《能源前沿(英文)》
>> 2021年
第15卷
第1期
doi:
10.1007/s11708-021-0735-2
RESEARCH ARTICLE
Enhanced photocatalytic water splitting with surface defective SrTiO
. Institute of Physical Chemistry, University of Hamburg, Grindelallee 117, 20146 Hamburg, Germany.. Research Center for Combustion and Environment Technology, Shanghai Jiao Tong University, Shanghai 200240, China
录用日期:
2021-03-30
发布日期:
2021-03-30
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摘要
Surface reconstructed SrTiO nanocrystals were synthesized by a thermal treatment process in presence of NaBH and SrTiO nanocrystals. The surface reconstruction of SrTiO nanocrystals is attributed to the introduction of surface oxygen vacancies or Ti sites (such as Ti and Ti ) during the hydrogenation treatment process. The light absorption and the charge transfer ability of SrTiO nanocrystals are simultaneously enhanced due to surface oxygen vacancies or Ti sites (such as Ti and Ti ), which are beneficial to photocatalytic water splitting. Meanwhile, these defects also change the redox potential of the photocatalysts. Since there existed a synergistic effect between the three, the ratio of hydrogen to oxygen production was also regulated.