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Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 1,   Pages 65-67 doi: 10.1007/s11705-009-0105-9

Abstract: Lithium is one of the most important light metals, which is widely used as raw materials for large-capacitySeawater, which contains 250 billion tons of lithium in total, has thus recently been noticed as a possibleresource of lithium.While, since the average concentration of lithium in seawater is quite low (0.17 mg·L ), enriching itThe adsorption method is the most prospective technology for increasing the concentration of lithium

Keywords： lithium     ion-sieve     seawater     spinel manganese oxide    

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Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 6,   Pages 749-758 doi: 10.1007/s11705-022-2261-0

Abstract: Since lithium iron phosphate cathode material does not contain high-value metals other than lithium,necessary to strike a balance between recovery efficiency and economic benefits in the recycling of waste lithiumdescribe a selective recovery process that can achieve economically efficient recovery and an acceptable lithiumAdjusting the acid concentration and amount of oxidant enables selective recovery of lithium ions.as acid concentration, acid dosage, amount of oxidant, and reaction temperature on the leaching of lithium

Keywords： lithium iron phosphate powder     stoichiometric number     selective leaching     lithium recovery    

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Capture of carbon dioxide over porous solid adsorbents lithium silicate, lithium aluminate and magnesium

P. V. Korake, A. G. Gaikwad

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 2,   Pages 215-226 doi: 10.1007/s11705-010-1012-9

Abstract: The capturing process for carbon dioxide over porous solid adsorbents such as lithium silicate, lithiumLithium silicate was prepared by the sol gel and solid fusion methods.The lithium silicate adsorbent was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopyThe capturing of carbon dioxide over lithium silicate, lithium aluminate, and magnesium aluminate wasThe effect of the addition of (promoter) sodium, potassium, and cesium in the lithium silicate adsorbent

Keywords： capturing CO2     lithium silicate     lithium aluminate     magnesium aluminate    

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Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 5,   Pages 755-763 doi: 10.1007/s11705-022-2137-3

Abstract: trifluoromethylsulfonyl)imide ([Hbet][Tf2N]) and Li2CO3 recovered from lithium-ion

Keywords： forward osmosis     lithium-ion battery     draw solution     lithium-containing wastewater     water treatment    

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Investigation of solution chemistry to enable efficient lithium recovery from low-concentration lithium-containing

Chunlong Zhao, Mingming He, Hongbin Cao, Xiaohong Zheng, Wenfang Gao, Yong Sun, He Zhao, Dalong Liu, Yanling Zhang, Zhi Sun

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 639-650 doi: 10.1007/s11705-019-1806-3

Abstract: In the production of lithium-ion batteries (LIBs) and recycling of spent LIBs, a large amount of low-concentrationlithium-containing wastewater (LCW) is generated.

Keywords： lithium-containing wastewater     lithium phosphate     precipitation     impurity ion    

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A review on the development of electrolytes for lithium-based batteries for low temperature applications

Frontiers in Energy 2023, Volume 17, Issue 1,   Pages 43-71 doi: 10.1007/s11708-022-0853-5

Abstract: The aerospace industry relies heavily on lithium-ion batteries in instrumentation such as satellitesdemands for greater energy storage rise, new materials also need to be adopted involving next generation lithium-ionWith these objectives in mind, tailoring of the electrolyte with higher-capacity materials such as lithiumreview paper highlights the progression of electrolyte research for low temperature performance of lithium-ion

Keywords： electrolyte     lithium-ion     low temperature     aerospace     solid-electrolyte interface    

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Primary nucleation of lithium carbonate

Yuzhu SUN, Xingfu SONG, Jin WANG, Yan LUO, Jianguo YU

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 1,   Pages 73-77 doi: 10.1007/s11705-009-0091-y

Abstract: A set of laser apparatus was used to explore the induction period and the primary nucleation of lithium

Keywords： lithium carbonate     primary nucleation     reactive crystallization     induction period    

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Continuous amino-functionalized University of Oslo 66 membranes as efficacious polysulfide barriers for lithium

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 2,   Pages 194-205 doi: 10.1007/s11705-022-2206-7

Abstract: The shuttle effect of soluble polysulfides is a serious problem impeding the development of lithium−sulfurcan act as ionic sieves and serve as barriers to polysulfides transport while allowing the passage of lithiumTherefore, lithium−sulfur batteries with this interlayer show a desirable initial capacity of 999.21

Keywords： lithium−sulfur batteries     amino-functionalized University of Oslo 66 membrane     polysulfide     interlayer    

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Preparation and characterization of lithium

Chang WANG,Yanlong ZHAI,Xi WANG,Ming ZENG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 4,   Pages 471-477 doi: 10.1007/s11705-014-1449-3

Abstract: Lithium -MnO ion-sieves were prepared from spinel LiMn O via treatment with nitric acid.effects of the calcination time and temperature on the preparation of the LiMn O precursor and the lithiumIn addition, the Li extraction ratio, the Mn dissolving ratio and the adsorption properties of the lithiumThe lithium ion-sieve had a high exchange capacity and was selective for Li .Specifically, at pH= 13, the ion exchange capacity of Li was 30.9 mg/g in 10 mmol/L LiCl solution and the lithium

Keywords： lithium ion-sieve     solid state reaction     adsorption     LiMn2O4    

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cladding LiMnO film electrode with enhanced stability for electrochemically selective extraction of lithium

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 2050-2060 doi: 10.1007/s11705-023-2343-7

Abstract: Reducing the dissolution of Mn from LiMn2O4 (LMO) and enhancing the stability of film electrodes are critical and challenging for Li+ ions selective extraction via electrochemically switched ion exchange technology. In this work, we prepared a nitrogen-doped carbon cladding LMO (C-N@LMO) by polymerization of polypyrrole and high-temperature annealing in the N2 gas to achieve the above purpose. The modified C-N@LMO film electrode exhibited lower Mn dissolution and better cyclic stability than the LMO film electrode. The dissolution ratio of Mn from the C-N@LMO film electrode decreased by 42% compared to the LMO film electrode after 10 cycles. The cladding layer not only acted as a protective layer but also functioned as a conductive shell, accelerating the migration rate of Li+ ions. The intercalation equilibrium time of the C-N@LMO film electrode reached within an hour during the extraction of Li+ ions, which was 33% less compared to the pure LMO film electrode. Meanwhile, the C-N@LMO film electrode retained evident selectivity toward Li+ ions, and the separation factor was 118.38 for Li+ toward Mg2+ in simulated brine. Therefore, the C-N@LMO film electrode would be a promising candidate for the recovery of Li+ ions from salt lakes.

Keywords： LiMn2O4     lithium extraction     surface coating     cyclic stability     Mn dissolution    

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Recent Advances in Energy Chemical Engineering of Next-Generation Lithium Batteries Review

Xue-Qiang Zhang, Chen-Zi Zhao, Jia-Qi Huang, Qiang Zhang

Engineering 2018, Volume 4, Issue 6,   Pages 831-847 doi: 10.1016/j.eng.2018.10.008

Abstract:

Rechargeable lithium-ion batteries (LIBs) afford a profound impact on our modern daily life.Next-generation lithium (Li) batteries, which employ Li metal as the anode and intercalation or conversionKey challenges and recent progress in lithium-ion, lithium–sulfur, and lithium–oxygen batteries

Keywords： Lithium-ion batteries     Lithium–sulfur batteries     Lithium–oxygen batteries     Lithium metal     Solid-state batteries    

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Localized high-concentration electrolytes for lithium metal batteries: progress and prospect

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1354-1371 doi: 10.1007/s11705-022-2286-4

Abstract: promising anode materials with an ultrahigh specific capacity and extremely low electrode potential, lithiumlimited Coulombic efficiency and potential safety risks severely hinder the practical applications of lithiummetal batteries due to the inevitable growth of lithium dendrites and poor interface stability., we provide an overview of the recent developments of localized high-concentration electrolytes in lithiumthe voltage window of electrolytes, enhance safety, and render low-temperature operation for robust lithium

Keywords： high-concentration electrolyte     localized high-concentration electrolyte     lithium metal battery     solid    

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Fabrication of layered structure VS anchor in 3D graphene aerogels as a new cathode material for lithium

Frontiers in Energy 2019, Volume 13, Issue 3,   Pages 597-602 doi: doi:10.1007/s11708-018-0576-9

Abstract: more and more attention for its high theoretical capacity (449 mAh/g with 3e− transfer) in lithium

Keywords： VS4     graphene aerogels     cathode     lithium storage    

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Development of barium@alginate adsorbents for sulfate removal in lithium refining

Lisa Xu, Kaifei Chen, George Q. Chen, Sandra E. Kentish, Gang (Kevin) Li

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 1,   Pages 198-207 doi: 10.1007/s11705-020-1968-z

Abstract: The demand for lithium has been steadily growing in recent years due to the boom of electric cars.High purity lithium is commonly used in the manufacture of battery grade lithium electrolyte.Sulfate residuals originating from acid leaching of lithium ores must be limited to below 20 mg·L duringsecondary barium contamination, these Ca/Ba@alginate adsorbents will find applications in ultra-refining of lithium

Keywords： barium@alginate     microcapsules     dropwise injection     sulfate removal     lithium    

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coated LiNi0.5Mn1.5O4 as the high performance cathode materials for lithium-ion

Shifeng YANG, Wenfeng REN, Jian CHEN

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 374-382 doi: 10.1007/s11708-017-0494-2

Abstract: preparation of Li SiO -coated LiNi Mn O materials by sintering the SiO -coated nickel-manganese oxides with lithiumWhen used as the cathode materials for lithium-ion batteries, the Li SiO -coated LiNi Mn O samples deliver

Keywords： lithium-ion batteries     cathode material     LiNi0.5Mn1.5O4     lithium-ion conductor    

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Title Author Date Type Operation

Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

Journal Article

Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

Journal Article

Capture of carbon dioxide over porous solid adsorbents lithium silicate, lithium aluminate and magnesium

P. V. Korake, A. G. Gaikwad

Journal Article

Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery

Journal Article

Investigation of solution chemistry to enable efficient lithium recovery from low-concentration lithium-containing

Chunlong Zhao, Mingming He, Hongbin Cao, Xiaohong Zheng, Wenfang Gao, Yong Sun, He Zhao, Dalong Liu, Yanling Zhang, Zhi Sun

Journal Article

A review on the development of electrolytes for lithium-based batteries for low temperature applications

Journal Article

Primary nucleation of lithium carbonate

Yuzhu SUN, Xingfu SONG, Jin WANG, Yan LUO, Jianguo YU

Journal Article

Continuous amino-functionalized University of Oslo 66 membranes as efficacious polysulfide barriers for lithium

Journal Article

Preparation and characterization of lithium

Chang WANG,Yanlong ZHAI,Xi WANG,Ming ZENG

Journal Article

cladding LiMnO film electrode with enhanced stability for electrochemically selective extraction of lithium

Journal Article

Recent Advances in Energy Chemical Engineering of Next-Generation Lithium Batteries

Xue-Qiang Zhang, Chen-Zi Zhao, Jia-Qi Huang, Qiang Zhang

Journal Article

Localized high-concentration electrolytes for lithium metal batteries: progress and prospect

Journal Article

Fabrication of layered structure VS anchor in 3D graphene aerogels as a new cathode material for lithium

Journal Article

Development of barium@alginate adsorbents for sulfate removal in lithium refining

Lisa Xu, Kaifei Chen, George Q. Chen, Sandra E. Kentish, Gang (Kevin) Li

Journal Article

coated LiNi0.5Mn1.5O4 as the high performance cathode materials for lithium-ion

Shifeng YANG, Wenfeng REN, Jian CHEN

Journal Article