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Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 12, doi: 10.1007/s11783-022-1589-5
● A series of mixed-LOFs and portable LOF-fibers were synthesized.
Keywords: Antibiotics Sensor Luminescence Lanthanide-organic frameworks
Xuewen Yi, Zhanqi Gao, Lanhua Liu, Qian Zhu, Guanjiu Hu, Xiaohong Zhou
Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 6, doi: 10.1007/s11783-020-1288-z
Keywords: Bioluminescent bacteria Acute toxicity Pearson correlation analysis Drinking water source Vibrio fischeri
Photoluminescent properties of Sb
Fushan WEN, Lingling SUN, Jinhyeok KIM
Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4, Pages 429-434 doi: 10.1007/s11705-011-1138-4
Keywords: hydrothermal solid-state luminescent borate
Aramballi J. Savyasachi, David F. Caffrey, Kevin Byrne, Gerard Tobin, Bruno D'Agostino, Wolfgang Schmitt, Thorfinnur Gunnlaugsson
Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 1, Pages 171-184 doi: 10.1007/s11705-018-1762-3
The europium heptadentate coordinatively unsaturated (Eu(III)) and the terbium (Tb(III)) 1,4,7,10-tetraazacyclododecane (cyclen) complexes 1 and 2 were used in conjunction with ligand 3 (1,3,5-benzene-trisethynylbenzoate) to form the supramolecular self-assembly structures 4 and 5; this being investigated in both the solid and the solution state. The resulting self-assemblies gave rise to metal centered emission (both in the solid and solution) upon excitation of 3, confirming its role as a sensitizing antenna. Drop-cased examples of ligand 3, and the solid forms of 4 and 5, formed from both organic and mixture of organic-aqueous solutions, were analyzed using Scanning Electron Microscopy, which showed significant changes in morphology; the ligand giving rise to one dimensional structures, while both 4 and 5 formed amorphous materials that were highly dense solid networks containing nanoporous features. The surface area (216 and 119 m2·g−1 for 4 and 5 respectively) and the ability of these porous materials to capture and store gases such as N2 investigated at 77 K. The self-assembly formation was also investigated in diluted solution by monitoring the various photophysical properties of 3–5. This demonstrated that the most stable structures were that consisting of a single antennae 3 and three complexes of 1 or 2 (e.g., 4 and 5) in solution. By monitoring the excited state lifetimes of the Eu(III) and Tb(III) ions in H2O and D2O respectively, we showed that their hydration states (the q-value) changed from ~2 to 0, upon formation of the assemblies, indicating that the three benzoates of 3 coordinated directly to the each of the three lanthanide centers. Finally we demonstrate that this hierarchically porous materials can be used for the sensing of organic solvents as the emission is highly depended on the solvent environment; the lanthanide emission being quenched in the presence of acetonitrile and THF, but greatly enhanced in the presence of methanol.
Keywords: self-assembly supramolecular chemistry lanthanides Eu(III) and Tb(III) complexes luminescence metallostars
Near-field radiative thermoelectric energy converters: a review
Eric TERVO, Elham BAGHERISERESHKI, Zhuomin ZHANG
Frontiers in Energy 2018, Volume 12, Issue 1, Pages 5-21 doi: 10.1007/s11708-017-0517-z
Keywords: energy conversion systems luminescent refrigeration near-field radiation thermophotovoltaic thermoradiative
Title Author Date Type Operation
Decoding and quantitative detection of antibiotics by a luminescent mixed-lanthanide-organic framework
Journal Article
Acute toxicity assessment of drinking water source with luminescent bacteria: Impact of environmental
Xuewen Yi, Zhanqi Gao, Lanhua Liu, Qian Zhu, Guanjiu Hu, Xiaohong Zhou
Journal Article
Self-assembled bright luminescent hierarchical materials from a tripodal benzoate antenna and heptadentate
Aramballi J. Savyasachi, David F. Caffrey, Kevin Byrne, Gerard Tobin, Bruno D'Agostino, Wolfgang Schmitt, Thorfinnur Gunnlaugsson
Journal Article