
南海富碳天然气直接利用技术发展研究
Development of Direct Utilization Technology for CO2-Rich Natural Gas in South China Sea
我国南海富碳天然气具有 CO2 含量高的特点,高效开发和精准利用南海富碳天然气资源,有助于积极应对气候变化,实现“碳达峰、碳中和”目标。本文分析了南海富碳天然气直接利用的需求和价值,概括了富碳天然气直接利用的发展现状;重点论述了富碳天然气 CO2-CH4 干重整技术、富碳天然气制甲醇一体化技术、富碳天然气 CO2 加氢制液体燃料技术、富碳天然气直接制精细化工品技术等的实施过程与应用特征。研究建议,南海富碳天然气资源有其特殊性,应加强研究并实施重点攻关,建立海洋富碳天然气综合利用技术工程化平台,与非化石能源风能、太阳能及核能紧密融合发展,推进南海富碳天然气产业的可持续发展;针对性布局南海富碳天然气产业,加强富碳天然气的开发与利用力度,尽快实现转型升级;建立“产学研用”战略联盟,保障产业与技术合作需求。
The natural gas in the South China Sea is characterized by a high CO2 content. The efficient development and precise utilization of CO2-rich natural gas resources in the South China Sea can help tackle climate change and achieve the goals of peaking carbon dioxide emissions and achieving carbon neutrality. In this article, we analyze the demand for and summarize the development status of the direct utilization of CO2-rich natural gas in the South China Sea. Subsequently, we focus on several key technologies and their application, including CO2-CH4 dry reforming, integration of CO2-rich natural gas to methanol, liquid fuel production through CO2 hydrogenation, and direct production of fine chemicals. We suggest that research on the CO2-rich natural gas resources in the South China Sea should be strengthened, an engineering platform for the comprehensive utilization of marine CO2-rich natural gas resources should be established, and the CO2-rich natural gas should be integrated with wind, solar, and nuclear energies to promote the sustainable development of the industry. Furthermore, the CO2-rich natural gas industry should be upgraded in the South China Sea, and a strategic alliance among production, education, research, and application should be established.
南海 / 富碳天然气 / 干重整 / CO2 加氢 / 液体燃料 / 精细化工
South China Sea / CO2-rich natural gas / dry reforming / CO2 hydrogenation / liquid fuel / fine chemicals
[1] |
Wu Q. Study on the technology clusters for direct utilization of carbon-rich natural gas and construction of hybrid system for energy and chemicals production [J]. China Petroleum Processing & Petrochemical Technology, 2020, 22(2): 1–9.
|
[2] |
付彧, 孙予罕. CH4-CO2重整技术的挑战与展望 [J]. 中国科学: 化学, 2020, 50(7): 816–831. Fu Y, Sun Y H. CH4-CO2 reforming: Challenges and outlook [J]. SCIENTIA SINICA Chimica, 2020, 50(7): 816–831.
|
[3] |
赵绍民, 王磊, 邵立红. 合成气成分对甲醇合成生产的影响 [J]. 煤化工, 2003, 31(2): 41–44. Zhao S M, Wang L, Shao L H. Effect of synthesis gas compositions on the methanol production [J]. Coal Chemical Industry, 2003, 31(2): 41–44.
|
[4] |
高鹏, 崔勖, 钟良枢, 等. CO/CO2加氢高选择性合成化学品和液 体燃料 [J]. 化工进展, 2019, 38(1): 183–195. Gao P, Cui X, Zhong L S, et al. CO/CO2 hydrogenation to chemicals and liquid fuels with high selectivity [J]. Chemical Industry and Engineering Process, 2019, 38 (1): 183–195.
|
[5] |
Chen Q Q, Wang D F, Gu Y, et al. Techno-economic evaluation of CO2-rich natural gas dry reforming for linear alpha olefins production [J]. Energy Conversion and Management, 2020, 205: 1–12.
|
[6] |
Li S Q, Fu Y, Kong W B, et al. Dually confined Ni nanoparticles by room-temperature degradation of AlN for dry reforming of methane [J]. Applied Catalysis B: Environmental, 2020, 277: 1–12.
|
[7] |
Zhang S P, Li D L, Liu Y, et al. Zirconium doped precipitated Fe-based catalyst for fischer-tropsch synthesis to light olefins at industrially relevant conditions [J]. Catalysis Letter, 2019, 149: 1486–1495.
|
[8] |
Lu F X, Chen X, Wen L X, et al. The synergic effects of iron carbides on conversion of syngas to alkene [J]. Catalysis Letters, 2021, 151: 2132–2143.
|
[9] |
Khodakov A Y, Chu W, Fongarland P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels [J]. Chemical Reviews, 2007, 107(5): 1692–1744.
|
[10] |
Cai F F, Ibrahim J J, Fu Y, et al. Low-temperature hydrogen production from methanol steam reforming on Zn-modified Pt/MoC catalysts [J]. Applied Catalysis B: Environmental, 2020, 264: 1–12.
|
[11] |
Chai Y J, Fu Y, Feng H, et al. A nickel-based perovskite catalyst with a bimodal size distribution of nickel particles for dry reforming of methane [J]. ChemCateChem, 2018, 10(9): 2078–2086.
|
[12] |
Wang C Z, Sun N N, Kang M, et al. The bi-functional mechanism of CH4 dry reforming over a Ni-CaO-ZrO2 catalyst: Further evidence via the identification of the active sites and kinetic studies [J]. Catalysis Science & Technology, 2013 3(9): 2435–2433.
|
[13] |
Guczi L, Erdohelyi A. Catalysis for alternative energy generation [M]. New York: Springer Science Business Media, 2012.
|
[14] |
Wang Y, Yao L, Wang Y N, et al. Low-temperature catalytic CO2 dry reforming of methane on Ni-Si/ZrO2 catalyst [J]. ACS Catalysis, 2018, 8(7): 6495–6506.
|
[15] |
Liu Z Y, Grinter D C, Lustemberg P G, et al. Dry reforming of methane on a highly-active Ni-CeO2 catalyst: Effects of metal-support interactions on C-H bond breaking [J]. Angewandte Chemie International Edition, 2016, 55(26): 7455–7459.
|
[16] |
Liu Z X, Zhou X, Miao Y, et al. A reversible fluorescent probe for real-time quantitative monitoring of cellular glutathione [J]. Angewandte Chemie International Edition, 2017, 56(21): 5812–5816.
|
[17] |
Jang W J, Jeong D W, Shim J O, et al. Combined steam and carbon dioxide reforming of methane and side reactions: Thermodynamic equilibrium analysis and experimental application [J]. Applied Energy, 2016, 173: 80–91.
|
[18] |
Palmer C, Upham D C, Smart S, et al. Dry reforming of methane catalysed by molten metal alloys [J]. Nature Catalysis, 2020 (3): 83–89.
|
[19] |
Song Y D, Ozdemir E, Ramesh S, et al. Response to comment on “Dry reforming of methane by stable Ni-Mo nanocatalysts on single-crystalline MgO” [J]. Science, 2020, 368(6492): 777–781.
|
[20] |
Oemar U, Kathiraser Y, Mo L, et al. CO2 reforming of methane over highly active la-promoted Ni supported on SBA-15 catalysts: Mechanism and kinetic modelling [J]. Catalysis Science & Technology, 2016, 6(4): 1173–1186.
|
[21] |
Buelens L C, Galvita V V, Poelman1 H, et al. Super-dry reforming of methane intensifies CO2 utilization via Le Chatelier’s principle [J]. Science, 2016, 354(6311): 449–452.
|
[22] |
Wang C , Guan E, Wang L, et al. Product selectivity controlled by nanoporous environments in zeolite crystals enveloping rhodium nanoparticle catalysts for CO2 hydrogenation [J]. Journal of the American Chemical Society, 2019, 141(21): 8482–8488.
|
[23] |
Zhang J, Wang L, Zhang B, et al. Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth [J]. Nature Catalysis, 2018, 1: 540–560.
|
[24] |
Gao P, Li S G, Bu X N, et al. Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst [J]. Nature Chemistry, 2017, 9(10): 1019–1024.
|
[25] |
陈倩倩, 顾宇, 唐志永, 等. 以二氧化碳规模化利用技术为核心 的碳减排方案 [J]. 中国科学院院刊, 2019, 34(4): 478–487. Chen Q Q, Gu Y, Tang Z Y, et al. Carbon dioxide sizable utilization technology based carbon reduction solutions [J]. Bulletin of the Chinese Academy of Sciences, 2019, 34(4): 478–487.
|
[26] |
Zhong L S, Yu F, An Y L, et al. Cobalt carbide nanoprisms for direct production of lower olefins from syngas [J]. Nature, 2016, 538(7623): 84–87.
|
[27] |
吴青, 鹿晓斌, 曲顺利, 等. 一种利用富碳天然气进行羰基合 成的方法 : CN111704533A [P/OL]. (2020-09-25)[2021-03-15]. http://pss-system.cnipa.gov.cn/sipopublicsearch/patentsearch/ showViewList-jumpToView.shtml. Wu Q, Lu X B, Qu S L, et al. Method for oxo synthesis using carbon-rich natural gas: CN111704533A [P/OL]. (2020-09-25) [2021-01-15]. http://pss-system.cnipa.gov.cn/sipopublicsearch/ patentsearch/showViewList-jumpToView.shtml.
|
[28] |
吴青, 鹿晓斌, 曲顺利, 等. 一种富碳天然气制备合成气的制备 系统及制备方法: CN111348622A [P/OL]. 2020-06-30 [2021-01- 15]. http://pss-system.cnipa.gov.cn/sipopublicsearch/patentsearch/ searchHomeIndex-searchHomeIndex.shtml. Wu Q, Lu X B, Qu S L, et al. Preparation system and preparation method for preparing synthesis gas from carbon-rich natural gas: CN111348622A [P/OL]. 2020-06-30 [2021-01-15]. http://pss-system.cnipa.gov.cn/sipopublicsearch/patentsearch/searchHomeIndex-searchHomeIndex.shtml.
|
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|
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