Feb 2025, Volume 45 Issue 2
    

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    Editorial
  • Xiangang Luo, Jinghua Teng, Mingbo Pu
  • News & Highlights
  • Mark Peplow

    Recent developments suggest that the race to power electric vehicles (EV) with solid-state batteries (SSB) has gained momentum. In January 2024, Toyota Motor Corporation (Toyota City, Japan) confirmed its previously stated plans to start producing SSB EV in the 2027-2028 timeframe [1] . In May 2024, it emerged that the Chinese government plans to invest more than six billion CNY (830 million USD) in projects intended to speed up SSB development [2] . In June 2024, the automaker Nio (Shanghai, China) began supplying customers with EVs containing “semi-solid-state” batteries—a hybrid technology that could serve as a stepping stone to fully solid versions [3] . In September 2024, SAIC Motor (Shanghai, China), China’s largest automobile manufacturer, announced that it would deliver its first SSB-powered vehicles in 2025 [4] .

  • Chris Palmer

    On 9 October 2024, in a high-profile vote of confidence for the promise of using artificial intelligence (AI) in scientific discovery, the Royal Swedish Academy of Sciences awarded Demis Hassabis (co-founder and chief executive officer) and John M. Jumper (director) of Google DeepMind (London, UK) the 2024 Nobel Prize in Chemistry for their pioneering work in developing the AI-powered protein structure prediction model AlphaFold2 (AF2) [1] . Also sharing the prize was David Baker (half to Hassabis and Jumper; half to Baker), professor of biochemistry at the University of Washington (Seattle, WA, USA), for his work on computational protein design that started with the mid-1990s development of Rosetta, a since-evolving suite of software tools that model protein structures using physical principles [2] —and now also AI [3] .

  • Mitch Leslie

    In February 2024, 192 lasers at the National Ignition Facility (NIF) in Livermore, CA, USA, began pouring 2.2 MJ of energy into a gold container smaller than the tip of a person’s little finger, heating it to more than three million degrees ( Fig. 1 ) [1] , [2] , [3] , [4] . Inside the container was a tiny fuel capsule containing tritium and deuterium that imploded at more than 400 km·s−1, causing atoms to combine and releasing 5.2 MJ of energy [1] , [2] , [3] , [4] .

  • Mitch Leslie

    The Thwaites Glacier in western Antarctica ( Fig. 1 ) keeps glaciologists and climate scientists awake at night. The 120 km-wide glacier loses about 45 billion tonnes of ice each year, accounting for about 4% of global sea level rise [1] . If it melted completely, sea levels would climb 65 cm, and follow-on effects could lead to a 3 m increase [2] .

  • Research
  • Review
    Rong Lin, Jin Yao, Zhihui Wang, Che Ting Chan, Din Ping Tsai

    Meta-devices have significantly revitalized the study of nonlinear optical phenomena. At the nanoscale, the detrimental effects of phase mismatching between fundamental and harmonic waves can be substantially reduced. This review analyzes the theoretical frameworks of how plasmonic and dielectric materials induce nonlinear optical properties. Plasmonic and dielectric nonlinear meta-devices that can excite strong resonant modes for efficiency enhancement are explored. We outline different strategies designed to shape the radiation pattern in order to increase the collection capability of nonlinear signals emitted from meta-devices. In addition, we discuss how nonlinear phase manipulation in meta-devices can integrate the benefits of efficiency enhancement and radiation shaping, not only boosting the energy density of the nonlinear signal but also facilitating a wide range of applications. Finally, potential research directions within this field are discussed.

  • Review
    Hanqing Cai, Liangliang Gu, Haifeng Hu, Qiwen Zhan

    The unique property of chirality is widely used in various fields. In the past few decades, a great deal of research has been conducted on the interactions between light and matter, resulting in significant technical advancements in the precise manipulation of light field wavefronts. In this review, which focuses on current chiral optics research, we introduce the fundamental theory of chirality and highlight the latest achievements in enhancing chiral signals through artificial nano-manufacturing technology, with a particular focus on mechanisms such as light scattering and Mie resonance used to amplify chiral signals. By providing an overview of enhanced chiral signals, this review aims to provide researchers with an in-depth understanding of chiral phenomena and its versatile applications in various domains.

  • Article
    Jian Chen,Jie Zhao,Xi Shen,Dewei Mo,Cheng-Wei Qiu,Qiwen Zhan
    While spin-orbit interaction has been extensively studied, few investigations have reported on the interaction between orbital angular momenta (OAMs). In this work, we study a new type of orbit–orbit coupling between the longitudinal OAM and the transverse OAM carried by a three-dimensional (3D) spatiotemporal optical vortex (STOV) in the process of tight focusing. The 3D STOV possesses orthogonal OAMs in the x–y, t–x, and y–t planes, and is preconditioned to overcome the spatiotemporal astigmatism effect. x, y, and t are the axes in the spatiotemporal domain. The corresponding focused wavepacket is calculated by employing the Debye diffraction theory, showing that a phase singularity ring is generated by the interactions among the transverse and longitudinal vortices in the highly confined STOV. The Fourier-transform decomposition of the Debye integral is employed to analyze the mechanism of the orbit–orbit interaction. This is the first revelation of coupling between the longitudinal OAM and the transverse OAM, paving the way for potential applications in optical trapping, laser machining, nonlinear light-matter interactions, and more.
  • Article
    Hanyu Zheng,Fan Yang,Hung-I Lin,Mikhail Y. Shalaginov,Zhaoyi Li,Padraic Burns,Tian Gu,Juejun Hu
    The emergence of metalenses has impacted a wide variety of applications such as beam steering, imaging, depth sensing, and display projection. Optical distortion, an important metric among many optical design specifications, has however rarely been discussed in the context of meta-optics. Here, we present a generic approach for on-demand distortion engineering using compound metalenses. We show that the extra degrees of freedom afforded by a doublet metasurface architecture allow custom-tailored angle-dependent image height relations and hence distortion control while minimizing other monochromatic aberrations. Using this platform, we experimentally demonstrate a compound fisheye metalens with diffraction-limited performance across a wide field of view of 140° and a low barrel distortion of less than 2%, compared with up to 22% distortion in a reference metalens without compensation. The design strategy and compound metalens architecture presented herein are expected to broadly impact metasurface applications in consumer electronics, automotive and robotic sensing, medical imaging, and machine vision systems
  • Article
    Jie Yang, Jiafu Wang, Xinmin Fu, Yueting Pan, Tiejun Cui, Xuezhi Zheng

    Optical singularities are topological defects of electromagnetic fields; they include phase singularity in scalar fields, polarization singularity in vector fields, and three-dimensional (3D) singularities such as optical skyrmions. The exploitation of photonic microstructures to generate and manipulate optical singularities has attracted wide research interest in recent years, with many photonic microstructures having been devised to this end. Accompanying these designs, scattered phenomenological theories have been proposed to expound the working mechanisms behind individual designs. In this work, instead of focusing on a specific type of microstructure, we concentrate on the most common geometric features of these microstructures—namely, symmetries—and revisit the process of generating optical singularities in microstructures from a symmetry viewpoint. By systematically employing the projection operator technique in group theory, we develop a widely applicable theoretical scheme to explore optical singularities in microstructures with rosette (i.e., rotational and reflection) symmetries. Our scheme agrees well with previously reported works and further reveals that the eigenmodes of a symmetric microstructure can support multiplexed phase singularities in different components, such as out-of-plane, radial, azimuthal, and left- and right-handed circular components. Based on these phase singularities, more complicated optical singularities may be synthesized, including C points, V points, L lines, Néel- and bubble-type optical skyrmions, and optical lattices, to name a few. We demonstrate that the topological invariants associated with optical singularities are protected by the symmetries of the microstructure. Lastly, based on symmetry arguments, we formulate a so-called symmetry matching condition to clarify the excitation of a specific type of optical singularity. Our work establishes a unified theoretical framework to explore optical singularities in photonic microstructures with symmetries, shedding light on the symmetry origin of multidimensional and multiplexed optical singularities and providing a symmetry perspective for exploring many singularity-related effects in optics and photonics.

    Highlights

    Developing a unified theoretical scheme to explore multidimensional optical singularities generated by photonic microstructures with Rosette symmetries.

    Revealing various multiplexed optical singularities in different dimensions intrinsically supported by the microstructures, including phase singularities, C points, V points, L lines, Néel- and bubble-type optical skyrmions, and singularity-related optical lattices.

    Shedding light on the symmetry origins of multidimensional optical singularities.

    Unveiling the excitation condition of optical singularities, which can serve as a general principle to derive various selection rules in the process of photonic spin-orbit interaction.

  • Article
    Yinghui Guo, Yunsong Lei, Mingbo Pu, Fei Zhang, Qi Zhang, Xiaoyin Li, Runzhe Zhang, Zhibin Zhao, Rui Zhou, Yulong Fan, Xiangang Luo

    Object imaging beyond the direct line of sight is significant for applications in robotic vision, remote sensing, autonomous driving, and many other areas. Reconstruction of a non-line-of-sight (NLOS) screen is a complex inverse problem that comes with ultrafast time-resolved imager requirements and substantial computational demands to extract information from the multi-bounce scattered light. Consequently, the echo signal always suffers from serious deterioration in both intensity and shape, leading to limited resolution and image contrast. Here, we propose a concept of vectorial digitelligent optics for high-resolution NLOS imaging to cancel the wall’s scattering and refocus the light onto hidden targets for enhanced echo. In this approach, the polarization and wavefront of the laser spot are intelligently optimized via a feedback algorithm to form a near-perfect focusing pattern through a random scattering wall. By raster scanning the focusing spot across the object’s surface within the optical-memory-effect range of the wall, we obtain nearly diffraction-limited NLOS imaging with an enhanced signal-to-noise ratio. Our experimental results demonstrate a resolution of 0.40 mm at a distance of 0.35 m, reaching the diffraction limit of the system. Furthermore, we demonstrate that the proposed method is feasible for various complex NLOS scenarios. Our methods may open an avenue for active imaging, communication, and laser wireless power transfer.

  • Article
    Dong Zhao, Hongkun Lian, Xueliang Kang, Kun Huang

    Optical data storage (ODS) is a low-cost and high-durability counterpart of traditional electronic or magnetic storage. As a means of enhancing ODS capacity, the multiple recording layer (MRL) method is more promising than other approaches such as reducing the recording volume and multiplexing technology. However, the architecture of current MRLs is identical to that of recording data into physical layers with rigid space, which leads to either severe interlayer crosstalk or finite recording layers constrained by the short working distances of the objectives. Here, we propose the concept of hybrid-layer ODS, which can record optical information into a physical layer and multiple virtual layers by using high-orthogonality random meta-channels. In the virtual layer, 32 images are experimentally reconstructed through holography, where their holographic phases are encoded into 16 printed images and complementary images in the physical layer, yielding a capacity of 2.5 Tbit·cm−3. A higher capacity is achievable with more virtual layers, suggesting hybrid-layer ODS as a possible candidate for next-generation ODS.

  • Article
    Yu Zhao, Huijiao Wang, Zile Li, Tian Huang, Chao Yang, Ying Qiu, Yuhan Gong, Zhou Zhou, Congling Liang, Lei Yu, Jin Tao, Shaohua Yu, Guoxing Zheng

    Advancements in mode-division multiplexing (MDM) techniques, aimed at surpassing the Shannon limit and augmenting transmission capacity, have garnered significant attention in optical fiber communication, propelling the demand for high-quality multiplexers and demultiplexers. However, the criteria for ideal-mode multiplexers/demultiplexers, such as performance, scalability, compatibility, and ultra-compactness, have only partially been achieved using conventional bulky devices (e.g., waveguides, gratings, and free space optics)—an issue that will substantially restrict the application of MDM techniques. Here, we present a neuro-meta-router (NMR) optimized through deep learning that achieves spatial multi-mode division and supports multi-channel communication, potentially offering scalability, compatibility, and ultra-compactness. An MDM communication system based on an NMR is theoretically designed and experimentally demonstrated to enable simultaneous and independent multi-dataset transmission, showcasing a capacity of up to 100 gigabits per second (Gbps) and a symbol error rate down to the order of 10-4, all achieved without any compensation technologies or correlation devices. Our work presents a paradigm that merges metasurfaces, fiber communications, and deep learning, with potential applications in intelligent metasurface-aided optical interconnection, as well as all-optical pattern recognition and classification.

  • Article
    Zebin Huang,Peipei Wang,Jiafu Chen,Wenjie Xiong,Huapeng Ye,Xinxing Zhou,Ze Dong,Dianyuan Fan,Shuqing Chen
    Optical orbital angular momentum (OAM) mode multiplexing has emerged as a promising technique for boosting communication capacity. However, most existing studies have concentrated on channel (de)multiplexing, overlooking the critical aspect of channel routing. This challenge involves the reallocation of multiplexed OAM modes across both spatial and temporal domains—a vital step for developing versatile communication networks. To address this gap, we introduce a novel approach based on the time evolution of OAM modes, utilizing the orthogonal conversion and diffractive modulation capabilities of unitary transformations. This approach facilitates high-dimensional orthogonal transformations of OAM mode vectors, altering both the propagation direction and the spatial location. Using Fresnel diffraction matrices as unitary operators, it manipulates the spatial locations of light beams during transmission, breaking the propagation invariance and enabling temporal evolution. As a demonstration, we have experimentally implemented the deep routing of four OAM modes within two distinct time sequences. Achieving an average diffraction efficiency above 78.31%, we have successfully deep-routed 4.69 Tbit·s−1 quadrature phase-shift keying (QPSK) signals carried by four multiplexed OAM channels, with a bit error rate below 10–6. These results underscore the efficacy of our routing strategy and its promising prospects for practical applications.
  • Review
    Jiarui Xie,Lijun Sun,Yaoyao Fiona Zhao
    Machine learning (ML) has recently enabled many modeling tasks in design, manufacturing, and condition monitoring due to its unparalleled learning ability using existing data. Data have become the limiting factor when implementing ML in industry. However, there is no systematic investigation on how data quality can be assessed and improved for ML-based design and manufacturing. The aim of this survey is to uncover the data challenges in this domain and review the techniques used to resolve them. To establish the background for the subsequent analysis, crucial data terminologies in ML-based modeling are reviewed and categorized into data acquisition, management, analysis, and utilization. Thereafter, the concepts and frameworks established to evaluate data quality and imbalance, including data quality assessment, data readiness, information quality, data biases, fairness, and diversity, are further investigated. The root causes and types of data challenges, including human factors, complex systems, complicated relationships, lack of data quality, data heterogeneity, data imbalance, and data scarcity, are identified and summarized. Methods to improve data quality and mitigate data imbalance and their applications in this domain are reviewed. This literature review focuses on two promising methods: data augmentation and active learning. The strengths, limitations, and applicability of the surveyed techniques are illustrated. The trends of data augmentation and active learning are discussed with respect to their applications, data types, and approaches. Based on this discussion, future directions for data quality improvement and data imbalance mitigation in this domain are identified.
  • Article
    Xunjia Li, Jianjun Luo, Jianfeng Ping, Zhong Lin Wang

    Efficient utilization of electrostatic charges is paramount for numerous applications, from printing to kinetic energy harvesting. However, existing technologies predominantly focus on the static qualities of these charges, neglecting their dynamic capabilities as carriers for energy conversion. Herein, we report a paradigm-shifting strategy that orchestrates the swift transit of surface charges, generated through contact electrification, via a freely moving droplet. This technique ingeniously creates a bespoke charged surface which, in tandem with a droplet acting as a transfer medium to the ground, facilitates targeted charge displacement and amplifies electrical energy collection. The spontaneously generated electric field between the charged surface and needle tip, along with the enhanced water ionization under the electric field, proves pivotal in facilitating controlled charge transfer. By coupling the effects of charge self-transfer, contact electrification, and electrostatic induction, a dual-electrode droplet-driven-tribo-electric nanogenerator (DD-TENG) is designed to harvest the water-related energy, exhibiting a two-order-of-magnitude improvement in electrical output compared to traditional single-electrode systems. Our strategy establishes a fundamental groundwork for efficient water drop energy acquisition, offering deep insights and substantial utility for future interdisciplinary research and applications in energy science.

  • Article
    Pan Wang, Tao Cheng, Zhuangxin Wei, Lu Liu, Yue Wang, Xiaohua Tian, Jianming Pan
    Expanding the specific surface area of substrates and carrying out precise surface engineering of imprinted nanocavities are crucial methods for enhancing the identification efficiency of molecularly imprinted polymers (MIPs). To implement this synergistic strategy, bioinspired surface engineering was used to incorporate dual covalent receptors via precise post-imprinting modifications (PIMs) onto mesoporous silica nanosheets. The prepared sorbents (denoted as "D-PMIPs") were utilized to improve the specific identification of adenosine 5′-monophosphate (AMP). Significantly, the mesoporous silica nanosheets possess a high surface area of approximately 498.73 m2∙g-1, which facilitates the formation of abundant specific recognition sites in the D-PMIPs. The dual covalent receptors are valuable for establishing the spatial orientation and arrangement of AMP through multiple cooperative interactions. PIMs enable precise site-specific functionalization within the imprinted cavities, leading to the tailor-made formation of complementary binding sites. The maximum number of high-affinity binding sites (Nmax) of the D-PMIPs is 39.99 μmol∙g-1, which is significantly higher than that of imprinted sorbents with a single receptor (i.e., S-BMIPs or S-PMIPs). The kinetic data of the D-PMIPs can be effectively described by a pseudo-second-order model, indicating that the main binding mechanism involves synergistic chemisorption from boronate affinity and the pyrimidine base. This study suggests that using dual covalent receptors and PIMs is a reliable approach for creating imprinted sorbents with high selectivity, allowing for the controlled engineering of imprinted sites.
  • Article
    Xuyuan Hou,Yuchen Shang,Luyao Chen,Bingtao Feng,Yuanlong Zhao,Xinyu Zhao,Kuo Hu,Qiang Tao,Pinwen Zhu,Zhihui Li,Ran Liu,Zhaodong Liu,Mingguang Yao,Bingbing Liu
    Ultrahigh pressure generation at high temperatures is technologically challenging for large sample volumes. In this study, we successfully generated pressures of 37.3–40.4 GPa at 1900–2100 K in a Walker-type large-volume press (LVP). Expansion of the pressure range at high temperatures was achieved by adapting newly designed ZK01F tungsten carbide (WC) anvils with tapered surfaces and using cell assemblies with an ∼1 mm3 sample volume and hard materials, as well as by applying certain adjustments to the apparatus. The pressure efficiencies of the different types of WC anvils and cell assemblies were also studied. Using the above-mentioned techniques, we successfully synthesized and characterized bulk samples of nearly pure sp3-hybridized ultrahard amorphous carbon, core–shell nanocrystals with high Néel temperatures, as well as large-sized single crystals of lower-mantle minerals. The developed LVP techniques presented here could enable the exploration of the chemical and physical properties of novel materials and Earth’s interior.
  • Article
    Hang Hua,Kouji Yasuda,Yutaro Norikawa,Toshiyuki Nohira
    Owing to the worldwide trend towards carbon neutrality, the number of Dy-containing heat-resistant Nd magnets used for wind power generation and electric vehicles is expected to increase exponentially. However, rare earth (RE) elements (especially Dy) are unevenly distributed globally. Therefore, an environmental-friendly recycling method for RE elements with a highly precise separation of Dy and Nd from end-of-life magnets is required to realize a carbon-neutral society. As an alternative to traditional hydrometallurgical RE separation techniques with a high environmental load, we designed a novel, highly efficient, and precise process for the separation and recycling of RE elements from magnet scrap. As a result, over 90% of the RE elements were efficiently extracted from the magnets using MgCl2 and evaporation loss was selectively suppressed by adding CaF2. The extracted RE elements were electrolytically separated based on the formation potential differences of the RE alloys. Nd and Dy metals with purities greater than 90% were estimated to be recovered at rates of 96% and 91%, respectively. Almost all the RE in the scraps could be separated and recycled as RE metals, and the byproducts were easily removed. Thus, this process is expected to be used on an industrial scale to realize a carbon-neutral society.
  • Article
    Jose Angel Leiva Vilaplana, Guangya Yang, Emmanuel Ackom, Roberto Monaco, Yusheng Xue

    Assessing the benefits and costs of digitalization in the energy industry is a complex issue. Traditional cost-benefit analysis (CBA) might encounter problems in addressing uncertainties, dynamic stakeholder interactions, and feedback loops arising out of the evolving nature of digitalization. This paper introduces a methodological framework to help address the intricate inter connections between digital applications and business models in the energy industry. The proposed framework leverages system dynamics to achieve two primary objectives. It investigates how digitalization generally influences the value proposition, value capture, and value creation dimensions of business models. It also quantifies the financial and social impacts of digitalization from a dynamic perspective. The proposed dynamic CBA allows for a more precise quantification of the benefits and costs, associated with evidence-based decision-making. Findings from an illustrative case study challenge the static assumptions of conventional methods. These methods often presume continuous operation, neglecting reinvestment and operational feedback loops, and resulting in negative net present values. Conversely, the outcomes of the proposed method indicate positive net present values when accounting for factors such as reinvestment rates and the willingness to invest in digitalization projects. The principles outlined in this paper can enable a more accurate assessment of digitalization projects, thus catalyzing the development of new CBA applications and guidelines for digitalization.

  • Article
    Xiaoguang Wu,Zhongwei Huang,Tengda Long,Gensheng Li,Shouceng Tian,Haizhu Wang,Ruiyue Yang,Kun Li,Zikang Wang
    Medium-high maturity continental shale oil is one of the hydrocarbon resources with the most potential for successful development in China. Nevertheless, the unique geological conditions of a multi-lithologic superposition shield the vertical propagation of hydraulic fractures and limit the longitudinal reconstruction in reservoirs, posing a great challenge for large-scale volumetric fracturing. Radial wellbore cross-layer fracturing, which transforms the interaction between the hydraulic fractures and lithologic interface into longitudinal multilayer competitive initiation, could provide a potential solution for this engineering challenge. To determine the longitudinal propagation behaviors of fractures guided by radial wellbores, true triaxial fracturing experiments were performed on multilayer shale-sandstone samples, with a focus on the injection pressure response, fracture morphology, and cross-layer pattern. The effects of the radial borehole length L, vertical stress difference Kv, injection rate Q, and viscosity ν of the fracturing fluid were analyzed. The results indicate that radial wellbores can greatly facilitate fracture initiation and cross-layer propagation. Unlike conventional hydraulic fracturing, there are two distinct fracture propagation patterns in radial wellbore fracturing: cross-layering and skip-layering. The fracture height guided by a radial wellbore is positively correlated with Kv, Q, and ν. Increasing these parameters causes a shift in the fracture initiation from a single root to an asynchronous root/toe end and can improve the cross-layer propagation capacity. Critical parameter thresholds exist for fracture propagation through and across interlayers under the guidance of radial boreholes. A parameter combination of critical cross-layering/skip-layering or alternating displacement/viscosity is recommended to simultaneously improve the fracture height and degree of lateral activation. The degree of correlation of different parameters with the vertical fracture height can be written as L > Q/ν > Kv. Increasing the radial wellbore length can effectively facilitate fracture cross-/skip-layer propagation and reduce the critical threshold of injection parameters, which is conducive to maximizing the stimulated reservoir volume.
  • Article
    Jiajia Wang,Huabo Duan,Kunyang Chen,Isabelle Y.S. Chan,Fan Xue,Ning Zhang,Xiangsheng Chen,Jian Zuo
    Surface space constraints and the associated massive carbon emissions present significant challenges to the sustainable development of megacities. Urban underground space (UUS) construction is expected to provide a practical approach for alleviating the space constraints of surface construction. However, in-depth examinations of the overall UUS system to reveal carbon emissions in the complex matrix are lacking. This study demonstrates the vital role of UUS development in achieving carbon neutrality using a streamlined life-cycle assessment method. Carbon emissions and the mitigation potential of building underground spaces, metro systems, and geothermal energy sources are analyzed. The construction of underground spaces in buildings is the largest carbon emitter within the entire UUS system, releasing a considerable 547.2 Mt in 2020. However, geothermal carbon sequestration, a significant element of the UUS system, provided an unexpected and impressive contribution, sequestering 170 Mt of carbon in 2020. This study shows that UUS addresses the lack of space for urban development and is a low-carbon method of urban construction. Therefore, developing low-carbon building technologies and improving the UUS development model is imperative to achieving better low-carbon balance. This helps to promote more coordinated and sustainable urban development.
  • Article
    Hong-Tao Shi,Xiao-Chi Feng,Zi-Jie Xiao,Chen-Yi Jiang,Wen-Qian Wang,Qin-Yao Zeng,Bo-Wen Yang,Qi-Shi Si,Qing-Lian Wu,Nan-Qi Ren
    Constructed wetlands (CWs) are a promising method to treat effluent from wastewater treatment plants (WWTPs). However, low carbon/nitrogen (C/N) ratios of the influent inhibit denitrification in CWs, resulting in poor nitrogen removal efficiency. Herein, we compared traditional (control), biochar (BC), and β-cyclodextrin-functionalized biochar (BC@β-CD) CW systems to investigate nitrogen removal from influent with low C/N ratios, and the mechanisms that enhance this process. The highest nitrogen removal rates were observed in the BC@β-CD group, with rates 45.89% and 42.48% higher than those of the control, accompanied by a 70.57% and 85.45% decrease in nitrous oxide release, when the C/N ratio decreased from 4 to 2, respectively. Metagenomic and enzymatic analyses indicated that BC@β-CD enhances nitrogen removal by coordinately promoting carbon metabolism and increasing denitrification enzyme activities, without affecting microbial species diversity in CWs. Structural equation modeling confirmed that the foremost advantages of BC@β-CD were effective electron generation and transportation resulting from increased activities of nicotinamide adenine dinucleotide (NADH) dehydrogenase and the electron transfer system (ETS), thereby strategically reallocating more carbon metabolic flow to support denitrification. Our results show that the application of BC@β-CD in CWs to optimize the reallocation of electrons from carbon metabolism is a feasible strategy to enhance denitrification under low C/N conditions.
  • Article
    Yijiao Chang,Xuan Wang,Bolin Zhao,Anjie Li,Yiru Wu,Bohua Wen,Bing Li,Xiao-yan Li,Lin Lin
    The rapidly growing demand for lithium iron phosphate (LiFePO4) as the cathode material of lithium-ion batteries (LIBs) has aggravated the scarcity of phosphorus (P) reserves on Earth. This study introduces an environmentally friendly and economical method of P recovery from municipal wastewater, providing the P source for LiFePO4 cathodes. The novel approach utilizes the sludge of Fe-coagulant-based chemical P removal (CPR) in wastewater treatment. After a sintering treatment with acid washing, the CPR sludge, enriched with P and Fe, transforms into purified P–Fe oxides (Fe2.1P1.0O5.6). These oxides can substitute up to 35% of the FePO4 reagent as precursor, producing a carbon-coated LiFePO4 (LiFePO4/C) cathode with a specific discharge capacity of 114.9 mA·h·g−1 at 170 mA·g−1, and cycle stability of 99.2% after 100 cycles. The enhanced cycle performance of the as-prepared LiFePO4/C cathode may be attributed to the incorporations of impurities (such as Ca2+ and Na+) from sludge, with improved stability of crystal structure. Unlike conventional P-fertilizers, this P recovery technology converts 100% of P in CPR sludge into the production of value-added LiFePO4/C cathodes. The recovered P from municipal wastewater can meet up to 35% of the P demand in the Chinese LIBs industry, offering a cost-effective solution for addressing the pressing challenges of P scarcity.
  • Article
    Zhenchao Zhou,Zejun Lin,Xinyi Shuai,Xiaoliang Ba,Chioma Achi,Mark A. Holmes,Tong Xu,Yingru Lu,Yonghong Xiao,Jianming Xu,Baojing Gu,Hong Chen
    The One Health concept acknowledges the importance of multiple dimensions in controlling antimicrobial resistance (AMR). However, our understanding of how anthropological, socioeconomic, and environmental factors drive AMR at a national level remains limited. To explore associations between potential contributing factors and AMR, this study analyzed an extensive database comprising 13 major antibiotic-resistant bacteria and over 30 predictors (e.g., air pollution, antibiotic usage, economy, husbandry, public services, health services, education, diet, climate, and population) from 2014 to 2020 across China. The multivariate analysis results indicate that fine particulate matter with a diameter of 2.5 μm or less (PM2.5) is associated with AMR, accounting for 12% of the variation, followed by residents’ income (10.3%) and antibiotic usage density (5.1%). A reduction in PM2.5 of 1 µg·m−3 is linked to a 0.17% decrease in aggregate antibiotic resistance (p < 0.001, R2 = 0.74). Under different scenarios of China’s PM2.5 air-quality projections, we further estimated the premature death toll and economic burden derived from PM2.5-related antibiotic resistance in China until 2060. PM2.5-derived AMR is estimated to cause approximately 27 000 (95% confidence interval (CI): 6468–48 830) premature deaths and about 0.51 (0.12–0.92) million years of life lost annually in China, equivalent to an annual welfare loss of 8.4 (2.0–15.0) billion USD. Implementing the “Ambitious Pollution 1.5 ℃ Goals” scenario to reduce PM2.5 concentrations could prevent roughly 14 000 (3324–26 320) premature deaths—with a potential monetary value of 9.8 (2.2–17.6) billion USD—from AMR by 2060. These results suggest that reducing air pollution may offer co-benefits in the health and economic sectors by mitigating AMR.
  • Review
    Jinhui Wu,Ning Gu
    The trajectory of human history is characterized by a persistent battle against disease. Over time, the field of medicine has transitioned from enigmatic witch doctors and herbal remedies to a sophisticated realm of contemporary medicine that includes fundamental medical and health sciences, clinical medicine, and public health. Nevertheless, the present phase of medical advancement encounters significant challenges, particularly in effectively translating basic research findings into practical applications in clinical and public health settings. Scientists increasingly collaborate with clinical experts to overcome these obstacles and address specific clinical issues by delving deeper into fundamental mechanisms. This collaborative effort has created a new interdisciplinary field: engineering medicine (EngMed), which focuses on addressing clinical and public health needs by integrating various scientific disciplines. This article discusses the definition, key tasks, significance, educational implications, and future trends in EngMed.
  • Review
    Song-Shun Lin,Shui-Long Shen,Annan Zhou,Xiang-Sheng Chen
    Construction engineering and management (CEM) has become increasingly complicated with the increasing size of engineering projects under different construction environments, motivating the digital transformation of CEM. To contribute to a better understanding of the state of the art of smart techniques for engineering projects, this paper provides a comprehensive review of multi-criteria decision-making (MCDM) techniques, intelligent techniques, and their applications in CEM. First, a comprehensive framework detailing smart technologies for construction projects is developed. Next, the characteristics of CEM are summarized. A bibliometric review is then conducted to investigate the keywords, journals, and clusters related to the application of smart techniques in CEM during 2000–2022. Recent advancements in intelligent techniques are also discussed under the following six topics: ① big data technology; ② computer vision; ③ speech recognition; ④natural language processing; ⑤ machine learning; and ⑥ knowledge representation, understanding, and reasoning. The applications of smart techniques are then illustrated via underground space exploitation. Finally, future research directions for the sustainable development of smart construction are highlighted.
  • Corrigendum
  • Corrigendum
    Ruogu Qi, Shanshan Wang, Jiayi Yu, Tianming Lu, Zhiqiang Bi, Weibo Liu, Yuanyuan Guo, Yong Bian, Jianliang Shen, Xuesong Zhang, Wenhao Hu