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《环境科学与工程前沿(英文)》 >> 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1139-y

Ozonation as an efficient pretreatment method to alleviate reverse osmosis membrane fouling caused by complexes of humic acid and calcium ion

1. Environmental Simulation and Pollution Control State Key Joint Laboratory, State Environmental Protection Key Laboratory of Microorganism Application and Risk Control (SMARC), School of Environment, Tsinghua University, Beijing 100084, China
2. Collaborative Innovation Center for Advanced Nuclear Energy Technology, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
3. Kurita Water Industries Ltd., Nakano-ku, Tokyo 164-0001, Japan
4. Shenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute, Shenzhen 518055, China

发布日期: 2019-05-15

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摘要

Humic acids (HA) didn’t cause obvious reverse osmosis (RO) membrane fouling in 45 h.

Osmotic pressure (NaCl) affected slightly the RO membrane fouling behavior of HA.

Ca2+ promoted aggregation of HA molecules and thus aggravated RO membrane fouling.

Ozonation eliminated the effect of Ca2+ on the RO membrane fouling behavior of HA.

The change of the structure of HA was related to its membrane fouling behavior.

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