Degradable Plastics Are Vulnerable to Cracks

Xuxu Yang , Jason Steck , Jiawei Yang , Yecheng Wang , Zhigang Suo

Engineering ›› 2021, Vol. 7 ›› Issue (5) : 624 -629.

PDF (1491KB)
Engineering ›› 2021, Vol. 7 ›› Issue (5) : 624 -629. DOI: 10.1016/j.eng.2021.02.009
Research
Letter

Degradable Plastics Are Vulnerable to Cracks

Author information +
History +
PDF (1491KB)

Abstract

A plastic may degrade in response to a trigger. The kinetics of degradation have long been characterized by the loss of weight and strength over time. These methods of gross characterization, however, are misleading when plastic degrades heterogeneously. Here, we study heterogeneous degradation in an extreme form: the growth of a crack under the combined action of chemistry and mechanics. An applied load opens the crack, exposes the crack front to chemical attack, and causes the crack to outrun gross degradation. We studied the crack growth in polylactic acid (PLA), a polyester in which ester bonds break by hydrolysis. We cut a crack in a PLA film using scissors, tore it using an apparatus, and recorded the crack growth using a camera through a microscope. In our testing range, the crack velocity was insensitive to load but was sensitive to humidity and pH. These findings will aid the development of degradable plastics for healthcare and sustainability.

Keywords

Degradation / Plastics / Hydrolysis / pH / Cracking

Cite this article

Download citation ▾
Xuxu Yang,Jason Steck,Jiawei Yang,Yecheng Wang,Zhigang Suo. Degradable Plastics Are Vulnerable to Cracks. Engineering, 2021, 7(5): 624-629 DOI:10.1016/j.eng.2021.02.009

登录浏览全文

4963

注册一个新账户 忘记密码

References

Funding

()

AI Summary AI Mindmap
PDF (1491KB)

1277

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/