
循环热载体无烟燃烧技术的试验研究
何方、王华、戴永年
Methane Nonflame Combustion in Molten Salt Using CuO Catalyst
He Fang、 Wang Hua、 Dai Yongnian
提出了一个基于熔融盐循环热载体的无烟燃烧技术,即把一个燃烧过程分为氧化剂生成和燃料燃烧两个步骤进行,燃烧过程能使助燃空气中的N<sub>2</sub>和燃烧产生的CO<sub>2</sub>在一套反应装置中进行分离,得到较高纯度的N<sub>2</sub>和CO<sub>2</sub>,N<sub>2</sub>可回收利用,CO<sub>2</sub>则可捕集起来安全封存。整个燃烧过程避免了向大气排放有害气体;以CuO为催化剂,对CH<sub>4</sub>在Li<sub>2</sub>CO<sub>3</sub>-K<sub>2</sub>CO<sub>3</sub>-Na<sub>2</sub>SO<sub>4</sub>熔盐体系中的熔融燃烧过程进行的试验研究结果表明,CH<sub>4</sub>能在该熔融盐体系中能完成无烟燃烧过程并放出热,失去晶格氧的CuO能与空气反应重新恢复其晶格氧,气相色谱分析结果显示,理想的反应条件下, 得到的N<sub>2</sub>的纯度为99.<sub>3</sub>%以上,CO<sub>2</sub>的纯度为95.1%以上。
A nonflame combustion technology using thermal cyclic carrier of molten salt introduced in this paper is developed based on the knowledge of energy chemistry, fuel cell and combustion. In this technology, a whole combustion is divided into two steps, i. e. section of producing oxide and section of combustion. In the first step, oxygen is separated form air, and pure N<sub>2</sub> is simultaneously left which is easily recovered. In the other step, fuels react with oxides formed in the first step, and at the same time, thermal energy, CO<sub>2</sub> and H<sub>2</sub>O are produced. The CO<sub>2</sub> is easily separated from water vapour and captured. There are theoretically no environmentally-unfriendly gases such as CO<sub>2</sub>,NO<sub>x</sub> and S0<sub>2</sub> discharged in the whole combustion process. A typical nonflame combustion system using Li<sub>2</sub>CO<sub>3</sub> + K<sub>2</sub>CO<sub>3</sub> + Na<sub>2</sub>SO<sub>4</sub> as molten salt system, CH<sub>4</sub> as fuel, CuO as catalyst was experimentally investigated. Experimental results show that the combustion process proceeded as theoretically analyzed, and high concentration CO<sub>2</sub> of 77.0%〜95.0% and N<sub>2</sub> of 91.9%〜99.<sub>3</sub>% were obtained. The high concentration of CO<sub>2</sub> is favorable for capturing and storing subsequently. So, the potential of reducing CO<sub>2</sub> emissions of this nonflame combustion technology is huge.
nonflame combustion technology / molten salt / greenhouse gas reduction
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