摘要
Experiments have been carried out to study the sorption of Benzo(a)pyrene(Bap) on sediment particles from the Yellow River using a batch equilibration technique. Effects of particle size on the adsorption and partition of Bap were investigated with the particle content of 3 g/L. Several significant results were obtained from the study. (1) Isotherms of Bap could be fitted with the dual adsorption-partition model under different particle sizes, and the measured value of the adsorption and partition was in agreement with the theoretical value of the dual adsorption-partition model. (2) When the particle diameter was "e 0.025 mm, the adsorption was predominant in the sorption of Bap, which accounted for 68.7% 82.4% of the sorption. For the particles with the size of 0.007 mm "e < 0.025 mm, the adsorption was predominant when the equilibrium concentration of Bap was 0 8.87 μg/L in the water phase; and the partition was predominant when the equilibrium concentration of Bap was higher than 8.87 μg/L in the water phase. When the particle diameter was <0.007 mm, the partition was predominant. (3) On the point of particle size, the contribution of adsorption to sorption followed the order: "e0.025 mm > 0.007 mm "d<0.025 mm > <0.007 mm . (4) The partition coefficients of Bap in solids with different particle sizes were linearly correlated with the organic content, and the K of Bap was about 1.26 x 10 (L/kg).