渗透汽化脱水分子筛膜的制备与应用研究

顾学红()、徐南平

中国工程科学 ›› 2014, Vol. 16 ›› Issue (12) : 52-58.

PDF(3341 KB)
PDF(3341 KB)
中国工程科学 ›› 2014, Vol. 16 ›› Issue (12) : 52-58.

渗透汽化脱水分子筛膜的制备与应用研究

  • 顾学红()、徐南平

作者信息 +

Study of zeolite membranes for pervaporation dehydration and their applications

  • Gu Xuehong、Xu Nanping

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History +

摘要

开发了擦涂-浸渍涂晶法和亚微米晶种诱导制备NaA分子筛膜技术,有效地提高了膜的成品率、缩短了合成时间,获得了适合规模化生产的制膜工艺。通过分子模拟的方法,对有机溶剂和水在分子筛膜中的传质机理进行了探讨。对NaA分子筛膜在体系中的水热、酸碱和盐稳定性进行了系统地研究,提出了相应的预处理工艺,并设计建造出渗透汽化工业应用装置,实现了长时间稳定运行。

Abstract

A seeding method by rubbing-dipcoating and induction with ball-milled seeds was developed to synthesize NaA zeolite membrane. The synthesis approach could improve the rate of qualified membranes and reduce the synthesis time efficiently,which is suitable for large-scale production of zeolite membranes. Mass transfer mechanism of organic solvent and water in a zeolite membrane was investigated with molecular simulation method. The stability of NaA zeolite membranes in hydrothermal,acid-base and salty environments was systematically studied. A pretreatment method was then proposed and industrial pervaporation plants were built up,which have been operated steadily for long term.

关键词

渗透汽化 / 分子筛膜 / 有机溶剂脱水 / 工业应用

Keywords

pervaporation / zeolite membrane / organic dehydration / industrial application

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顾学红,徐南平. 渗透汽化脱水分子筛膜的制备与应用研究. 中国工程科学. 2014, 16(12): 52-58

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