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Reaction and characterization of crosslinking hyperbranched poly (amine-ester) with succine anhydride

XIAO Ling, WEI Xiuzhen, ZHU Baoku

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 355-359 doi: 10.1007/s11705-007-0064-y

摘要： Basing on hydroxyl terminated hyperbranched poly (amine-ester)s (HPAEs), the cross-linking reactions and preparation of ester-crosslinked HPAE films were investigated using succine anhydride (SA) as crosslink reagent. It was proved that the cross-linking reaction between HPAE and SA followed a two-step mechanism. This mechanism provides an efficient route to prepare HPAE/SA cross-linked films, in which, the precursor films were prepared by casting HPAE/SA solution at a lower temperature, and then curing the films at a higher temperature. By varying SA content, the solid HPAE/SA films with different cross-linking degrees were prepared successfully. The highest tensile strength of the cross-linked film could reach 59.60 MPa. With all water contact angle smaller than 74.3°, the crosslinked films demonstrated good hydrophilic properties.

关键词： different cross-linking     amine-ester     temperature     crosslinked     efficient    

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Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic

Jun Wei, Jianbo Zhao, Di Cai, Wenqiang Ren, Hui Cao, Tianwei Tan

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 857-867 doi: 10.1007/s11705-019-1880-6

摘要： In addition to the specific surface area, surface topography and characteristics such as the pore size, pore size distribution, and micro/mesopores ratio are factors that determine the performance of porous carbons (PCs) in the fields of energy, catalysis, and adsorption. Based on the mechanism of weight loss of polyaspartic acid at high temperatures, this study provided a new method for adjusting the surface morphology of PCs by changing the cross-linking ratio of the precursor, where cross-linked polyaspartic acid was used as precursor without additional activating agents. N adsorption analysis indicated that the specific surface area of the obtained PCs was as high as 1458 m ·g , of which 1200 m ·g was the contribution of the microporous area and the highest pore volume was 1.13 cm ·g , of which the micropore volume was 0.636 cm ·g . The thermogravimetric analysis results of the precursor, and also the scanning electron microscopy and Brunauer–Emmet–Teller analysis results of the carbonization product confirmed that the prepared PCs presented multilevel pore structure, and the diameters of most pores were 0.78 and 3.97 nm; moreover, the pore size distribution was relatively uniform. This conferred the PCs the ultrahigh hydrogen adsorption capacity of up to 4.52 wt-% at 77 K and 1.13 bar, in addition to their great energy storage and catalytic potential.

关键词： porous carbon     multilevel pores     polyaspartic acid     cross-linking     hydrogen adsorption    

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Crosslinking acrylamide with EDTA-intercalated layered double hydroxide for enhanced recovery of Cr(VI) and Congo red: Adsorptive and mechanistic study

Jing Li, Haiqin Yu, Xue Zhang, Rixin Zhu, Liangguo Yan

《环境科学与工程前沿（英文）》 2020年 第14卷 第3期 doi: 10.1007/s11783-020-1229-x

摘要： Functional groups of AM and EDTA in composite increased removal of Cr(VI) and CR. Removal process reached equilibrium within 30 min and was minimally affected by pH. Elimination of Cr(VI) was promoted by coexisting CR. Adsorption process of CR was less influenced by the presence of Cr(VI). Mechanisms were electrostatic attraction, surface complexation and anion exchange. We prepared ethylenediaminetetraacetic acid (EDTA)-intercalated MgAl-layered double hydroxide (LDH-EDTA), then grafted acrylamide (AM) to the LDH-EDTA by a cross-linking method to yield a LDH-EDTA-AM composite; we then evaluated its adsorptive ability for Congo red (CR) and hexavalent chromium (Cr(VI)) in single and binary adsorption systems. The adsorption process on LDH-EDTA-AM for CR and Cr(VI) achieved equilibrium quickly, and the removal efficiencies were minimally affected by initial pH. The maximum uptake quantities of CR and Cr(VI) on LDH-EDTA-AM were 632.9 and 48.47 mg/g, respectively. In mixed systems, chromate removal was stimulated by the presence of CR, while the adsorption efficiency of CR was almost not influenced by coexisting Cr(VI). The mechanisms involved electrostatic attraction, surface complexation, and anion exchange for the adsorption of both hazardous pollutants. In the Cr(VI) adsorption process, reduction also took place. The removal efficiencies in real contaminated water were all higher than those in the laboratory solutions.

关键词： Chromate     Dye adsorption     Simultaneous removal     Cross-linking method     Amino functionalization    

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The mechanisms linking adiposopathy to type 2 diabetes

null

《医学前沿（英文）》 2013年 第7卷 第4期   页码 433-444 doi: 10.1007/s11684-013-0288-9

摘要：

Obesity is defined as excessive accumulation of body fat in proportion to body size. When obesity occurs, the functions of adipose tissue may be deregulated, which is termed as adiposopathy. Adiposopathy is an independent risk factor for many diseases, including diabetes and cardiovascular diseases. In overweight or obese subjects with adiposopathy, hyperlipidemia exerts lipotoxicity in pancreatic islet and liver and induces pancreatic β cell dysfunction and liver insulin resistance, which are the decisive factors causing type 2 diabetes. Moreover, adipokines have been shown to play important roles in the regulation of glucose homeostasis. When adiposopathy occurs, abnormal changes in the serum adipokine profile correlate with the development and progression of pancreatic β cell dysfunction and insulin resistance in peripheral tissue. The current paper briefly discusses the latest findings regarding the effects of adiposopathy-related lipotoxicity and cytokine toxicity on the development of type 2 diabetes.

关键词： obesity     adiposopathy     lipotoxicity     adipokines     diabetes    

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利用两个自适应特征改进实体链接 Research Article

张鸿彬,陈权,张伟文

《信息与电子工程前沿（英文）》 2022年 第23卷 第11期   页码 1620-1630 doi: 10.1631/FITEE.2100495

摘要：

实体链接是自然语言处理中的一项基本任务。现有的基于神经网络的系统更多地关注全局模型的构建，而忽略了局部模型中潜在的语义信息和有效实体类型信息的获取。本文提出两个自适应特征，其中第一个自适应特征使得局部和全局模型能够捕获潜在信息，第二个自适应特征能够描述实体类型嵌入的有效信息。这些自适应特征可以很自然地协同工作来处理一些不确定的实体类型信息。实验结果表明，我们的实体链接系统在AIDA-B和MSNBC数据集上取得了最佳的性能，并在域外数据集上达到了最佳的平均性能。这些结果表明，所提出的自适应特征能够基于其自身不同的上下文来捕获有利于实体链接的信息。

关键词： 实体链接；局部模型；全局模型；自适应特征；实体类型    

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A review on anammox process for the treatment of antibiotic-containing wastewater: Linking effects with

Jinjin Fu, Quan Zhang, Baocheng Huang, Niansi Fan, Rencun Jin

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1309-y

摘要： Abstract • Anammox is promising for nitrogen removal from antibiotic-containing wastewater. • Most antibiotics could inhibit the anammox performance and activity. • Antibiotic pressure promoted the increase in antibiotic resistance genes (ARGs). • Antibiotic-resistance mechanisms of anammox bacteria are speculated. Antibiotic is widely present in the effluent from livestock husbandry and the pharmaceutical industry. Antibiotics in wastewater usually have high biological toxicity and even promote the occurrence and transmission of antibiotic resistant bacteria and antibiotic resistance genes. Moreover, most antibiotic-containing wastewater contains high concentration of ammonia nitrogen. Improper treatment will lead to high risk to the surrounding environment and even human health. The anaerobic ammonium oxidation (anammox) with great economic benefit and good treatment effect is a promising process to remove nitrogen from antibiotic-containing wastewater. However, antibiotic inhibition has been observed in anammox applications. Therefore, a comprehensive overview of the single and combined effects of various antibiotics on the anammox system is conducted in this review with a focus on nitrogen removal performance, sludge properties, microbial community, antibiotic resistance genes and anammox-involved functional genes. Additionally, the influencing mechanism of antibiotics on anammox consortia is summarized. Remaining problems and future research needs are also proposed based on the presented summary. This review provides a better understanding of the influences of antibiotics on anammox and offers a direction to remove nitrogen from antibiotic-containing wastewater by the anammox process.

关键词： Anammox     Antibiotic     Mechanism     Inhibition    

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Semantics for linking data from 4D BIM to digital collaborative support

Calin BOJE, Veronika BOLSHAKOVA, Annie GUERRIERO, Sylvain KUBICKI, Gilles HALIN

《工程管理前沿（英文）》 2022年 第9卷 第1期   页码 104-116 doi: 10.1007/s42524-020-0111-7

摘要： Synchronous collaboration sessions within the context of 4D BIM position construction professionals into a complex socio–technical system. This system includes hardware, software, people, and broader community aspects. This article strictly focuses on the ontology representation of synchronous collaboration sessions with collocated collective decision-making. The model is designed by considering various 4D BIM model uses while a digital multiuser touch table facilitates the collaboration between actors. The outlined ontological model aims to improve interoperability and to move toward a knowledge-driven, smart-built environment paradigm. A knowledge engineering methodology is outlined, by virtue of which the semantics of the presented model are defined and discussed. Concepts from nearby knowledge fields, especially from the Industry Foundation Classes, are reused. Several examples on querying the knowledge base according to the project meeting requirements are outlined to demonstrate the benefits of using the model. Although 4D BIM model data can be imported by using standard formats, capturing data about the social context remains a challenge in the future. This is expected to change the ontology model structure by considering user ergonomics, data modeling requirements, as well as technical implementation constraints.

关键词： 4D BIM     ontology     IFC     decision-making     linked data     collaboration     planning    

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Linking key intervention timings to rapid declining effective reproduction number to quantify lessons

Zhihang Peng, Wenyu Song, Zhongxing Ding, Quanquan Guan, Xu Yang, Qiaoqiao Xu, Xu Wang, Yankai Xia

《医学前沿（英文）》 2020年 第14卷 第5期   页码 623-629 doi: 10.1007/s11684-020-0788-3

摘要： Coronavirus disease 2019 (COVID-19) is currently under a global pandemic trend. The efficiency of containment measures and epidemic tendency of typical countries should be assessed. In this study, the efficiency of prevention and control measures in China, Italy, Iran, South Korea, and Japan was assessed, and the COVID-19 epidemic tendency among these countries was compared. Results showed that the effective reproduction number( ) in Wuhan, China increased almost exponentially, reaching a maximum of 3.98 before a lockdown and rapidly decreased to below 1 due to containment and mitigation strategies of the Chinese government. The in Italy declined at a slower pace than that in China after the implementation of prevention and control measures. The in Iran showed a certain decline after the establishment of a national epidemic control command, and an evident stationary phase occurred because the best window period for the prevention and control of the epidemic was missed. The epidemic in Japan and South Korea reoccurred several times with the fluctuating greatly. The epidemic has hardly rebounded in China due to the implementation of prevention and control strategies and the effective enforcement of policies. Other countries suffering from the epidemic could learn from the Chinese experience in containing COVID-19.

关键词： COVID-19     epidemic control comparison     Chinese experience    

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化学工业绿色制造产业链接技术和发展方向探析

李瑾,胡山鹰,陈定江,宋晓旭,张群,樊炯明,李光耀,马淑杰,金涌

《中国工程科学》 2017年 第19卷 第3期   页码 72-79 doi: 10.15302/J-SSCAE-2017.03.011

摘要：

“十三五”以来，我国化学工业的绿色发展取得了显著进步，在产品产量提高的同时，资源消耗、能源消耗、污染排放均实现了大幅减少。绿色制造是当前我国实现可持续发展的必要途径。要实现化学工业的绿色发展，除了要关注化工行业自身的绿色制造，还要关注化工产业与其他行业、与社会进行产业链接时的绿色协调发展。本文在对我国化学工业绿色发展现状进行分析的基础上，给出我国化工行业绿色发展的方向，提出化学工业绿色制造产业链接的关键技术，并通过五个企业案例进行典型模式分析。

关键词： 绿色制造     产业链接技术     战略     化学工业    

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Linking elements to outcomes of knowledge transfer in the project environment: Current review and future

《工程管理前沿（英文）》 2022年 第9卷 第2期   页码 221-238 doi: 10.1007/s42524-022-0195-3

摘要： A project is a specific effort to create a unique product, so it is a favorable place for knowledge creation and development. Knowledge can be transferred inside and outside projects and their parent project-based organizations, thus affecting project performance and organizational competitiveness. However, the current research on the elements and outcomes of knowledge transfer (KT) in the project environment lacks completeness and clarity, and that on the different levels of KT is fragmented. This study aims to conduct comprehensive research to determine and link the elements and outcomes of KT in the project environment. The authors systematically analyzed the relevant literature from 2000 to 2021, which showed an increasing publication trend. They divided KT in the project environment into three levels according to the transfer scenario: Intra-project, cross-project, and cross-organizational KT. Five-dimensional transfer elements and two-dimensional transfer outcomes were then identified and analyzed from previous literature. Lastly, the relationships between the transfer elements and outcomes were gathered to create a comprehensive model. Importantly, the knowledge gap in the current literature was highlighted, and future research directions were put forward. This study builds a theoretical framework linking transfer elements to outcomes that can serve as a basis for scholars and practitioners to develop effective strategies for KT in the project environment.

关键词： knowledge transfer     knowledge management     project management     project environment     literature review    

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Methods and applications of DEA cross-efficiency: Review and future perspectives

Jie WU, Jiasen SUN, Liang LIANG

《工程管理前沿（英文）》 2021年 第8卷 第2期   页码 199-211 doi: 10.1007/s42524-020-0133-1

摘要： The field of engineering management usually involves evaluation issues, such as program selection, team performance evaluation, technology selection, and supplier evaluation. The traditional self-evaluation data envelopment analysis (DEA) method usually exaggerates the effects of several inputs or outputs of the evaluated decision-making unit (DMU), resulting in unrealistic results. To address this problem, scholars have proposed the cross-efficiency evaluation (CREE) method. Compared with the DEA method, CREE can rank DMUs more completely by using reasonable weights. With the extensive application of this technique, several problems, such as non-unique weights and non-Pareto optimal results, have arisen in CREE methods. Therefore, the improvement of CREE has attracted the attention of many scholars. This paper reviews the theory and applications of CREE, including the non-uniqueness problem, the aggregation of cross-efficiency data, and applications in engineering management. It also discusses the directions for future research on CREE.

关键词： cross-efficiency evaluation     efficiency     secondary goal model     aggregation     review    

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Prevalence and determinations of physical inactivity among public hospital employees in Shanghai, China: a cross-sectional

null

《医学前沿（英文）》 2015年 第9卷 第1期   页码 100-107 doi: 10.1007/s11684-014-0372-9

摘要：

This study aims to explore the prevalence and determinations of physical inactivity among hospital employees in Shanghai, China. A cross-sectional study of 4612 employees aged 19 to 68 years was conducted through stratified cluster sampling from different classes of Shanghai hospitals in 2011. The total physical activity was evaluated using the metabolic equivalent according to the Global Physical Activity Questionnaire. Among the participants, 38.5%, 32.3%, and 64.6% of the employees are inactive at work, commuting, and taking leisure time, respectively. Up to 41.8% of the men and 37.8% of the women (P = 0.012) are physically inactive. When the age and educational level are adjusted, male doctors and medical technicians show a higher percentage of physical inactivity than male workers in logistics (P = 0.001). Among females, employees who are working in second- and third-class hospitals show a higher proportion of physical inactivity than those who are working in community health care centers. Logistic regression analyses show that the odds ratios (ORs) of leisure-time physical inactivity associated with the intensity of physical activity at work are 2.259, 2.897, and 4.266 for men (P<0.001) and 2.456, 3.259, and 3.587 for women (P<0.001), respectively. The time during commuting activities is significantly associated with leisure-time physical inactivity in either sex (OR= 2.116 for men and 2.173 for women, P<0.001). Hospital employees, particularly doctors and medical technicians, show a higher proportion of physical inactivity than other inhabitants in Shanghai. The time and intensity of activity at work and commuting are associated with leisure-time activities.

关键词： prevalence     determination     employee     public hospital     cross-sectional study     physical inactivity    

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River Chief System (RCS): An experiment on cross-sectoral coordination of watershed governance

Longfei Wang, Jiaxin Tong, Yi Li

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1157-9

摘要：

The trans-regional characteristics of watershed governance produce more problems beyond the capacity of each individual water-related department, leading to the fragmentation of watershed management. The River Chief System (RCS) has experienced swift developments over the past decade in China by appointing the local government heads as river chiefs. RCS works efficiently in the short-term due to its superiority in the inclusion of clear responsibility, authority, and multi-sectoral collaboration. However, the characteristics of the authority-based vertical coordination of the hierarchical system remain unchanged, and therefore the problems of organizational logic and the responsibility dilemma still exist. Tasks including perfecting of laws, integrated watershed management, and public participation still need to be completed. RCS reflects the routine and characteristics of the migration of national governance, and as such provides new insights for other developing countries in the design of river management systems.

关键词： River Chief System     Watershed governance     Cross-sectoral coordination     Environmental protection    

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Air bearing center cross gap of neutron stress spectrometer sample table support system

Yang LI,Yunxin WU,Hai GONG,Xiaolei FENG

《机械工程前沿（英文）》 2016年 第11卷 第4期   页码 403-411 doi: 10.1007/s11465-016-0405-y

摘要：

A support system is the main load-bearing component of sample table for neutron stress spectrometer, and air bearing is an important element of a support system. The neutron stress spectrometer sample table was introduced, and the scheme for air bearing combination was selected. To study the performance of air bearing center cross gap, finite element models (FEMs) were established based on air motion and Reynolds equations, effects of air supply pressure, and gap parameters on the overturning moment and bearing capacity of air bearing center cross gap were analyzed. Results indicate that the width, depth, and height differences of the marble floor gap played important roles in the performance of the air bearing. When gap width is lesser than 1 mm and gap depth is lower than 0.4 mm, bearing capacity and overturning moment would vary rapidly with the variation of the width and depth. A gap height difference results in the bearing capacity dropping rapidly. The FEM results agree well with experimental results. Further, findings of the study could guide the design of the support system and marble floor.

关键词： neutron stress spectrometer     sample table     support system     air bearing     center cross gap     simulation     experiment    

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Characterization of hidden rules linking symptoms and selection of acupoint using an artificial neural

Won-Mo Jung, In-Soo Park, Ye-Seul Lee, Chang-Eop Kim, Hyangsook Lee, Dae-Hyun Hahm, Hi-Joon Park, Bo-Hyoung Jang, Younbyoung Chae

《医学前沿（英文）》 2019年 第13卷 第1期   页码 112-120 doi: 10.1007/s11684-017-0582-z

摘要： Comprehension of the medical diagnoses of doctors and treatment of diseases is important to understand the underlying principle in selecting appropriate acupoints. The pattern recognition process that pertains to symptoms and diseases and informs acupuncture treatment in a clinical setting was explored. A total of 232 clinical records were collected using a Charting Language program. The relationship between symptom information and selected acupoints was trained using an artificial neural network (ANN). A total of 11 hidden nodes with the highest average precision score were selected through a tenfold cross-validation. Our ANN model could predict the selected acupoints based on symptom and disease information with an average precision score of 0.865 (precision, 0.911; recall, 0.811). This model is a useful tool for diagnostic classification or pattern recognition and for the prediction and modeling of acupuncture treatment based on clinical data obtained in a real-world setting. The relationship between symptoms and selected acupoints could be systematically characterized through knowledge discovery processes, such as pattern identification.

关键词： acupuncture     indication     neural network     pattern identification     prediction    

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标题 作者 时间 类型 操作

Reaction and characterization of crosslinking hyperbranched poly (amine-ester) with succine anhydride

XIAO Ling, WEI Xiuzhen, ZHU Baoku

期刊论文

Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic

Jun Wei, Jianbo Zhao, Di Cai, Wenqiang Ren, Hui Cao, Tianwei Tan

期刊论文

Crosslinking acrylamide with EDTA-intercalated layered double hydroxide for enhanced recovery of Cr(VI) and Congo red: Adsorptive and mechanistic study

Jing Li, Haiqin Yu, Xue Zhang, Rixin Zhu, Liangguo Yan

期刊论文

The mechanisms linking adiposopathy to type 2 diabetes

null

期刊论文

利用两个自适应特征改进实体链接

张鸿彬,陈权,张伟文

期刊论文

A review on anammox process for the treatment of antibiotic-containing wastewater: Linking effects with

Jinjin Fu, Quan Zhang, Baocheng Huang, Niansi Fan, Rencun Jin

期刊论文

Semantics for linking data from 4D BIM to digital collaborative support

Calin BOJE, Veronika BOLSHAKOVA, Annie GUERRIERO, Sylvain KUBICKI, Gilles HALIN

期刊论文

Linking key intervention timings to rapid declining effective reproduction number to quantify lessons

Zhihang Peng, Wenyu Song, Zhongxing Ding, Quanquan Guan, Xu Yang, Qiaoqiao Xu, Xu Wang, Yankai Xia

期刊论文

化学工业绿色制造产业链接技术和发展方向探析

李瑾,胡山鹰,陈定江,宋晓旭,张群,樊炯明,李光耀,马淑杰,金涌

期刊论文

Linking elements to outcomes of knowledge transfer in the project environment: Current review and future

期刊论文

Methods and applications of DEA cross-efficiency: Review and future perspectives

Jie WU, Jiasen SUN, Liang LIANG

期刊论文

Prevalence and determinations of physical inactivity among public hospital employees in Shanghai, China: a cross-sectional

null

期刊论文

River Chief System (RCS): An experiment on cross-sectoral coordination of watershed governance

Longfei Wang, Jiaxin Tong, Yi Li

期刊论文

Air bearing center cross gap of neutron stress spectrometer sample table support system

Yang LI,Yunxin WU,Hai GONG,Xiaolei FENG

期刊论文

Characterization of hidden rules linking symptoms and selection of acupoint using an artificial neural

Won-Mo Jung, In-Soo Park, Ye-Seul Lee, Chang-Eop Kim, Hyangsook Lee, Dae-Hyun Hahm, Hi-Joon Park, Bo-Hyoung Jang, Younbyoung Chae

期刊论文