期刊首页 优先出版 当期阅读 过刊浏览 作者中心 关于期刊 English

2015年 第9卷 第3期

摘要

关键词

相关研究

回顶部

《化学科学与工程前沿（英文）》 >> 2015年 第9卷 第3期 doi: 10.1007/s11705-015-1530-6

Fluoroalcohol-mediated reductive iodonio-Claisen rearrangement: Synthesis of complex

Department of Chemistry and Biochemistry and School of Green Chemistry and Engineering, The University of Toledo, Toledo, OH 43606, USA

录用日期： 2015-09-10 发布日期： 2015-09-30
HTML13 PDF 5 收藏 0

下一篇 上一篇

摘要

Reductive iodonio-Claisen rearrangement (RICR) involving -iodanes and allyl or substituted-allyl silanes in fluoroalcohols, such as 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) and 2,2,2-trifluoroethanol (TFE), was studied for the synthesis of complex -allyl or substituted-allyl iodoarenes. In comparison to the previously reported condition involving boron trifluoride diethyl etherate, the RICR mediated by fluoroalcohols was found to proceed more effectively. The resulting complex -allyl iodoarenes are useful synthetic intermediates and can be readily converted to various heterocyclic compounds.

相关研究