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期刊论文 1

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2007 1

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Synthesis and thermosensitive behavior of dextran graft copolymers containing poly (N-vinylcaprolactam) side chains

SHI Huangying, CHEN Wenjuan, ZHANG Liming

《化学科学与工程前沿(英文)》 2007年 第1卷 第1期   页码 72-75 doi: 10.1007/s11705-007-0015-7

摘要: New graft copolymers were synthesized by grafting N-vinylcaprolactam onto dextran. Their composition and structure were investigated by elemental analyses, infrared spectra and thermogravimetric analyses. By optical transmittance measurements, it was found that the aqueous solutions of these graft copolymers showed a temperature-dependent transmittance change due to the introduction of thermosensitive poly (-vinylcaprolactam) graft chains. Moreover, the lower critical solution temperature (LCST) of the graft copolymer in aqueous solution was dependent on its grafting extent and concentration. The LCST value was found to increase with the increase of the grafting extent and decrease with the increase of the copolymer concentration. With these stimuli-response properties, such polysaccharide derivative may hold potential applications in biomedicine and biotechnology.

关键词: transmittance     copolymer concentration     LCST     temperature     elemental    

标题 作者 时间 类型 操作

Synthesis and thermosensitive behavior of dextran graft copolymers containing poly (N-vinylcaprolactam) side chains

SHI Huangying, CHEN Wenjuan, ZHANG Liming

期刊论文