 第1期   页码 123-132 doi: 10.1007/s11465-019-0556-8

摘要: Rolling contact fatigue (RCF) issues, such as pitting, might occur on bevel gears because load fluctuation induces considerable subsurface stress amplitudes. Such issues can dramatically affect the service life of associated machines. An accurate geometry model of a hypoid gear utilized in the main reducer of a heavy-duty vehicle is developed in this study with the commercial gear design software MASTA. Multiaxial stress–strain states are simulated with the finite element method, and the RCF life is predicted using the Brown–Miller–Morrow fatigue criterion. The patterns of fatigue life on the tooth surface are simulated under various loading levels, and the RCF curve is numerically generated. Moreover, a typical torque–time history on the driven axle is described, followed by the construction of program load spectrum with the rain flow method and the Goodman mean stress equation. The effects of various fatigue damage accumulation rules on fatigue life are compared and discussed in detail. Predicted results reveal that the Miner linear rule provides the most optimistic result among the three selected rules, and the Manson bilinear rule produces the most conservative result.

关键词: bevel gear     rolling contact fatigue (RCF)     multiaxial fatigue criterion     load spectrum     damage accumulation rule    

一种新的通信抗干扰技术体制:预编码跳码扩谱

姚富强,张毅

《中国工程科学》 2011年 第13卷 第10期   页码 69-75

摘要:

基于常规直扩体制的不足,笔者分析了跳码扩谱的必要性,提出和研究了一种新的预编码跳码扩谱通信抗干扰技术体制,重点讨论了预编码跳码扩谱的基本原理与自编码跳码扩谱的异同点、关键技术等,最后分析了其基本性能。该体制和性能已在实际中得到初步验证。

关键词: 通信抗干扰     直接序列扩谱     预编码跳码扩谱     自编码跳码扩谱    

Partial anammox achieved in full scale biofilm process for typical domestic wastewater treatment

《环境科学与工程前沿(英文)》 2022年 第16卷 第3期 doi: 10.1007/s11783-021-1467-6

摘要:

• A full scale biofilm process was developed for typical domestic wastewater treatment.

关键词: Full scale     Anammox     Domestic wastewater     Biofilm     Candidatus Brocadia    

Novel sensing techniques for full-scale testing of civil structures

Kaoshan DAI, Zhenhua HUANG

《结构与土木工程前沿(英文)》 2012年 第6卷 第3期   页码 240-256 doi: 10.1007/s11709-012-0172-8

摘要: Performing full-scale structural testing is an important methodology for researchers and engineers in the civil engineering industry. Full scale testing helps the researchers understand civil infrastructures’ loading scenarios, behaviors, and health conditions. It helps the engineers verify, polish, and simplify the structural design and analysis theories. To conduct a full-scale structural testing, sensors are used for data acquisitions. To help structural researchers and engineers get familiar with sensing technologies and select the most effective sensors, this study reviewed and categorized new sensing techniques for full-scale structural testing applications. The researchers of this study categorized sensors used for civil-infrastructure testing into traditional contact sensors and remote sensors based upon their application methodologies, and into cabled sensors and wireless sensors based upon their data communication strategies. The detailed descriptions of wireless sensors and remote sensing techniques and their on-site full-scale applications are presented.

关键词: sensing technique     full-scale testing     wireless sensor     remote sensing     LiDAR     laser vibrometer    

A novel light fluctuation spectrum method for in-line particle sizing

Shouxuan QIN, Xiaoshu CAI, Li MA

《能源前沿(英文)》 2012年 第6卷 第1期   页码 89-97 doi: 10.1007/s11708-012-0176-z

摘要: This paper discusses two problems in in-line particle sizing when using light fluctuation method. First, by retrieving the ratio of particle concentrations at different time, the intensity of incident light is obtained. There exists narrow error between the calculated and pre-detected value of the intensity of incident light. Secondly, by combining spectrum analysis with Gregory’s theory, a multi-sub-size zone model is proposed, with which the relationship between the distribution of turbidity and the particle size distribution (PSD) can be established, and an algorithm developed to determine the distribution of turbidity. Experiments conducted in the laboratory indicate that the measured size distribution of pulverized coal conforms well with the imaging result.

关键词: in-line measurement     particle size distribution (PSD)     incident light intensity     particle concentration     light fluctuation    

密码函数的一类递归构造方法

滕吉红,张文英,刘文芬,李世取

《中国工程科学》 2003年 第5卷 第7期   页码 47-52

摘要:

首先利用递归的方法证明了结构形式更为一般的布尔函数的Walsh谱分解式,然后利用这类布尔函数Walsh谱分解式,给出了密码学和编码学中具有重要应用价值的一些布尔函数,如弹性函数、Bent函数以及满足严格雪崩准则的布尔函数的构造方法。

关键词: Walsh谱     Walsh谱分解式     Bent函数     弹性函数     严格雪崩准则    

Measurement and analysis of tip clearance unsteady flow spectrum in axial-flow fan rotor

LIU Bo, HOU Weimin, MA Changyou, WANG Yangang, ZHOU Qiang

《能源前沿(英文)》 2008年 第2卷 第4期   页码 448-452 doi: 10.1007/s11708-008-0088-0

摘要: The dynamic pressure measurement device and test technology are described in this study. The tip clearance unsteady flow development from the inlet to the outlet of an axial-flow rotor was revealed by analyzing pressure frequency spectrum acquired from measuring the unsteady pressure field of the tip endwall. The experiment provides test basis for thoroughly understanding the tip clearance unsteady flow and building interaction models of tip clearance flow and main flow.

关键词: development     endwall     unsteady pressure     pressure measurement     experiment    

Optimizing the configuration of a clearwell by integrating pilot and full-scale tracer testing

LIU Wenjun, DU Zhipeng, JIN Junwei

《环境科学与工程前沿(英文)》 2007年 第1卷 第3期   页码 270-275 doi: 10.1007/s11783-007-0045-x

摘要: In this paper, the main factors impacting the plug flow pattern of a clearwell were investigated by integrating pilot-scale, full-scale clearwell tracer testing and computational fluid dynamics (CFD) simulation. It was found that pilot tracer testing, full-scale tracer testing and CFD simulation all demonstrated that the correlation between the ratio of / and can be approximately expressed by: / = 0.189 4ln()-0.049 4. This study confirmed that the installation of baffles within clearwells is an efficient way to optimize their configuration. In addition, the inlet velocity has a minimal contribution to the ratio of /. However, the ratio of turning channel width to channel width () significantly contributes to the ratio of/. The optimal ratio of is 0.8–1.2 for maintaining better plug flow pattern. The number of turning channels is one of the main factors that impact the ratio of /. When increasing the number of turning channels, a lower ratio of / is obtained.

基于双正交复序列的高效扩频调制方法

史小红

《中国工程科学》 2012年 第14卷 第3期   页码 108-112

摘要:

提出了一种采用双正交复序列的高效扩频调制与解调方法(DoCS)。输入数据比特流被分割为长度为M的组,每组的M比特作为输入码字,从2M-2个长度为L的DoCS序列中选择一条序列进行发送,被选中的序列以QPSK方式调制在载波上,实现扩频通信。文中还提出了一种前向相位校正(FPC)方法来解决该系统中收发两端的载波同步问题。

关键词: 调制与解调技术     高效扩频调制     前向相位校正     双正交码    

标题 作者 时间 类型 操作

Solar fuel from photo-thermal catalytic reactions with spectrum-selectivity: a review

Sanli TANG, Jie SUN, Hui HONG, Qibin LIU

期刊论文

Ultrathin microcrystalline hydrogenated Si/Ge alloyed tandem solar cells towards full solar spectrum

Yu Cao, Xinyun Zhu, Xingyu Tong, Jing Zhou, Jian Ni, Jianjun Zhang, Jinbo Pang

期刊论文

全光谱 LED 照明用荧光粉发展现状及趋势

陈晓霞,张霞 ,刘荣辉,刘元红,周裔朋,庄卫东

期刊论文

Mirror system based therapy for autism spectrum disorders

CHEN Wei, ZHANG Jing, DING Jun

期刊论文

Investigating the raveling test for full-depth reclamation

Robert HILL, Andrew BRAHAM

期刊论文

Detection of geosmin and 2-methylisoborneol by liquid-liquid extraction-gas chromatograph mass spectrum(LLE-GCMS) and solid phase extraction-gas chromatograph mass spectrum (SPE-GCMS)

MA Xiaoyan, CHEN Beibei, LI Qingsong, ZHANG Qiaoli, GU Guofen

期刊论文

Contact fatigue life prediction of a bevel gear under spectrum loading

Pan JIA, Huaiju LIU, Caichao ZHU, Wei WU, Guocheng LU

期刊论文

一种新的通信抗干扰技术体制:预编码跳码扩谱

姚富强,张毅

期刊论文

Partial anammox achieved in full scale biofilm process for typical domestic wastewater treatment

期刊论文

Novel sensing techniques for full-scale testing of civil structures

Kaoshan DAI, Zhenhua HUANG

期刊论文

A novel light fluctuation spectrum method for in-line particle sizing

Shouxuan QIN, Xiaoshu CAI, Li MA

期刊论文

密码函数的一类递归构造方法

滕吉红,张文英,刘文芬,李世取

期刊论文

Measurement and analysis of tip clearance unsteady flow spectrum in axial-flow fan rotor

LIU Bo, HOU Weimin, MA Changyou, WANG Yangang, ZHOU Qiang

期刊论文

Optimizing the configuration of a clearwell by integrating pilot and full-scale tracer testing

LIU Wenjun, DU Zhipeng, JIN Junwei

期刊论文

基于双正交复序列的高效扩频调制方法

史小红

期刊论文