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2017 1

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5-戊二胺 1

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三参数区间数 1

代谢 1

增强剂 1

多指标决策 1

尼龙66树脂 1

抗静电 1

生物基聚酰胺 1

细菌生产 1

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Antibacterial and anti-flaming PA6 composite with metathetically prepared nano AgCl@BaSO

Wei Zhang, Boren Xu, Caihong Gong, Chunwang Yi, Shen Zhang

《化学科学与工程前沿（英文）》 2021年第15卷第2期页码 340-350 doi: 10.1007/s11705-020-1942-9

摘要： In this study, a facile and environmentally friendly method with low energy consumption for preparing nanoscale AgCl and BaSO co-precipitates (AgCl@BaSO co-precipitates) was developed based on the metathetical reaction. Then, the dried co-precipitates were melt-compounded with polyamide 6 (PA6) resins at a specified mass ratio in a twin-screw extruder. The results demonstrated that in the absence of any coating agent or carrier, the nanoparticles of AgCl@BaSO co-precipitates were homogeneously dispersed in the PA6 matrix. Further analysis showed that after the addition of AgCl@BaSO co-precipitates, the antibacterial performance, along with the flame-retardance and anti-dripping characteristics of PA6, was enhanced significantly. In addition, the PA6 composites possessed high spinnability in producing pre-oriented yarn.

关键词： nano AgCl@BaSO₄ co-precipitates antibacterial flame resistance PA6 composite PA6 yarn

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A comprehensive analysis of a 3-P (Pa) S spatial parallel manipulator

Yuzhe LIU,Liping WANG,Jun WU,Jinsong WANG

《机械工程前沿（英文）》 2015年第10卷第1期页码 7-19 doi: 10.1007/s11465-015-0324-3

摘要：

In this paper, a novel 3-degree of freedom (3-DOF) spatial parallel kinematic machine (PKM) is analyzed. The manipulator owns three main motions (two rotations and one translation) and three concomitant motions (one rotation and two translations). At first, the structure of this spatial PKM is simplified according to the characteristic of each limb. Secondly, the kinematics model of this spatial PKM is set up. In addition, the relationship between the main motions and concomitant motions is studied. The workspaces respectively based on the outputs and inputs are derived and analyzed. Furthermore, the velocity model is put forward. Two indexes based on the velocity model are employed to investigate the performance of this spatial PKM. At last, the output error model can be obtained and simulated. The comprehensive kinematics analysis in this paper is greatly useful for the future applications of this spatial PKM.

关键词： parallel mechanism concomitant motions kinematics workspaces error model

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Preparation and rheological behaviors of PA6/SiO2 nanocompiste

WEI Shanshan, LIU Yuejun, LI Xianggang, HUANG Yugang, WANG Xiayu, ZHANG Ping

《化学科学与工程前沿（英文）》 2007年第1卷第4期页码 332-337 doi: 10.1007/s11705-007-0060-2

摘要： The polyamide 6 (PA6)/SiO nanocomposites were prepared by in situ polymerization and the rheological behaviors were investigated. The morphology of resultant materials was characterized by scanning electron microscopy (SEM) and the rheological behaviors were characterized by capillary rheometer. The results showed that the SiO particle size was around 50 nm and the particles dispersed evenly in PA6 matrix. The nanocomposites were pesudoplastic fluids and the apparent viscosities of nanocomposites increased initially and then decreased with the increase in nano-SiO content at the same temperature. The non-Newtonian indexes of nanocomposites were smaller than those of pure PA6. With the increase in nano-SiO content the apparent viscous activation energies of nanocomposites increased initially and then decreased. The rheological behaviors revealed that there were strong interactions between PA6 macromolecule chains and nano-SiO particles.

关键词： polyamide temperature rheological activation pesudoplastic

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1,5-戊二胺的细菌合成及应用 Review

马伟超, 陈可泉, 李艳, 郝宁, 王昕, 欧阳平凯

《工程（英文）》 2017年第3卷第3期页码 308-317 doi: 10.1016/J.ENG.2017.03.012

摘要：

1,5-戊二胺是一种广泛分布于原核和真核生物中的具有多种生物活性的天然多胺，正日益成为一种重要的工业化学品，并在多个领域展现出广泛的应用前景，特别是作为单体用于合成生物基聚酰胺。基于1,5-戊二胺的聚酰胺5X 具有优异的性能和环境友好特性，因而有广泛的应用前景。本文总结了近期关于1,5-戊二胺在细菌中的生物合成、代谢及生理学功能，着重介绍了1,5-戊二胺在大肠杆菌的代谢调控机制。文中还综述了微生物发酵法和全细胞催化法生产1,5-戊二胺的进展及1,5-戊二胺的分离纯化方法。此外，对1,5-戊二胺在生物基聚酰胺合成中的应用进行了总结，并对利用可再生资源生产1,5-戊二胺进行了展望和对以后的研究提出了建议。

关键词： 1 5-戊二胺代谢细菌生产生物基聚酰胺 PA 5X

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抗静电增强尼龙66研制

刘建强

《中国工程科学》 2004年第6卷第6期页码 77-78

摘要：

以阴离子和非离子型抗静电剂组成复合抗静电体系，用玻璃纤维为增强剂，研制成具有良好抗静电和机械性能优良的尼龙66；介绍了抗静电复合体系及玻璃纤维含量对抗静电增强尼龙性能的影响。

关键词：尼龙66树脂抗静电增强剂

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三参数区间数研究及其在决策分析中的应用

胡启洲,张卫华,于莉

《中国工程科学》 2007年第9卷第3期页码 47-51

摘要：

在定义三参数区间数的基础上，给出了三参数区间数的运算关系；然后将权重为区间数的多指标决策问题转化为指标取值为三参数区间数的多指标决策问题；在三参数区间数理想方案点定义的基础上，给出了权重为三参数区间数的逼近理想点法；最后将其应用于某城市公交线网的优化调整中。结果表明，该法科学合理、切实可行。

关键词：多指标决策三参数区间数逼近理想点法

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Preparation and properties of hollow fibre nanofiltration membrane with continuous coffee-ring structure

Xiuzhen Wei, Xufeng Xu, Yi Chen, Qian Zhang, Lu Liu, Ruiyuan Yang, Jinyuan Chen, Bosheng Lv

《化学科学与工程前沿（英文）》 2021年第15卷第2期页码 351-362 doi: 10.1007/s11705-020-1943-8

摘要： Polyamide (PA) hollow fibre composite nanofiltration (NF) membranes with a coffee-ring structure and beneficial properties were prepared by adding graphene oxide (GO) into the interfacial polymerization process. The presentation of the coffee-ring structure was attributed to the heterogeneous, finely dispersed multiphase reaction system and the “coffee-stain” effect of the GO solution. When the piperazine concentration was 0.4 wt-%, the trimesoyl chloride concentration was 0.3 wt-%, and the GO concentration was 0.025 wt-%, the prepared NF membranes showed the best separation properties. The permeate flux was 76 L·m ·h , and the rejection rate for MgSO was 98.6% at 0.4 MPa. Scanning electron microscopy, atomic force microscopy, and attenuated total reflectance-Fourier transform infrared spectroscopy were used to characterize the chemical structure and morphology of the PA/GO NF membrane. The results showed that GO was successfully entrapped into the PA functional layer. Under neutral operating conditions, the PA/GO membrane showed typical negatively charged NF membrane separation characteristics, and the rejection rate decreased in the order of Na SO >MgSO >MgCl >NaCl. The PA/GO NF membrane showed better antifouling performance than the PA membrane.

关键词： GO PA interfacial polymerization hollow fibre NF membrane