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Engineering >> 2017, Volume 3, Issue 3 doi: 10.1016/J.ENG.2017.03.005

Improved Oxygen Evolution Kinetics and Surface States Passivation of Ni-Bi Co-Catalyst for a Hematite Photoanode

a Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Received: 2017-01-19 Revised: 2017-03-18 Accepted: 2017-03-22 Available online: 2017-05-17

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Abstract

This paper describes the combinational surface kinetics enhancement and surface states passivation of nickel-borate (Ni-Bi) co-catalyst for a hematite (Fe2O3) photoanode. The Ni-Bi-modified Fe2O3 photoanode exhibits a cathodic onset potential shift of 230 mV and a 2.3-fold enhancement of the photocurrent at 1.23 V, versus the reversible hydrogen electrode (RHE). The borate (Bi) in the Ni-Bi film promotes the release of protons for the oxygen evolution reaction (OER).

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