Experimental study of the influence of acid wash on cellulose pyrolysis

2007年第1卷第1期

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《化学科学与工程前沿（英文）》 >> 2007年第1卷第1期 doi: 10.1007/s11705-007-0007-7

Experimental study of the influence of acid wash on cellulose pyrolysis

1.State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China; 2.Electric Power College, South China University of Technology, Guangzhou 510640, China;

发布日期： 2007-03-05

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摘要

The analysis of microstructure and polymerization degree showed that acid wash altered the cellulose morphology and decreased the polymerization degree significantly. A series of experiments were done to study the effect of acid wash on cellulose rapid pyrolysis. Experimental results showed that under acid pretreatment, the yield of bio-oil decreased while the production of gas and char increased. With an increase in acid concentration, this trend would be further enhanced. Sulphuric acid limited the formation of bio-oil more effectively than hydrochloric acid and phosphoric acid. According to the GC-MS analysis of bio-oil, high-concentration acid wash restrained the formation of levoglucosan by catalyzing dehydration process and cross linking reaction.