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Jian-Feng Chen
Engineering 2017, Volume 3, Issue 3, Pages 283-284 doi: 10.1016/J.ENG.2017.03.025
An Overview of Metal–Organic Frameworks for Green Chemical Engineering Review
Xiang-Jing Kong, Jian-Rong Li
Engineering 2021, Volume 7, Issue 8, Pages 1115-1139 doi: 10.1016/j.eng.2021.07.001
Given the current global energy and environmental issues resulting from the fast pace of industrialization, the discovery of new functional materials has become increasingly imperative in order to advance science and technology and address the associated challenges. The boom in metal–organic frameworks (MOFs) and MOF-derived materials in recent years has stimulated profound interest in exploring their structures and applications. The preparation, characterization, and processing of MOF materials are the basis of their full engagement in industrial implementation. With intensive research in these topics, it is time to promote the practical utilization of MOFs on an industrial scale, such as for green chemical engineering, by taking advantage of their superior functions. Many famous MOFs have already demonstrated superiority over traditional materials in solving real-world problems. This review starts with the basic concept of MOF chemistry and ends with a discussion of the industrial production and exploitation of MOFs in several fields. Its goal is to provide a general scope of application to inspire MOF researchers to convert their focus on academic research to one on practical applications. After the obstacles of cost, scale-up preparation, processability, and stability have been overcome, MOFs and MOF-based devices will gradually enter the factory, become a part of our daily lives, and help to create a future based on green production and green living.
Keywords： Metal-organic frameworks (MOFs) Application Green chemical engineering
Green Chemical Engineering for a Better Life
Jian-Feng Chen
Engineering 2017, Volume 3, Issue 3, Pages 279-279 doi: 10.1016/J.ENG.2017.03.028
Green Production Technology of the Monomer of Nylon-6: Caprolactam Review
Baoning Zong, Bin Sun, Shibiao Cheng, Xuhong Mu, Keyong Yang, Junqi Zhao, Xiaoxin Zhang, Wei Wu
Engineering 2017, Volume 3, Issue 3, Pages 379-384 doi: 10.1016/J.ENG.2017.03.003
After two decades’ endeavor, the Research Institute of Petroleum Processing (RIPP) has successfully developed a green caprolactam (CPL) production technology. This technology is based on the integration of titanium silicate (TS)-1 zeolite with the slurry-bed reactor for the ammoximation of cyclohexanone, the integration of silicalite-1 zeolite with the moving-bed reactor for the gas-phase rearrangement of cyclohexanone oxime, and the integration of an amorphous nickel (Ni) catalyst with the magnetically stabilized bed reactor for the purification of caprolactam. The world’s first industrial plant based on this green CPL production technology has been built and possesses a capacity of 200 kt·a−1. Compared with existing technologies, the plant investment is pronouncedly reduced, and the nitrogen (N) atom utilization is drastically improved. The waste emission is reduced significantly; for example, no ammonium sulfate byproduct is produced. As a result, the price difference between CPL and benzene drops. In 2015, the capacity of the green CPL production technology reached 3 × 106 t·a−1, making China the world’s largest CPL producer, with a global market share exceeding 50%.
Keywords： Green chemistry Green engineering Caprolactam Production technology
Sinopec Dalian（Fushun） Research Institute of Petroleum and Petochemicals
Strategic Study of CAE 2001, Volume 3, Issue 6, Pages 93-94
The Development of Petrochemical Industry and Catalytic Technology
Cao Xianghong
Strategic Study of CAE 1999, Volume 1, Issue 3, Pages 11-15
Catalytic technology is the basis of petrochemical industry. In this thesis, the technological progress of petrochemical enterprises promoted by the advance of catalytic technology was discussed, with examples .Meanwhile, petrochemical industry also raises a series of new subjects for the development of catalytic technology ： the technical revamping of existing plants require catalyst with higher activity ; the cleaning production process requires environmental friendly catalyst; the product structure adjustment requires excellent adaptability of catalyst; saving energy and lowering consumption and cost, as well as strengthening product competitiveness require continuous reduction of catalyst production cost and improvement of catalyst life, conversion rate, selectivity etc.
Keywords： petrochemical industry catalytic technology
Chemical, Metallurgy & Materials Engineering Front 2018
Chemical, Metallurgy & Materials Engineering Project Team
Engineering Fronts 2018, Volume 2, Issue 1, Pages 55-78
Design and Fabrication of Ceramic Catalytic Membrane Reactors for Green Chemical Engineering Applications Feature Article
Guangru Zhang, Wanqin Jin, Nanping Xu
Engineering 2018, Volume 4, Issue 6, Pages 848-860 doi: 10.1016/j.eng.2017.05.001
Catalytic membrane reactors (CMRs), which synergistically carry out separations and reactions, are expected to become a green and sustainable technology in chemical engineering. The use of ceramic membranes in CMRs is being widely considered because it permits reactions and separations to be carried out under harsh conditions in terms of both temperature and the chemical environment. This article presents the two most important types of CMRs: those based on dense mixed-conducting membranes for gas separation, and those based on porous ceramic membranes for heterogeneous catalytic processes. New developments in and innovative uses of both types of CMRs over the last decade are presented, along with an overview of our recent work in this field. Membrane reactor design, fabrication, and applications related to energy and environmental areas are highlighted. First, the configuration of membranes and membrane reactors are introduced for each of type of membrane reactor. Next, taking typical catalytic reactions as model systems, the design and optimization of CMRs are illustrated. Finally, challenges and difficulties in the process of industrializing the two types of CMRs are addressed, and a view of the future is outlined.
Keywords： Dense ceramic membrane Porous ceramic membrane Catalytic membrane reactor Gas separation Heterogeneous catalysis
Developing coal chemical industry and ensuring national energy security
Xu Yaowu,Xu Liwei,Lu Yongjun
Strategic Study of CAE 2011, Volume 13, Issue 11, Pages 20-25
This article proposes the way of thinking and viewpoints for implementing the strategy of coal replacing oil in view of actual situation of energy structure in China by means of explanation and analysis on theory and practice, expounding the necessity and significance of implementing the strategy of coal chemical industry replacing oil chemical industry from several respects, summarizes the technical process and market situation of several main coal chemical industry products, and makes comparison and analysis on their competitiveness. Based on this, this article explicitly proposes the detailed ideas and suggestions for implementing the strategy of coal replacing oil. At the same time, the article makes analysis and explanation on several focus issues such as water resource and carbon emission that attract much attention during the development of coal chemical industry, and proposes its own viewpoints.
Keywords： coal chemical industry replacement oil chemical industry strategy energy security advice
The Research Group of Chemical, Metallurgical, and Material Fields
Strategic Study of CAE 2018, Volume 20, Issue 6, Pages 34-41 doi: 10.15302/J-SSCAE-2018.06.006
The chemical, metallurgical and material industries re-process natural resources to produce materials, chemicals, and secondary energies necessary for human life, thereby providing an important material basis for social development and economic construction. This paper reviews the recognized disruptive technologies in the history of chemical, metallurgical, and material industries, and analyzes the impact of such technologies on people's daily lives, the progress of human society, and the disruption of traditional technologies. According to vision driving, problem orientation, and the world technology development trend, we forecast the future sustainable science development models, which are efficient, safe, energy-saving, and environment-friendly, in the chemical, metallurgical, and material industries, and predict the impacts of possible disruptive technologies on national economy and people’s livelihood. The slurry bed hydro-conversion technology, the metallurgical manufacturing process function expansion technology, grapheme, and other disruptive technologies are proposed. Finally, relevant policies and suggestions are put forward for the cultivation, development, and environment of disruptive technologies.
Keywords： chemical industry metallurgy material disruptive technology national economy and people’s livelihood
Study on the trinity strategy of coal chemical industry park
Wang Yingluo
Strategic Study of CAE 2008, Volume 10, Issue 12, Pages 39-44
The National Eleventh Five-Year Plan for National Economic and Social Development of China clearly points out that China will vigorously develop coal chemical industry, promote in-depth processing and utilization of coal, develop circular economy, conserve resource, promote clean production and reduce the impact of development on environment and ecology. This paper firstly discussed the trinity strategy of "Coal mining – Coal chemical industry – Coal chemical industry equipment manufacturing" , then discussed the strategic meaning, feasibility and economic benefit of the trinity strategy,finally proposed a kind of circular economy development mode of coal chemical industry park, including the implementation steps of trinity strategy, the operation and management mode of implementing circular economic industry park.
Keywords： coal mining coal chemical industry equipment manufacturing
Chemical, Metallurgical, and Materials Engineering Front 2023
Chemical, Metallurgical, and Materials Engineering Project Team
Engineering Fronts 2023, Volume 7, Issue 1, Pages 67-93
Title Author Date Type Operation
An Overview of Metal–Organic Frameworks for Green Chemical Engineering
Xiang-Jing Kong, Jian-Rong Li
Journal Article
Green Production Technology of the Monomer of Nylon-6: Caprolactam
Baoning Zong, Bin Sun, Shibiao Cheng, Xuhong Mu, Keyong Yang, Junqi Zhao, Xiaoxin Zhang, Wei Wu
Journal Article
2020石油化工与绿色发展国际学术会议
17 Apr 2020
Conference Information
2020绿色化工与环境科学国际学术会议(ICGCES 2020)
12 Jun 2020
Conference Information
Chemical, Metallurgy & Materials Engineering Front 2018
Chemical, Metallurgy & Materials Engineering Project Team
Journal Article
Design and Fabrication of Ceramic Catalytic Membrane Reactors for Green Chemical Engineering Applications
Guangru Zhang, Wanqin Jin, Nanping Xu
Journal Article
Developing coal chemical industry and ensuring national energy security
Xu Yaowu,Xu Liwei,Lu Yongjun
Journal Article
Preliminary Study on Impact of Disruptive Technologies in Chemical, Metallurgical, and Material Fields
The Research Group of Chemical, Metallurgical, and Material Fields
Journal Article
Chemical, Metallurgical, and Materials Engineering Front 2023
Chemical, Metallurgical, and Materials Engineering Project Team
Journal Article
Clayton Radke : Molecular Thermodynamics of Polymer-Electrolyte Fuel-Cell（PEFC）Membranes（2019.5.24）
22 Apr 2021
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