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CECE-GC 1

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分离氚 1

可逆分解电压 1

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水果蔬菜 1

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反应堆含氚重水提氚关键技术研究进展

孙颖,王和义,桑革,罗阳明,曹伟,刘云怒,熊义富

《中国工程科学》 2007年 第9卷 第5期   页码 1-6

摘要：

基于建立的年处理10t重水的组合电解催化交换唱色谱分离（CECE-GC）实验系统，就含氘轻水提氘演示实验及利用含氚轻水进行含氚重水提氚模拟运行做了介绍结果表明，240h含氚轻水的连续运行，CECE系统整体浓缩倍数约为4，电解池氕、氚分离因子约为10；8 m3/d色谱分离系统运行23h，可将10.5m3料气的CECE-GC实验系统的建立，为重水提氚技术的进一步工程化提供了研究平台。

关键词： 重水     提氚     CECE-GC     演示实验    

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CECE法重水电解分离氚的热力学研究

朱正和,傅依备,孙颖,汪小琳,罗阳明,罗文浪,胡胜,阮文

《中国工程科学》 2008年 第10卷 第5期   页码 19-24

摘要：

文章研究了CECE法中D2-含氚重水同位素交换以及电解的热力学问题，即可逆分解电压和2个反应(19-1) 和(19-

关键词： 分离氚     联合电解-催化交换法(CECE法)     热力学     可逆分解电压    

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Pyrolysis behaviors of oil sludge based on TG/FTIR and PY-GC/MS

Wei SONG, Jianguo LIU, Yongfeng NIE,

《环境科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 59-64 doi: 10.1007/s11783-009-0152-y

摘要： Pyrolysis is an alternative technology for oil sludge treatment. Thermogravimetric Analysis-Fourier Transform Infrared Spectroscopy and Pyrolysis-Gas Chromatography/Mass Spectrometry were employed to investigate the pyrolysis process and products of oil sludge. The pyrolysis process was divided into five stages: drying and gas desorption, oil volatilization, main pyrolysis, semi-coke charring, and mineral decomposition. The main reaction temperatures ranged from 497.6 K to 753.2 K. The products were mainly composed of pairs of alkane and alkene (carbon number ranges from 1 to 27). The mechanisms consisted of random chain scission followed by end chain scission at high temperatures with volatilization occurring during the whole process. This study is useful not only for the proper design of a pyrolysis system, but also for improving the utilization of liquid oil products.

关键词： oil sludge     pyrolysis     Thermogravimetric Analysis-Fourier Transform Infrared Spectroscopy (TG-FTIR)     Pyrolysis-Gas Chromatography/Mass Spectrometry (PY-GC/MS)    

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GC/LC-Q-TOFMS 两种技术联用同时筛查水果蔬菜中733 种农药残留 Article

庞国芳, 常巧英, 白若镔, 范春林, 张紫娟, 闫宏远, 吴兴强​​​​​

《工程（英文）》 2020年 第6卷 第4期   页码 432-441 doi: 10.1016/j.eng.2019.08.008

摘要：

本文通过创建LC-Q-TOFMS（525种农药）和GC-Q-TOFMS（485种农药和209种PCBs）两大精确质谱数数据库，开发了一次样品制备、两种高分辨质谱联用同时检测733种农药化学污染物残留的检测方法通过8种代表性水果蔬菜对联用技术的筛查农药范围、灵敏度、回收率和重现性等方法效能评价，显示出这项联用技术有三方面优势：①两种技术联用与单种技术相比，其发现能力分别提高了51.1%（GC-Q-TOFMS，

关键词： 农药残留     GC-Q-TOFMS     LC-Q-TOFMS     精确质量数据库     谱图库     水果蔬菜    

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A new procedure combining GC-MS with accelerated solvent extraction for the analysis of phthalic acid

Tingting MA, Ying TENG, Peter CHRISTIE, Yongming LUO, Yongshan CHEN, Mao YE, Yujuan HUANG

《环境科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 31-42 doi: 10.1007/s11783-012-0463-2

摘要： An optimized procedure based on gas chromatography-mass spectrometry (GC-MS) combined with accelerated solvent extraction (ASE) is developed for the analysis of six phthalic acid esters (PAEs), which are priority soil pollutants nominated by United States Environmental Protection Agency (USEPA). Quantification of PAEs in soil employs ultrasonic extraction (UE) (USEPA 3550) and ASE (USEPA 3545), followed by clean up procedures involving three different chromatography columns and two combined elution methods. GC-MS conditions under selected ion monitoring (SIM) mode are described and quality assurance and quality control (QA/QC) criteria with high accuracy and sensitivity for target analytes were achieved. Method reliability is assured with the use of an isotopically labeled PAE, di- -butyl phthalate-d4 (DnBP-D4), as a surrogate, and benzyl benzoate (BB) as an internal standard, and with the analysis of certified reference materials (CRM). QA/QC for the developed procedure was tested in four PAE-spiked soils and one PAE-contaminated soil. The four spiked soils were originated from typical Chinese agricultural fields and the contaminated soil was obtained from an electronic waste dismantling area. Instrument detection limits (IDLs) for the six PAEs ranged 0.10–0.31 μg·L and method detection limits (MDLs) of the four spiked soils varied from a range of 20–70 μg·kg to a range of 90– 290 μg·kg . Linearity of response between 20 μg·L and 2 mg·L was also established and the correlation coefficients ( ) were all>0.998. Spiked soil matrix showed relative recovery rates between 75 and 120% for the six target compounds and about 93% for the surrogate substance. The developed procedure is anticipated to be highly applicable for field surveys of soil PAE pollution in China.

关键词： phthalic acid esters     quality assurance and quality control     soil type     accelerated solvent extraction     certified reference materials    

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Thermal degradation characteristics and products obtained after pyrolysis of specific polymers found in Waste Electrical and Electronic Equipment

Evangelia C. Vouvoudi, Aristea T. Rousi, Dimitris S. Achilias

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0996-5

摘要： Modern societies strongly support the recycling practices over simple waste accumulation due to environmental harm caused. In the framework of sustainable recycling of plastics from WEEE, pyrolysis is proposed here as a means of obtaining secondary value-added products. The aim of this study was to investigate the thermal degradation and the products obtained after pyrolysis of specific polymers found in the plastic part of WEEE, using thermogravimetric analysis and a pyrolizer equipped with a GC/MS. Polymers studied include ABS, HIPS, PC and a blend having a composition similar to that appearing in WEEE. It was found that, PC shows greater heat endurance compared to the other polymers, whereas ABS depolymerizes in three-steps. The existence of several polymers in the blend results in synergistic effects which decrease the onset and final temperature of degradation. Moreover, the fragmentation occurred in the pyrolyzer, at certain temperatures, resulted in a great variety of compounds, depending on the polymer type, such as monomers, aromatic products, phenolic compounds and hydrocarbons. The main conclusion from this investigation is that pyrolysis could be an effective method for the sustainable recycling of the plastic part of WEEE resulting in a mixture of chemicals with varying composition but being excellent to be used as fuel retrieved from secondary recycling sources.

关键词： Pyrolysis     WEEE recycling     ABS     HIPS     PC     Py-GC/MS     TGA    

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Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic products

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

《能源前沿（英文）》 2010年 第4卷 第3期   页码 424-429 doi: 10.1007/s11708-010-0015-z

摘要： Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed to achieve fast pyrolysis of xylan and on-line analysis of pyrolysis vapors. Tests were conducted to investigate the effects of temperature on pyrolytic products, and to reveal the effect of HZSM-5 and M/HZSM-5 (M= Fe, Zn) zeolites on pyrolysis vapors. The results showed that the total yield of pyrolytic products first increased and then decreased with the increase of temperature from 350°C to 900°C. The pyrolytic products were complex, and the most abundant products included hydroxyacetaldehyde, acetic acid, 1-hydroxy-2-propanone, 1-hydroxy-2-butanone and furfural. Catalytic cracking of pyrolysis vapors with HZSM-5 and M/HZSM-5 (M= Fe, Zn) catalysts significantly altered the product distribution. Oxygen-containing compounds were reduced considerably, and meanwhile, a lot of hydrocarbons, mainly toluene and xylenes, were formed. M/HZSM-5 catalysts were more effective than HZSM-5 in reducing the oxygen-containing compounds, and therefore, they helped to produce higher contents of hydrocarbons than HZSM-5.

关键词： xylan     fast pyrolysis     catalytic pyrolysis     Py-GC/MS     HZSM-5    

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Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extraction and gas chromatography-mass spectrometry

Wenfeng SUN, Ruibao JIA, Baoyu GAO

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 66-74 doi: 10.1007/s11783-010-0257-3

摘要： In this paper, a method using solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) was developed to simultaneously analyze five taste and odor compounds in surface water, i.e., 2-methylisoborneol (2-MIB), 2,4,6-trichloroanisole (TCA), 2-isopropyl-3-methoxy pyrazine (IPMP), 2-isobutyl-3-methoxy pyrazine (IBMP), and -1,10-dimethyl- -9-decalol (geosmin, GSM). The mass spectrometry was operated in selective ion monitoring (SIM) mode. Three kinds of SPE columns and three eluting solvents were compared, the C18 column was chosen as optimum SPE column, and methanol was chosen as the optimum eluting solvent. It was found that the method showed good linearity in the range of 1–200 ng·L and gave detection limits of 0.5–1.5 ng·L for individual compounds. Good recoveries (93.5%–108%) and relative standard deviations (1.58%–7.31%) were also obtained. Additionally, concentrations of these taste and odor compounds in Jinan’s surface and drinking water were analyzed by applying this method, and the results showed that GSM and 2-MIB were the dominant taste and odor compounds in Jinan’s raw water.

关键词： solid-phase extraction (SPE)     gas chromatography-mass spectrometry (GC-MS)     taste and odor compounds     surface water     micropollutant    

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An extraction- assay system: Evaluation on flavonols in plant resistance to Pb and Cd by supercritical extraction- gas chromatography

Xu Zhang, Huanhuan Yang, Xinlei Wang, Wen Song, Zhaojie Cui

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1059-2

摘要：

SFE-GC system is established for flavonols assessment.

Optimal parameters of SFE-GC are evaluated and determined.

Quercetin and kaempferol are detected in plant under heavy metal stress.

Gene expression analysis shows consistent regularity with content of flavonols.

ROS level is applied for elaborating the plant resistance status.

关键词： Flavonols     Heavy metal     Supercritical carbon dioxide extraction (SFE)     GC     Plant resistance    

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Odour reducing microbial-mineral additive for poultry manure treatment

Kajetan Kalus, Sebastian Opaliński, Devin Maurer, Somchai Rice, Jacek A. Koziel, Mariusz Korczyński, Zbigniew Dobrzański, Roman Kołacz, Beata Gutarowska

《环境科学与工程前沿（英文）》 2017年 第11卷 第3期 doi: 10.1007/s11783-017-0928-4

摘要： Poultry production systems are associated with emissions of odorous volatile organic compounds (VOCs), ammonia (NH ), hydrogen sulfide (H S), greenhouse gases, and particulate matter. Development of mitigation technologies for these emissions is important. Previous laboratory-scale research on microbial-mineral treatment has shown to be effective for mitigation of NH , H S and amines emissions from poultry manure. The aim of this research was to assess the effectiveness of surface application of a microbial-mineral treatment for other important odorants, i.e., phenolics and sulfur-containing VOCs. Microbial-mineral litter additive consisting of 20% (w/w) of bacteria powder (six strains of heterotrophic bacteria) and 80% of mineral carrier (perlite-bentonite) was used at a dose of 500 g?m (per ~31 kg of manure). Samples of air were collected in two series, 4 and 7 days after application of additives. An odor profile of the poultry manure was determined using simultaneous chemical and sensory analysis. Reduction levels of VOCs determined on Day 4 was between 31% and 83% for mineral adsorbent treatment and in the range of 9% and 96% for microbial-mineral additive, depending on the analyzed compound. Reduction levels on Day 7 were considerably lower than on Day 4, suggesting that the odorous VOCs treatment efficacy is relatively short. There was no significant difference between treatments consisting of microbial-mineral additive and mineral carrier alone.

关键词： Odour mitigation     Poultry manure additive     GC-MS-Olfactometry     Volatile organic compounds    

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标题 作者 时间 类型 操作

反应堆含氚重水提氚关键技术研究进展

孙颖,王和义,桑革,罗阳明,曹伟,刘云怒,熊义富

期刊论文

CECE法重水电解分离氚的热力学研究

朱正和,傅依备,孙颖,汪小琳,罗阳明,罗文浪,胡胜,阮文

期刊论文

Pyrolysis behaviors of oil sludge based on TG/FTIR and PY-GC/MS

Wei SONG, Jianguo LIU, Yongfeng NIE,

期刊论文

GC/LC-Q-TOFMS 两种技术联用同时筛查水果蔬菜中733 种农药残留

庞国芳, 常巧英, 白若镔, 范春林, 张紫娟, 闫宏远, 吴兴强​​​​​

期刊论文

A new procedure combining GC-MS with accelerated solvent extraction for the analysis of phthalic acid

Tingting MA, Ying TENG, Peter CHRISTIE, Yongming LUO, Yongshan CHEN, Mao YE, Yujuan HUANG

期刊论文

Thermal degradation characteristics and products obtained after pyrolysis of specific polymers found in Waste Electrical and Electronic Equipment

Evangelia C. Vouvoudi, Aristea T. Rousi, Dimitris S. Achilias

期刊论文

Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic products

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

期刊论文

Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extraction and gas chromatography-mass spectrometry

Wenfeng SUN, Ruibao JIA, Baoyu GAO

期刊论文

An extraction- assay system: Evaluation on flavonols in plant resistance to Pb and Cd by supercritical extraction- gas chromatography

Xu Zhang, Huanhuan Yang, Xinlei Wang, Wen Song, Zhaojie Cui

期刊论文

Odour reducing microbial-mineral additive for poultry manure treatment

Kajetan Kalus, Sebastian Opaliński, Devin Maurer, Somchai Rice, Jacek A. Koziel, Mariusz Korczyński, Zbigniew Dobrzański, Roman Kołacz, Beata Gutarowska

期刊论文