固体氧化物燃料电池（SOFC）是全固态的化学发电装置，其构成材料固体氧化物对SOFC性能的影响尤为重要。本文从材料对SOFC电化学性能影响的视角出发，立足电化学、固体电化学的基本原理，概述了SOFC构成材料的电化学表征方法，并将一些研究积累赘述文中，希望有利于材料的进一步研究。

Solid oxide fuel cells (SOFCs) are the solid-state devices for generating electricity from the chemical energy. The effect of solid oxide materials on the performance of SOFC is especially important. From the influence of materials on electrochemical performance of SOFC, this paper summarizes electrochemical characterization methods for the composition materials of SOFC briefly based on the fundamentals of electrochemistry and solid electrochemistry. Some research experience is also included in the paper, which can facilitate the further research of materials.