一种新的概念，受限空间内的界面聚合，用于研究反渗透膜(RO)/纳滤膜(NF)复合膜的合成。实验设计使用受保护的多胺单体通过延迟扩散与均苯三甲酰氯反应，获得了过渡态结构的RO/NF膜。在NF膜水相配方中加入大分子模板剂，诱导界面反应在受限空间内定向发生，将聚合物网络的聚集态由无序转变为有序，同时NF膜对盐的截留性能不变，水通量提高一倍。RO膜有机相配方中加入纳米分子筛，提升水通量超过50 %，复合膜表面结构呈现NF膜的特性，同时脱盐性能保持不变。

Herein, we report a new concept, constricted interfacial polymerization to study the formation of polyamide thin film composite membranes. Delayed diffusion of protected polyfunctional amine reacts with acyl chloride to produce a transition surface structure. Hydrophilic macromolecules and amphiphilic template induced interfacial polymerization reacted in a limited zone, the aggregation state of polymer chains transform from a random state to a regular stateand membrane permeability increases without a loss of salt rejection. Zeolite nanoparticles dispersed in RO composite membrane changed film morphology and water permeability is increased nearly 50% with equivalent salt rejection.