Water Harvesting with Zeolite, MOF, COF, and HOF Adsorbents

Bo Zhang; Zhi Wang; Freek Kapteijn; Xinlei Liu

doi:10.1016/j.eng.2025.10.011

Engineering ›› DOI: 10.1016/j.eng.2025.10.011

review-article

Water Harvesting with Zeolite, MOF, COF, and HOF Adsorbents

Bo Zhang ^a^,^b
, Zhi Wang ^a^,^b
, Freek Kapteijn ^c
, Xinlei Liu ^a^,^b^,^*

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Abstract

To deal with global water shortage, water vapor in the air is regarded as a freshwater source that cannot be ignored, especially in water-scarce regions. Adsorption-based atmospheric water harvesting (AAWH) is a promising option that utilizes the interaction between the internal structure of the adsorbent material and water molecules to accumulate water. Novel water harvesting adsorbents such as zeolites, metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) have given new perspectives to fundamentally improve the effectiveness of AAWH, benefiting from their steep S-shaped isotherms. Based on the selection criteria derived from the principle of AAWH, 5 zeolites, 20 MOFs, 6 COFs, and one HOF are identified as potential candidates. From the analysis of the water adsorption mechanisms of these four types of materials and summarizing the latest progress in AAWH devices, the next-generation AAWH technology should focus on the scale-up of well-designed adsorbent components and their integration into efficient system devices to promote the practical application of AAWH.

Keywords

Water adsorption / Water harvesting / Zeolite / Metal–organic frameworks / Covalent organic frameworks / Hydrogen-bonded organic frameworks

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Bo Zhang, Zhi Wang, Freek Kapteijn, Xinlei Liu. Water Harvesting with Zeolite, MOF, COF, and HOF Adsorbents. Engineering DOI:10.1016/j.eng.2025.10.011

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References

Publishing order | Descend order by publishing year | Descend order by cited within

[1]	Meng Y, Dang Y, Suib SL.Materials and devices for atmospheric water harvesting.Cell Rep Phys Sci 2022; 3(7):100976.

[2]	Tu Y, Wang R, Zhang Y, Wang J.Progress and expectation of atmospheric water harvesting.Joule 2018; 2(8):1452-1475.

[3]	Zhang S, Fu J, Xing G, Zhu W, Ben T.Recent advances in porous adsorbent assisted atmospheric water harvesting: a review of adsorbent materials.Chem Synth 2023; 3(2):10.

[4]	Fathieh F, Kalmutzki MJ, Kapustin EA, Waller PJ, Yang J, Yaghi OM.Practical water production from desert air.Sci Adv 2018; 4(6):eaat3198.

[5]	Hanikel N, Prevot MS, Fathieh F, Kapustin EA, Lyu H, Wang H, et al.Rapid cycling and exceptional yield in a metal-organic framework water harvester.ACS Cent Sci 2019; 5(10):1699-1706.

[6]	Kim H, Rao SR, Kapustin EA, Zhao L, Yang S, Yaghi OM, et al.Adsorption-based atmospheric water harvesting device for arid climates.Nat Commun 2018; 9(1):1191.

[7]	Kim H, Yang S, Rao SR, Narayanan S, Kapustin EA, Furukawa H, et al.Water harvesting from air with metal-organic frameworks powered by natural sunlight.Science 2017; 356(6336):430-434.

[8]	Sun C, Sheng D, Wang B, Feng X.Covalent organic frameworks for extracting water from air.Angew Chem Int Ed 2023; 62(25):e202303378.

[9]	Zhang B, Zhu Z, Wang X, Liu X, Kapteijn F.Water adsorption in MOFs: structures and applications.Adv Funct Mater 2024; 34(43):2304788.

[10]	Han B, Ng MS, Chakraborty A.Optimizing metal-organic frameworks for adsorption-based atmospheric water harvesting: a systematic evaluation of pristine and modified MOFs for enhanced performance in diverse climates.Chem Eng J 2025; 521:166607.

[11]	Liu X, Wang X, Kapteijn F.Water and metal-organic frameworks: from interaction toward utilization.Chem Rev 2020; 120(16):8303-8377.

[12]	Kalmutzki MJ, Diercks CS, Yaghi OM.Metal-organic frameworks for water harvesting from air.Adv Mater 2018; 30(37):1704304.

[13]	Zhou XY, Lu HY, Zhao F, Yu GH.Atmospheric water harvesting: a review of material and structural designs.ACS Mater Lett 2020; 2(7):671-684.

[14]	LaPotin A, Zhong Y, Zhang LA, Zhao L, Leroy A, Kim H, et al.Dual-stage atmospheric water harvesting device for scalable solar-driven water production.Joule 2021; 5(1):166-182.

[15]	Lassitter T, Hanikel N, Coyle DJ, Hossain MI, Lipinski B, O M’Brien, et al.Mass transfer in atmospheric water harvesting systems.Chem Eng Sci 2024; 285:119430.

[16]	Hanikel N, Pei XK, Chheda S, Lyu H, Jeong W, Sauer J, et al.Evolution of water structures in metal-organic frameworks for improved atmospheric water harvesting.Science 2021; 374(6566):454-459.

[17]	Hanikel N, Kurandina D, Chheda S, Zheng Z, Rong Z, Neumann SE, et al.MOF linker extension strategy for enhanced atmospheric water harvesting.ACS Cent Sci 2023; 9(3):551-557.

[18]	Sun C, Zhu Y, Shao P, Chen L, Huang X, Zhao S, et al.2D covalent organic framework for water harvesting with fast kinetics and low regeneration temperature.Angew Chem Int Ed 2023; 62(11):e202217103.

[19]	Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, et al.Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report).Pure Appl Chem 2015; 87(9–10):1051-1069.

[20]	van MA der Veen, Canossa S, Wahiduzzaman M, Nenert G, Frohlich D, Rega D, et al.Confined water cluster formation in water harvesting by metal-organic frameworks: CAU-10-H versus CAU-10–CH3.Adv Mater 2024; 36(12):2210050.

[21]	Zhang S, Fu JR, Xing GL, Zhu WD, Ben T.Porous materials for atmospheric water harvesting.ChemistryOpen 2023; 12(5):e202300046.

[22]	Ejeian M, Wang RZ.Adsorption-based atmospheric water harvesting.Joule 2021; 5(7):1678-1703.

[23]

Herzog TH, Jaenchen J, Kontogeorgopoulos EM, Lutz W.Steamed zeolites for heat pump applications and solar driven thermal adsorption storage.In: Häberle A, editor. Proceedings of the 2nd International Conference on Solar Heating and Cooling for Buildings and Industry (SHC); 2013 Sep 23–25; Freiburg, Germany. Red Hook: Curran Associates, Inc.; 2013. p. 380–3.

[24]	Tashiro Y, Kubo M, Katsumi Y, Meguro T, Komeya K.Assessment of adsorption-desorption characteristics of adsorbents for adsorptive desiccant cooling system.J Mater Sci 2004; 39(4):1315-1319.

[25]	Tatlier M, Munz G, Henninger SK.Relation of water adsorption capacities of zeolites with their structural properties.Microporous Mesoporous Mater 2018; 264:70-75.

[26]	Abd SN Elwadood, Dum LFée, Al YWahedi, Al AAlili, Karanikolos GN.Aluminophosphate-based adsorbents for atmospheric water generation.J Water Process Eng 2022; 49:103099.

[27]	Russina M, Günther G, Grzimek V, Schlegel MC, Veziri CM, Karanikolos GN, et al.Nanoscale dynamics and transport in highly ordered low-dimensional water.J Phys Chem Lett 2019; 10(20):6339-6344.

[28]	Schlegel MC, Grzimek V, Guenther G, Svetogorov R, Veziri CM, Kapsi M, et al.Explaining water adsorption in one-dimensional channels in AlPO₄–5 on molecular scale.Microporous Mesoporous Mater 2020; 304:109201.

[29]	Nie C, Yan N, Liao C, Ma C, Liu X, Wang J, et al.Unraveling a stable 16-ring aluminophosphate DNL-11 through three-dimensional electron diffraction for atmospheric water harvesting.J Am Chem Soc 2024; 146(15):10257-10262.

[30]	Risti Ać, Logar NZ, Henninger SK, Kaucic V.The performance of small-pore microporous aluminophosphates in low-temperature solar energy storage: the structure-property relationship.Adv Funct Mater 2012; 22(9):1952-1957.

[31]	Krajnc A, Varlec J, Mazaj M, Ristic A, Logar NZ, Mali G.Superior performance of microporous aluminophosphate with LTA topology in solar-energy storage and heat reallocation.Adv Energy Mater 2017; 7(11):1601815.

[32]	LaPotin A, Kim H, Rao SR, Wang EN.Adsorption-based atmospheric water harvesting: impact of material and component properties on system-level performance.Acc Chem Res 2019; 52(6):1588-1597.

[33]	Myat A, Kim NChoon, Thu K, Kim YD.Experimental investigation on the optimal performance of Zeolite-water adsorption chiller.Appl Energy 2013; 102:582-590.

[34]	de MF Lange, Verouden KJFM, Vlugt TJH, Gascon J, Kapteijn F.Adsorption-driven heat pumps: the potential of metal-organic frameworks.Chem Rev 2015; 115(22):12205-12250.

[35]	Oppenheim JJ, Ho CH, Alezi D, Andrews JL, Chen TY, Dinakar B, et al.Cooperative interactions with water drive hysteresis in a hydrophilic metal-organic framework.Chem Mater 2024; 36(7):3395-3404.

[36]	Hanikel N, Prevot MS, Yaghi OM.MOF water harvesters.Nat Nanotechnol 2020; 15(5):348-355.

[37]	Alvarez E, Guillou N, Martineau C, Bueken B, Van Bde Voorde, Le CGuillouzer, et al.The structure of the aluminum fumarate metal-organic framework A520.Angew Chem Int Ed 2015; 54(12):3664-3668.

[38]	Jeremias F, Fröhlich D, Janiak C, Henninger SK.Advancement of sorption-based heat transformation by a metal coating of highly-stable, hydrophilic aluminium fumarate MOF.RSC Adv 2014; 4(46):24073-24082.

[39]	Lenzen D, Zhao J, Ernst SJ, Wahiduzzaman M, Ken AInge, Fröhlich D, et al.A metal-organic framework for efficient water-based ultra-low-temperature-driven cooling.Nat Commun 2019; 10(1):3025.

[40]	Furukawa H, Gandara F, Zhang YB, Jiang J, Queen WL, Hudson MR, et al.Water adsorption in porous metal-organic frameworks and related materials.J Am Chem Soc 2014; 136(11):4369-4381.

[41]	Cho KH, Mileo PGM, Lee JS, Lee UH, Park J, Cho SJ, et al.Defective Zr-fumarate MOFs enable high-efficiency adsorption heat allocations.ACS Appl Mater Interfaces 2021; 13(1):1723-1734.

[42]	Lee JS, Yoon JW, Mileo PGM, Cho KH, Park J, Kim K, et al.Porous metal-organic framework CUK-1 for adsorption heat allocation toward green applications of natural refrigerant water.ACS Appl Mater Interfaces 2019; 11(29):25778-25789.

[43]	Alezi D, Oppenheim JJ, Sarver PJ, Iliescu A, Dinakar B, Dinca M.Tunable low-relative humidity and high-capacity water adsorption in a bibenzotriazole metal-organic framework.J Am Chem Soc 2023; 145(46):25233-25241.

[44]	Wright AM, Rieth AJ, Yang S, Wang EN, Dinca M.Precise control of pore hydrophilicity enabled by post-synthetic cation exchange in metal-organic frameworks.Chem Sci 2018; 9(15):3856-3859.

[45]	Rieth AJ, Wright AM, Skorupskii G, Mancuso JL, Hendon CH, Dinca M.Record-setting sorbents for reversible water uptake by systematic anion exchanges in metal-organic frameworks.J Am Chem Soc 2019; 141(35):13858-13866.

[46]	Rieth AJ, Yang S, Wang EN, Dinca M.Record atmospheric fresh water capture and heat transfer with a material operating at the water uptake reversibility limit.ACS Cent Sci 2017; 3(6):668-672.

[47]	Bagi S, Wright AM, Oppenheim J, Dinca M, Roman-Leshkov Y.Accelerated synthesis of a Ni₂Cl₂(BTDD) metal-organic framework in a continuous flow reactor for atmospheric water capture.ACS Sustain Chem Eng 2021; 9(11):3996-4003.

[48]	Wang S, Lee JS, Wahiduzzaman M, Park J, Muschi M, Martineau-Corcos C, et al.A robust large-pore zirconium carboxylate metal-organic framework for energy-efficient water-sorption-driven refrigeration.Nat Energy 2018; 3(11):985-993.

[49]	Li B, Lu FF, Gu XW, Shao K, Wu E, Qian G.Immobilization of Lewis basic nitrogen sites into a chemically stable metal-organic framework for benchmark water-sorption-driven heat allocations.Adv Sci 2022; 9(11):e2105556.

[50]	Canivet J, Bonnefoy J, Daniel C, Legrand A, Coasne B, Farrusseng D.Structure-property relationships of water adsorption in metal-organic frameworks.New J Chem 2014; 38(7):3102-3111.

[51]	Alawadhi AH, Chheda S, Stroscio GD, Rong ZC, Kurandina D, Nguyen HL, et al.Harvesting water from air with high-capacity, stable furan-based metal-organic frameworks.J Am Chem Soc 2024; 146(3):2160-2166.

[52]	Reinsch H, van MAder Veen, Gil B, Marszalek B, Verbiest T, de DVos, et al.Structures, sorption characteristics, and nonlinear optical properties of a new series of highly stable aluminum MOFs.Chem Mater 2013; 25(1):17-26.

[53]	Matemb TJ Ma Ntep, Wahiduzzaman M, Laurenz E, Cornu I, Mouchaham G, Dovgaliuk I, et al.When polymorphism in metal-organic frameworks enables water sorption profile tunability for enhancing heat allocation and water harvesting performance.Adv Mater 2024; 36(12):2211302.

[54]	Cadiau A, Lee JS, Damasceno DBorges, Fabry P, Devic T, Wharmby MT, et al.Design of hydrophilic metal organic framework water adsorbents for heat reallocation.Adv Mater 2015; 27(32):4775-4780.

[55]	Cho KH, Borges DD, Lee UH, Lee JS, Yoon JW, Cho SJ, et al.Rational design of a robust aluminum metal-organic framework for multi-purpose water-sorption-driven heat allocations.Nat Commun 2020; 11(1):5112.

[56]	Oppenheim JJ, Dinca M.Isoreticular curves: a theory of capillary condensation to model water sorption within microporous sorbents.J Am Chem Soc 2024; 146(30):20615-20626.

[57]	Gaab M, Trukhan N, Maurer S, Gummaraju R, Müller U.The progression of Al-based metal-organic frameworks-from academic research to industrial production and applications.Microporous Mesoporous Mater 2012; 157:131-136.

[58]	Zhang Q, Dong S, Shao P, Zhu Y, Mu Z, Sheng D, et al.Covalent organic framework-based porous ionomers for high-performance fuel cells.Science 2022; 378(6616):181-186.

[59]	Li HF, Li HY, Dai QQ, Li H, Br JLédas.Hydrolytic stability of boronate ester-linked covalent organic frameworks.Adv Theory Simul 2018; 1(2):1700015.

[60]	Kandambeth S, Dey K, Banerjee R.Covalent organic frameworks: chemistry beyond the structure.J Am Chem Soc 2019; 141(5):1807-1822.

[61]	Nguyen HL, Hanikel N, Lyle SJ, Zhu C, Proserpio DM, Yaghi OM.A porous covalent organic framework with voided square grid topology for atmospheric water harvesting.J Am Chem Soc 2020; 142(5):2218-2221.

[62]	Biswal BP, Kandambeth S, Chandra S, Shinde DB, Bera S, Karak S, et al.Pore surface engineering in porous, chemically stable covalent organic frameworks for water adsorption.J Mater Chem A Mater Energy Sustain 2015; 3(47):23664-23669.

[63]	Li J, Jing XC, Li QQ, Li SW, Gao X, Feng X, et al.Bulk COFs and COF nanosheets for electrochemical energy storage and conversion.Chem Soc Rev 2020; 49(11):3565-3604.

[64]	Zhao S, Jiang C, Fan J, Hong S, Mei P, Yao R, et al.Hydrophilicity gradient in covalent organic frameworks for membrane distillation.Nat Mater 2021; 20(11):1551-1558.

[65]	Zhu Q, Wang X, Clowes R, Cui P, Chen LJ, Little MA, et al.3D cage COFs: a dynamic three-dimensional covalent organic framework with high-connectivity organic cage nodes.J Am Chem Soc 2020; 142(39):16842-16848.

[66]	Ma J, Fu XB, Li Y, Xia T, Pan L, Yao YF.Solid-state NMR study of adsorbed water molecules in covalent organic framework materials.Microporous Mesoporous Mater 2020; 305:110287.

[67]	Stegbauer L, Hahn MW, Jentys A, Savasci G, Ochsenfeld C, Lercher JA, et al.Tunable water and CO₂ sorption properties in isostructural azine-based covalent organic frameworks through polarity engineering.Chem Mater 2015; 27(23):7874-7881.

[68]	Fritz PW, Coskun A.Postfunctionalized covalent organic frameworks for water harvesting.ACS Cent Sci 2022; 8(7):871-873.

[69]	Nguyen HL, Gropp C, Hanikel N, Möckel A, Lund A, Yaghi OM.Hydrazine-hydrazide-linked covalent organic frameworks for water harvesting.ACS Cent Sci 2022; 8(7):926-932.

[70]	Nguyen HL.Covalent organic frameworks for atmospheric water harvesting.Adv Mater 2023; 35(17):2300018.

[71]	Tan KT, Tao SS, Huang N, Jiang DL.Water cluster in hydrophobic crystalline porous covalent organic frameworks.Nat Commun 2021; 12(1):6747.

[72]	Chen LH, Han WK, Yan XD, Zhang JW, Jiang YQ, Gu ZG.A highly stable ortho-ketoenamine covalent organic framework with balanced hydrophilic and hydrophobic sites for atmospheric water harvesting.ChemSusChem 2022; 15(24):e202201824.

[73]	Lin RB, He Y, Li P, Wang H, Zhou W, Chen B.Multifunctional porous hydrogen-bonded organic framework materials.Chem Soc Rev 2019; 48(5):1362-1389.

[74]	Lee WG, Yoon TU, Bae YS, Kim KS, Baek SB.Selective separation of Xe/Kr and adsorption of water in a microporous hydrogen-bonded organic framework.RSC Adv 2019; 9(63):36808-36814.

[75]	Yang Q, Wang Y, Shang Y, Du J, Yin J, Liu D, et al.Three hydrogen-bonded organic frameworks with water-induced single-crystal-to-single-crystal transformation and high proton conductivity.Cryst Growth Des 2020; 20(5):3456-3465.

[76]	Roques N, Mouchaham G, Duhayon C, Brandes S, Tachon A, Weber G, et al.A robust nanoporous supramolecular metal-organic framework based on ionic hydrogen bonds.Chemistry 2014; 20(37):11690-11694.

[77]	Luo YH, He XT, Hong DL, Chen C, Chen FH, Jiao J, et al.A dynamic 3D hydrogen-bonded organic frameworks with highly water affinity.Adv Funct Mater 2018; 28(48):1804822.

[78]	Boer SA, Conte L, Tarzia A, Huxley MT, Gardiner MG, Appadoo DRT, et al.Water sorption controls extreme single-crystal-to-single-crystal molecular reorganization in hydrogen bonded organic frameworks.Chemistry 2022; 28(57):e202201929.

[79]	Ma K, Li P, Xin JH, Chen Y, Chen Z, Goswami S, et al.Ultrastable mesoporous hydrogen-bonded organic framework-based fiber composites toward mustard gas detoxification.Cell Rep Phys Sci 2020; 1(2):100024.

[80]	Roques N, Tovar-Molle A, Duhayon C, Brandes S, Spiess A, Janiak C, et al.Modulation of the sorption characteristics for an H-bonded porous architecture by varying the chemical functionalization of the channel walls.Chemistry 2022; 28(61):e202201935.

[81]	Li J, Wang Y, Chen Y, Xiong Q, Yang J, Li L, et al.Round-the-clock water harvesting from dry air using a metal-organic framework.Chin J Chem Eng 2022; 49:170-177.

[82]	Cao HH, Shi L, Xiong ZY, Zhu HY, Wang H, Wang K, et al.Two-periodic MoS₂-type metal-organic frameworks with intrinsic intralayer porosity for high-capacity water sorption.Adv Mater 2025; 37(4):2414362.

[83]	Severino MI, Gkaniatsou E, Nouar F, Pinto ML, Serre C.MOFs industrialization: a complete assessment of production costs.Faraday Discuss 2021; 231:326-341.

[84]	Zheng ZL, Nguyen HL, Hanikel N, Li KKY, Zhou ZH, Ma TQ, et al.High-yield, green and scalable methods for producing MOF-303 for water harvesting from desert air.Nat Protoc 2023; 18(1):136-156.

[85]	Zheng Z, Alawadhi AH, Yaghi OM.Green synthesis and scale-up of MOFs for water harvesting from air. Mol Front J, 7(01n02):20–39 (2023)

[86]	Liu ZL, Xu JX, Xu M, Huang CF, Wang RZ, Li TX, et al.Ultralow-temperature-driven water-based sorption refrigeration enabled by low-cost zeolite-like porous aluminophosphate.Nat Commun 2022; 13(1):193.

[87]	Kim YD, Thu K, Ng KC.Adsorption characteristics of water vapor on ferroaluminophosphate for desalination cycle.Desalination 2014; 344:350-356.

[88]	de MF Lange, Zeng T, Vlugt TJH; Gascon J, Kapteijn F.Manufacture of dense CAU-10-H coatings for application in adsorption driven heat pumps: optimization and characterization.CrystEngComm 2015; 17(31):5911-5920.

[89]	Yoon TU, Baek SB, Kim D, Kim EJ, Lee WG, Singh BK, et al.Efficient separation of C₂ hydrocarbons in a permanently porous hydrogen-bonded organic framework.Chem Commun (Camb) 2018; 54(67):9360-9363.

[90]	Li TX, Wu MQ, Xu JX, Du RX, Yan TS, Wang PF, et al.Simultaneous atmospheric water production and 24-hour power generation enabled by moisture-induced energy harvesting.Nat Commun 2022; 13(1):6771.

[91]	Song W, Zheng Z, Alawadhi AH, Yaghi OM.MOF water harvester produces water from Death Valley desert air in ambient sunlight.Nat Water 2023; 1(7):626-634.

[92]	Tao Y, Li Q, Wu Q, Li H.Embedding metal foam into metal-organic framework monoliths for triggering a highly efficient release of adsorbed atmospheric water by localized eddy current heating.Mater Horiz 2021; 8(5):1439-1445.

[93]	Li Q, Ying Y, Tao Y, Li H.Assemblable carbon fiber/metal-organic framework monoliths for energy-efficient atmospheric water harvesting.Ind Eng Chem Res 2022; 61(3):1344-1354.

[94]	Wu QN, Su W, Li QQ, Tao YL, Li HQ.Enabling continuous and improved solar-driven atmospheric water harvesting with Ti₃C₂-incorporated metal-organic framework monoliths.ACS Appl Mater Interfaces 2021; 13(32):38906-38915.

[95]	Bai ZY, Wang PF, Xu JX, Wang RZ, Li TX.Progress and perspectives of sorption-based atmospheric water harvesting for sustainable water generation: materials, devices, and systems.Sci Bull (Beijing) 2024; 69(5):671-687.

[96]	Feng YH, Wang RZ, Ge TS.Pathways to energy-efficient water production from the atmosphere.Adv Sci 2022; 9(36):2204508.

[97]	Bezrukov AA, O DJ’Hearn, Gascon-Perez V, Darwish S, Kumar A, Sanda S, et al.Metal-organic frameworks as regeneration optimized sorbents for atmospheric water harvesting.Cell Rep Phys Sci 2023; 4(2):101252.

[98]	Almassad HA, Abaza RI, Siwwan L, Al-Maythalony B, Cordova KE.Environmentally adaptive MOF-based device enables continuous self-optimizing atmospheric water harvesting.Nat Commun 2022; 13(1):4873.

[99]	Wright AM, Kapelewski MT, Marx S, Farha OK, Morris W.Transitioning metal-organic frameworks from the laboratory to market through applied research.Nat Mater 2025; 24(2):178-187.

[100]

Farrusseng D, Daniel C, Hamill C, Casaban J, Didriksen T, Blom R, et al.Adsorber heat exchanger using Al-fumarate beads for heat-pump applications-a transport study.Faraday Discuss 2021; 225:384-402.

[101]

Chen Z, Shao Z, Tang Y, Deng F, Du S, Wang R.Study of the scale-up effect on the water sorption performance of MOF materials.ACS Mater Au 2023; 3(1):43-54.

[102]

Fuchs A, Knechtel F, Wang HZ, Ji Z, Wuttke S, Yaghi OM, et al.Water harvesting at the single-crystal level.J Am Chem Soc 2023; 145(26):14324-14334.

[103]

Terzis A, Ramachandran A, Wang KC, Asheghi M, Goodson KE, Santiago JG.High-frequency water vapor sorption cycling using fluidization of metal-organic frameworks.Cell Rep Phys Sci 2020; 1(5):100057.

[104]

European Commission.G.Technology readiness levels (TRL). In: Horizon 2020 work programme 2014–2015. Brussels: European Commission; 2014.

[105]

.Source global.Own your source of drinking water [Internet]. Scottsdale: Source global; undated [cited 2025 Sep 6]. Available from: https://www.source.co/.

[106]

Wei Z, Wang J, Guo S, Tan SC.Towards highly salt-rejecting solar interfacial evaporation: photothermal materials selection, structural designs, and energy management.Nano Research Energy 2022; 1:9120014.

[107]

Ahmad S, Siddiqui AR, Yang KJ, Zhou M, Ali HM, Hardian R, et al.Lubricated surface in a vertical double-sided architecture for radiative cooling and atmospheric water harvesting.Adv Mater 2024; 36(51):2404037.

[108]

Zhou M, Song HM, Xu XY, Shahsafi A, Qu YR, Xia ZY, et al.Vapor condensation with daytime radiative cooling.Proc Natl Acad Sci USA 2021; 118(14):e2019292118.

[109]

Xu ZX, Wang YM, Lin LC.Connectivity analysis of adsorption sites in metal-organic frameworks for facilitated water adsorption.ACS Appl Mater Interfaces 2023; 15(40):47081-47093.

[110]

Datar A, Witman M, Lin LC.Improving computational assessment of porous materials for water adsorption applications via flat histogram methods.J Phys Chem C Nanomater Interfaces 2021; 125(7):4253-4266.

[111]

Datar A, Witman M, Lin LC.Monte Carlo simulations for water adsorption in porous materials: best practices and new insights.AIChE J 2021; 67(12):e17447.

[112]

Wang YM, Datar A, Xu ZX, Lin LC.In silico screening of metal-organic frameworks for water harvesting.J Phys Chem C Nanomater Interfaces 2024; 128(1):384-395.

[113]

Liu Z, Shen D, Cai S, Tu Z, Li S.Machine learning-assisted prediction of water adsorption isotherms and cooling performance.J Mater Chem A Mater Energy Sustain 2023; 11(36):19455-19464.

[114]

Han B, Chakraborty A.Machine learning optimized adsorption heat transformations from adsorbents screening to enhanced performances.Energy Convers Manage 2025; 344:120272.

[115]

Zheng ZL, Alawadhi AH, Chheda S, Neumann SE, Rampal N, Liu SC, et al.Shaping the water-harvesting behavior of metal-organic frameworks aided by fine-tuned GPT models.J Am Chem Soc 2023; 145(51):28284-28295.

[116]

Guo S, Zhang YX, Tan SC.Device design and optimization of sorption-based atmospheric water harvesters.Device 2023; 1(4):100099.

[117]

Zhao G, Moulijn JA, Kapteijn F, Dautzenberg FM, Xu B, Lu Y.Monolithic fiber/foam-structured catalysts: beyond honeycombs and micro-channels.Catal Rev 2023; 66(5):1870-1950.

[118]

Kapteijn F, Moulijn JA.Structured catalysts and reactors-perspectives for demanding applications.Catal Today 2022; 383:5-14.

[119]

Gascon J, van JROmmen, Moulijn JA, Kapteijn F.Structuring catalyst and reactor-an inviting avenue to process intensification.Catal Sci Technol 2015; 5(2):807-817.

[120]

Zhang YX, Tan SC.Best practices for solar water production technologies.Nat Sustain 2022; 5(7):554-556.

[121]

Yang KJ, Pan TT, Ferhat N, Felix AI, Waller RE, Hong PY, et al.A solar-driven atmospheric water extractor for off-grid freshwater generation and irrigation.Nat Commun 2024; 15(1):6260.