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Do right PLS and do PLS right: A critical review of the application of PLS-SEM in construction management

Ningshuang ZENG, Yan LIU, Pan GONG, Marcel HERTOGH, Markus KÖNIG

《工程管理前沿（英文）》 2021年 第8卷 第3期   页码 356-369 doi: 10.1007/s42524-021-0153-5

摘要： Partial least squares structural equation modeling (PLS-SEM) is a modern multivariate analysis technique with a demonstrated ability to estimate theoretically established cause-effect relationship models. This technique has been increasingly adopted in construction management research over the last two decades. Accordingly, a critical review of studies adopting PLS-SEM appears to be a timely and valuable endeavor. This paper offers a critical review of 139 articles that applied PLS-SEM from 2002 to 2019. Results show that the misuse of PLS-SEM can be avoided. Critical issues related to the application of PLS-SEM, research design, model development, and model evaluation are discussed in detail. This paper is the first to highlight the use and misuse of PLS-SEM in the construction management area and provides recommendations to facilitate the future application of PLS-SEM in this field.

关键词： PLS     SEM     construction management     literature review     misuse    

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Lignin-based polymer with high phenolic hydroxyl group content prepared by the alkyl chain bridging method and applied as a dopant of PEDOT

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1075-1084 doi: 10.1007/s11705-022-2272-x

摘要： Inspired by the importance of the phenolic group to the electron transporting property of hole transport materials, phenolic hydroxyl groups were introduced in lignosulfonate (LS) via the alkyl chain bridging method to prepare phenolated-lignosulfonate (PLS). The results showed that the phenolic group was boosted from 0.81 mmol∙g–1 of LS to 1.19 mmol∙g–1 of PLS. The electrochemical property results showed two oxidation peaks in the cyclic voltammogram (CV) curve of PLS, and the oxidation potential of the PLS-modified electrode decreased by 0.5 eV compared with that of LS. This result indicates that PLS is more easily oxidized than LS. Based on the excellent electron transporting property of PLS, PLS was applied as a dopant in poly(3,4-ethylenedioxythiophene) (PEDOT, called PEDOT:PLSs). PLS showed excellent dispersion properties for PEDOT. Moreover, the transmittance measurement results showed that the transmittance of PEDOT:PLSs exceeded 85% in the range of 300–800 nm. The CV results showed that the energy levels of PEDOT:PLSs could be flexibly adjusted by PLS amounts. The results indicate that the phenolic hydroxyl group of lignin can be easily boosted by the alkyl chain bridging method, and phenolated lignin-based polymers may have promising potential as dopants of PEDOT to produce hole transporting materials for different organic photovoltaic devices.

关键词： lignosulfonate     phenolic group     PEDOT:PLS     hole extract layer     energy level    

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Comparison of optimal capacitor placement methods in radial distribution system with load growth and ZIP load model

Veera Venkata Satya Naryana MURTY, Ashwani KUMAR

《能源前沿（英文）》 2013年 第7卷 第2期   页码 197-213 doi: 10.1007/s11708-013-0249-7

摘要： In this paper, a combined power loss sensitivity (PLS) index-based approach is proposed to determine the optimal location of the capacitors in the radial distribution system (RDS) based on the real and reactive combined loss sensitivity index, as capacitor placement not only reduces real power loss with voltage profile improvement but also reduces reactive power loss due to the reactive power compensation in the network. The results have been obtained with the existing methods of power loss index (PLI) and index vector (IV) method for comparison. Besides, the optimal placement has been obtained with the proposed method as well as existing methods and the total kVar support has been obtained. In addition, the results of net cost savings for the 10-, 34-, and 69-bus systems are obtained for comparison. Moreover, the results have been obtained for a large system of 85 buses to validate the results with combined sensitivity based approach. Furthermore, the load growth factor has been considered in the study which is essential for the planning and expansion of the existing systems, whereas the impact of the realistic load model as ZIP load model has been considered for the study of all the systems.

关键词： load growth     load models     reactive power compensation     radial distribution system     power loss index (PLI)     power loss sensitivity (PLS)     index vector (IV)    

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Real time monitoring of bioreactor mAb IgG3 cell culture process dynamics via Fourier transform infrared spectroscopy: Implications for enabling cell culture process analytical technology? ?

Huiquan Wu, Erik Read, Maury White, Brittany Chavez, Kurt Brorson, Cyrus Agarabi, Mansoor Khan

《化学科学与工程前沿（英文）》 2015年 第9卷 第3期   页码 386-406 doi: 10.1007/s11705-015-1533-3

摘要： Compared to small molecule process analytical technology (PAT) applications, biotechnology product PAT applications have certain unique challenges and opportunities. Understanding process dynamics of bioreactor cell culture process is essential to establish an appropriate process control strategy for biotechnology product PAT applications. Inline spectroscopic techniques for real time monitoring of bioreactor cell culture process have the distinct potential to develop PAT approaches in manufacturing biotechnology drug products. However, the use of inline Fourier transform infrared (FTIR) spectroscopic techniques for bioreactor cell culture process monitoring has not been reported. In this work, real time inline FTIR Spectroscopy was applied to a lab scale bioreactor mAb IgG3 cell culture fluid biomolecular dynamic model. The technical feasibility of using FTIR Spectroscopy for real time tracking and monitoring four key cell culture metabolites (including glucose, glutamine, lactate, and ammonia) and protein yield at increasing levels of complexity (simple binary system, fully formulated media, actual bioreactor cell culture process) was evaluated via a stepwise approach. The FTIR fingerprints of the key metabolites were identified. The multivariate partial least squares (PLS) calibration models were established to correlate the process FTIR spectra with the concentrations of key metabolites and protein yield of in-process samples, either individually for each metabolite and protein or globally for all four metabolites simultaneously. Applying the 2 derivative pre-processing algorithm to the FTIR spectra helps to reduce the number of PLS latent variables needed significantly and thus simplify the interpretation of the PLS models. The validated PLS models show promise in predicting the concentration profiles of glucose, glutamine, lactate, and ammonia and protein yield over the course of the bioreactor cell culture process. Therefore, this work demonstrated the technical feasibility of real time monitoring of the bioreactor cell culture process via FTIR spectroscopy. Its implications for enabling cell culture PAT were discussed.

关键词： process analytical technology (PAT)     Fourier-transform infrared (FTIR) spectroscopy     partial least squares (PLS) regression     mouse IgG3     bioreactor cell culture process     real time process monitoring    

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标题 作者 时间 类型 操作

Do right PLS and do PLS right: A critical review of the application of PLS-SEM in construction management

Ningshuang ZENG, Yan LIU, Pan GONG, Marcel HERTOGH, Markus KÖNIG

期刊论文

Lignin-based polymer with high phenolic hydroxyl group content prepared by the alkyl chain bridging method and applied as a dopant of PEDOT

期刊论文

Comparison of optimal capacitor placement methods in radial distribution system with load growth and ZIP load model

Veera Venkata Satya Naryana MURTY, Ashwani KUMAR

期刊论文

Real time monitoring of bioreactor mAb IgG3 cell culture process dynamics via Fourier transform infrared spectroscopy: Implications for enabling cell culture process analytical technology? ?

Huiquan Wu, Erik Read, Maury White, Brittany Chavez, Kurt Brorson, Cyrus Agarabi, Mansoor Khan

期刊论文